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Literature DB >> 17048831

Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations.

Abstract

The dirhodium tetracarboxylate, Rh(2)(S-TCPTAD)(4), derived from adamantylglycine, is an effective chiral catalyst for both inter- and intramolecular C-H aminations. [reaction: see text]

Entities: Chemical

Mesh：

Substances：

Year: 2006 PMID： 17048831 DOI： 10.1021/ol061742l

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

25 in total

1. Mechanism and Dynamics of Intramolecular C-H Insertion Reactions of 1-Aza-2-azoniaallene Salts.

Authors: Xin Hong; Daniel A Bercovici; Zhongyue Yang; Nezar Al-Bataineh; Ramya Srinivasan; Ram C Dhakal; K N Houk; Matthias Brewer
Journal: J Am Chem Soc Date: 2015-07-07 Impact factor: 15.419

2. Application of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids.

Authors: Stephen P Lathrop; Mohammad Movassaghi
Journal: Chem Sci Date: 2014-01-01 Impact factor: 9.825

Review 3. Complementary Strategies for Directed C(sp³ )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.

Authors: John C K Chu; Tomislav Rovis
Journal: Angew Chem Int Ed Engl Date: 2017-12-05 Impact factor: 15.336

Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations.

1. Mechanism and Dynamics of Intramolecular C-H Insertion Reactions of 1-Aza-2-azoniaallene Salts.

2. Application of diazene-directed fragment assembly to the total synthesis and stereochemical assignment of (+)-desmethyl-meso-chimonanthine and related heterodimeric alkaloids.

Review 3. Complementary Strategies for Directed C(sp³ )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.

4. Room-temperature enantioselective C-H iodination via kinetic resolution.

5. Site-selective and stereoselective functionalization of non-activated tertiary C-H bonds.

6. Ligand-accelerated enantioselective methylene C(sp3)-H bond activation.

7. Rhodium-catalyzed enantioselective cyclopropanation of electron deficient alkenes.

8. I(III)-Catalyzed Oxidative Cyclization-Migration Tandem Reactions of Unactivated Anilines.

9. Metal-Catalyzed and Metal-Free Intermolecular Amination of Light Alkanes and Benzenes.

Review 10. Catalytic C-H functionalization by metal carbenoid and nitrenoid insertion.

Review 3. Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.

Review 10. Catalytic C-H functionalization by metal carbenoid and nitrenoid insertion.

Review 3. Complementary Strategies for Directed C(sp³ )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer.