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Literature DB >> 21919144

Copper-catalyzed trifluoromethylation of unactivated olefins.

Andrew T Parsons¹, Stephen L Buchwald.

Abstract

Entities: CellLine Chemical Gene

Mesh：

Substances：
Alkenes
Fluorine
Copper

Year: 2011 PMID： 21919144 PMCID： PMC3390945 DOI： 10.1002/anie.201104053

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

× No keyword cloud information.

30 in total

1. Perfluoroalkylation with Organosilicon Reagents.

Authors: G. K. Surya Prakash; Andrei K. Yudin
Journal: Chem Rev Date: 1997-05-08 Impact factor: 60.622

2. Electrophilic Perfluoroalkylating Agents.

Authors: Teruo Umemoto
Journal: Chem Rev Date: 1996-08-01 Impact factor: 60.622

3. Structure, Reactivity, and Chemistry of Fluoroalkyl Radicals.

Authors: William R. Dolbier
Journal: Chem Rev Date: 1996-08-01 Impact factor: 60.622

4. Novel 10-I-3 hypervalent iodine-based compounds for electrophilic trifluoromethylation.

Authors: Patrick Eisenberger; Sebastian Gischig; Antonio Togni
Journal: Chemistry Date: 2006-03-08 Impact factor: 5.236

5. Facile Ar-CF3 bond formation at Pd. Strikingly different outcomes of reductive elimination from [(Ph3P)2Pd(CF3)Ph] and [(Xantphos)Pd(CF3)Ph].

Authors: Vladimir V Grushin; William J Marshall
Journal: J Am Chem Soc Date: 2006-10-04 Impact factor: 15.419

6. Nucleophilic perfluoroalkylation of aldehydes, ketones, imines, disulfides, and diselenides.

Authors: Chaya Pooput; William R Dolbier; Maurice Médebielle
Journal: J Org Chem Date: 2006-04-28 Impact factor: 4.354

7. Palladium-catalyzed regio- and stereoselective formate reduction of fluorine-containing allylic mesylates. A new entry for the construction of a tertiary carbon attached with a fluoroalkyl group.

Authors: Tsutomu Konno; Tsuyoshi Takehana; Makoto Mishima; Takashi Ishihara
Journal: J Org Chem Date: 2006-04-28 Impact factor: 4.354

8. New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation Of carbonyl compounds with N-formylmorpholine derivatives

Authors:
Journal: Org Lett Date: 2000-07-13 Impact factor: 6.005

9. Radical trifluoromethylation of titanium ate enolate.

Authors: Yoshimitsu Itoh; Koichi Mikami
Journal: Org Lett Date: 2005-02-17 Impact factor: 6.005

10. The first Cu(I)-mediated nucleophilic trifluoromethylation reactions using (trifluoromethyl)trimethylsilane in ionic liquids.

Authors: Jinwi Kim; Jean'ne M Shreeve
Journal: Org Biomol Chem Date: 2004-09-03 Impact factor: 3.876

29 in total

10. Iron(II)-Catalyzed Azidotrifluoromethylation of Olefins and N-Heterocycles for Expedient Vicinal Trifluoromethyl Amine Synthesis.

Authors: Cheng-Liang Zhu; Cheng Wang; Qi-Xue Qin; Sam Yruegas; Caleb D Martin; Hao Xu
Journal: ACS Catal Date: 2018-04-20 Impact factor: 13.084

Copper-catalyzed trifluoromethylation of unactivated olefins.

1. Perfluoroalkylation with Organosilicon Reagents.

2. Electrophilic Perfluoroalkylating Agents.

3. Structure, Reactivity, and Chemistry of Fluoroalkyl Radicals.

4. Novel 10-I-3 hypervalent iodine-based compounds for electrophilic trifluoromethylation.

5. Facile Ar-CF3 bond formation at Pd. Strikingly different outcomes of reductive elimination from [(Ph3P)2Pd(CF3)Ph] and [(Xantphos)Pd(CF3)Ph].

6. Nucleophilic perfluoroalkylation of aldehydes, ketones, imines, disulfides, and diselenides.

7. Palladium-catalyzed regio- and stereoselective formate reduction of fluorine-containing allylic mesylates. A new entry for the construction of a tertiary carbon attached with a fluoroalkyl group.

8. New stable reagents for the nucleophilic trifluoromethylation. 1. Trifluoromethylation Of carbonyl compounds with N-formylmorpholine derivatives

9. Radical trifluoromethylation of titanium ate enolate.

10. The first Cu(I)-mediated nucleophilic trifluoromethylation reactions using (trifluoromethyl)trimethylsilane in ionic liquids.

1. Synthesis and applications of α-trifluoromethylated alkylboron compounds.

2. Allylic functionalization of unactivated olefins with Grignard reagents.

Review 3. Hypervalent Iodine Reagents in High Valent Transition Metal Chemistry.

4. Catalytic One-Step Deoxytrifluoromethylation of Alcohols.

5. Copper-catalyzed oxytrifluoromethylation of unactivated alkenes.

6. The palladium-catalyzed trifluoromethylation of vinyl sulfonates.

7. Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis.

8. Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates.

9. Mechanistic studies on intramolecular C-H trifluoromethoxylation of (hetero)arenes via OCF3-migration.

10. Iron(II)-Catalyzed Azidotrifluoromethylation of Olefins and N-Heterocycles for Expedient Vicinal Trifluoromethyl Amine Synthesis.