| Literature DB >> 15704916 |
Yoshimitsu Itoh1, Koichi Mikami.
Abstract
The radical trifluoromethylation of ketone titanium ate enolates gave alpha-CF3 ketones in good yields. The use of excess amount of LDA and Ti(OiPr)4 in the preparation of titanium ate enolates is the key to the efficient radical trifluoromethylation. [reaction: see text]Entities:
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Year: 2005 PMID： 15704916 DOI： 10.1021/ol047565a
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005