Literature DB >> 21804756

Rhodium-Catalyzed C-H Amination - An Enabling Method for Chemical Synthesis.

J Du Bois1.   

Abstract

Reaction methods for selective C-H amination are finding ever-increasing utility for the preparation of nitrogen-derived fine chemicals. This brief account highlights the remarkable versatility of n class="Chemical">dirhodium-based catalysts for promoting oxidation of aliphatic C-H centers in both intra- and intermolecular reaction processes.

Entities:  

Year:  2011        PMID: 21804756      PMCID: PMC3143484          DOI: 10.1021/op200046v

Source DB:  PubMed          Journal:  Org Process Res Dev        ISSN: 1083-6160            Impact factor:   3.317


  52 in total

1.  Enantioselective C-H amination using cationic ruthenium(II)-pybox catalysts.

Authors:  Erika Milczek; Nadège Boudet; Simon Blakey
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

2.  A stereoselective synthesis of (-)-tetrodotoxin.

Authors:  Andrew Hinman; J Du Bois
Journal:  J Am Chem Soc       Date:  2003-09-24       Impact factor: 15.419

3.  Introduction to selective functionalization of C-H bonds.

Authors:  Robert H Crabtree
Journal:  Chem Rev       Date:  2010-02-10       Impact factor: 60.622

4.  Enantioselective synthesis of the bromopyrrole alkaloids manzacidin A and C by stereospecific C-h bond oxidation.

Authors:  Paul M Wehn; J Du Bois
Journal:  J Am Chem Soc       Date:  2002-11-06       Impact factor: 15.419

5.  Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations.

Authors:  Ravisekhara P Reddy; Huw M L Davies
Journal:  Org Lett       Date:  2006-10-26       Impact factor: 6.005

Review 6.  Understanding and exploiting C-H bond activation.

Authors:  Jay A Labinger; John E Bercaw
Journal:  Nature       Date:  2002-05-30       Impact factor: 49.962

7.  C-H bond functionalization in complex organic synthesis.

Authors:  Kamil Godula; Dalibor Sames
Journal:  Science       Date:  2006-04-07       Impact factor: 47.728

8.  Oxaziridine-mediated catalytic hydroxylation of unactivated 3 degrees C-H bonds using hydrogen peroxide.

Authors:  Benjamin H Brodsky; J Du Bois
Journal:  J Am Chem Soc       Date:  2005-11-09       Impact factor: 15.419

9.  Toward a synthetically useful stereoselective C-H amination of hydrocarbons.

Authors:  Chungen Liang; Florence Collet; Fabien Robert-Peillard; Paul Müller; Robert H Dodd; Philippe Dauban
Journal:  J Am Chem Soc       Date:  2007-12-12       Impact factor: 15.419

10.  (+)-saxitoxin: a first and second generation stereoselective synthesis.

Authors:  James J Fleming; Matthew D McReynolds; J Du Bois
Journal:  J Am Chem Soc       Date:  2007-07-21       Impact factor: 15.419

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  27 in total

1.  Mechanism and Dynamics of Intramolecular C-H Insertion Reactions of 1-Aza-2-azoniaallene Salts.

Authors:  Xin Hong; Daniel A Bercovici; Zhongyue Yang; Nezar Al-Bataineh; Ramya Srinivasan; Ram C Dhakal; K N Houk; Matthias Brewer
Journal:  J Am Chem Soc       Date:  2015-07-07       Impact factor: 15.419

2.  Application of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids.

Authors:  Stephen P Lathrop; Mohammad Movassaghi
Journal:  Chem Sci       Date:  2014-01-01       Impact factor: 9.825

3.  Chemoselective amination of propargylic C(sp³)-H bonds by cobalt(II)-based metalloradical catalysis.

Authors:  Hongjian Lu; Chaoqun Li; Huiling Jiang; Christopher L Lizardi; X Peter Zhang
Journal:  Angew Chem Int Ed Engl       Date:  2014-05-19       Impact factor: 15.336

4.  Identifying Amidyl Radicals for Intermolecular C-H Functionalizations.

Authors:  Matthew M Tierney; Stefano Crespi; Davide Ravelli; Erik J Alexanian
Journal:  J Org Chem       Date:  2019-09-06       Impact factor: 4.354

5.  Quantum Suppression of Intramolecular Deuterium Kinetic Isotope Effects in a Pericyclic Hydrogen Transfer Reaction.

Authors:  Xiao Li; Darrin M York; Matthew P Meyer
Journal:  J Phys Chem A       Date:  2019-04-22       Impact factor: 2.781

6.  Palladium-catalysed electrophilic aromatic C-H fluorination.

Authors:  Kumiko Yamamoto; Jiakun Li; Jeffrey A O Garber; Julian D Rolfes; Gregory B Boursalian; Jannik C Borghs; Christophe Genicot; Jérôme Jacq; Maurice van Gastel; Frank Neese; Tobias Ritter
Journal:  Nature       Date:  2018-02-21       Impact factor: 49.962

7.  Transition-Metal- and Light-Free Directed Amination of Remote Unactivated C(sp3)-H Bonds of Alcohols.

Authors:  Daria Kurandina; Dongari Yadagiri; Mónica Rivas; Aleksei Kavun; Padon Chuentragool; Keiichi Hayama; Vladimir Gevorgyan
Journal:  J Am Chem Soc       Date:  2019-05-08       Impact factor: 15.419

8.  Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascade.

Authors:  Yajing Lian; Joshua R Hummel; Robert G Bergman; Jonathan A Ellman
Journal:  J Am Chem Soc       Date:  2013-08-19       Impact factor: 15.419

9.  An expedient synthesis of maraviroc (UK-427,857) via C-H functionalization.

Authors:  T Aaron Bedell; Graham A B Hone; Justin Du Bois; Erik J Sorensen
Journal:  Tetrahedron Lett       Date:  2015-06-03       Impact factor: 2.415

10.  Intramolecular C(sp3)-N coupling by oxidation of benzylic C,N-dianions.

Authors:  Jenna L Jeffrey; Emily S Bartlett; Richmond Sarpong
Journal:  Angew Chem Int Ed Engl       Date:  2013-01-16       Impact factor: 15.336

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