Diethyl 4-[2-(4-meth-oxy-phen-yl)-1H-pyrazol-3-yl]-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxyl-ate.

In the title compound, C(23)H(27)N(3)O(5), the pyrazole ring is inclined at dihedral angles of 38.16 (6) and 80.80 (6)°, respectively, to the least-squares planes of the benzene and dihydro-pyridine rings. In the crystal, adjacent mol-ecules are linked via a pair of N-H⋯N hydrogen bonds, forming an inversion dimer. The dimers are stacked in a column along the a axis through N-H⋯O hydrogen bonds. Intra- and inter-molecular C-H⋯N and C-H⋯O hydrogen bonds are also observed.

Related literature

For applications of pyridine derivatives, see: Surendra Kumar et al. (2011 ▶); Swarnalatha et al. (2011 ▶). For the stability of the temperature controller used in the data collection, see: Cosier & Glazer (1986 ▶).

Experimental

Crystal data

C23H27N3O5

M = 425.48

Triclinic,

a = 8.5800 (1) Å

b = 11.1286 (1) Å

c = 11.4996 (1) Å

α = 94.425 (1)°

β = 99.191 (1)°

γ = 92.992 (1)°

V = 1078.37 (2) Å3

Z = 2

Mo Kα radiation

μ = 0.09 mm−1

T = 100 K

0.39 × 0.23 × 0.22 mm

Data collection

Bruker SMART APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2009 ▶) T min = 0.965, T max = 0.980

28279 measured reflections

7437 independent reflections

5974 reflections with I > 2σ(I)

R int = 0.022

Refinement

R[F 2 > 2σ(F 2)] = 0.046

wR(F 2) = 0.134

S = 1.05

7437 reflections

293 parameters

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.51 e Å−3

Δρmin = −0.29 e Å−3

Data collection: APEX2 (Bruker, 2009 ▶); cell refinement: SAINT (Bruker, 2009 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2009 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536811017600/is2709sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536811017600/is2709Isup2.hkl

Supplementary material file. DOI: 10.1107/S1600536811017600/is2709Isup3.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C23H27N3O5	Z = 2
Mr = 425.48	F(000) = 452
Triclinic, P1	Dx = 1.310 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 8.5800 (1) Å	Cell parameters from 9992 reflections
b = 11.1286 (1) Å	θ = 2.4–32.9°
c = 11.4996 (1) Å	µ = 0.09 mm−1
α = 94.425 (1)°	T = 100 K
β = 99.191 (1)°	Block, yellow
γ = 92.992 (1)°	0.39 × 0.23 × 0.22 mm
V = 1078.37 (2) Å3

Bruker SMART APEXII CCD area-detector diffractometer	7437 independent reflections
Radiation source: fine-focus sealed tube	5974 reflections with I > 2σ(I)
graphite	Rint = 0.022
φ and ω scans	θmax = 32.0°, θmin = 1.8°
Absorption correction: multi-scan (SADABS; Bruker, 2009)	h = −12→12
Tmin = 0.965, Tmax = 0.980	k = −16→16
28279 measured reflections	l = −17→17

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.046	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.134	H atoms treated by a mixture of independent and constrained refinement
S = 1.05	w = 1/[σ2(Fo2) + (0.0684P)2 + 0.3274P] where P = (Fo2 + 2Fc2)/3
7437 reflections	(Δ/σ)max = 0.001
293 parameters	Δρmax = 0.51 e Å−3
0 restraints	Δρmin = −0.29 e Å−3

Experimental. The crystal was placed in the cold stream of an Oxford Cryosystems Cobra open-flow nitrogen cryostat (Cosier & Glazer, 1986) operating at 100.0 (1) K.

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
O1	0.16548 (9)	0.44561 (8)	0.87653 (7)	0.02135 (17)
O2	0.38602 (9)	0.35073 (8)	0.93477 (7)	0.01969 (16)
O3	0.47154 (11)	0.01240 (8)	0.66212 (9)	0.0295 (2)
O4	0.25759 (10)	−0.00120 (7)	0.52149 (7)	0.02201 (17)
O5	0.90976 (11)	0.04691 (9)	1.17677 (8)	0.0292 (2)
N1	0.25821 (10)	0.36906 (8)	0.52613 (8)	0.01673 (17)
N2	0.83784 (11)	0.41106 (8)	0.76648 (8)	0.01671 (17)
N3	0.77514 (11)	0.47186 (9)	0.67396 (8)	0.01983 (18)
C1	0.29133 (12)	0.24919 (10)	0.50498 (9)	0.01684 (19)
C2	0.36451 (12)	0.19308 (9)	0.59735 (9)	0.01576 (18)
C3	0.43164 (11)	0.26769 (9)	0.71308 (9)	0.01462 (18)
H3A	0.4394	0.2133	0.7788	0.018*
C4	0.31145 (12)	0.36043 (9)	0.73257 (9)	0.01510 (18)
C5	0.24375 (12)	0.41694 (9)	0.63803 (9)	0.01594 (18)
C6	0.15830 (13)	0.53096 (10)	0.64023 (10)	0.0202 (2)
H6A	0.1846	0.5744	0.7190	0.030*
H6B	0.0439	0.5110	0.6218	0.030*
H6C	0.1905	0.5820	0.5813	0.030*
C7	0.23910 (14)	0.19722 (11)	0.37946 (9)	0.0223 (2)
H7A	0.3043	0.1305	0.3620	0.033*
H7B	0.2510	0.2600	0.3257	0.033*
H7C	0.1279	0.1672	0.3687	0.033*
C8	0.37462 (13)	0.06117 (10)	0.59670 (9)	0.01829 (19)
C9	0.25093 (15)	−0.13152 (10)	0.52548 (11)	0.0248 (2)
H9A	0.2395	−0.1533	0.6057	0.030*
H9B	0.3485	−0.1647	0.5043	0.030*
C10	0.10914 (15)	−0.18010 (11)	0.43720 (11)	0.0263 (2)
H10A	0.0967	−0.2680	0.4382	0.039*
H10B	0.1238	−0.1600	0.3580	0.039*
H10C	0.0143	−0.1440	0.4578	0.039*
C11	0.27844 (12)	0.39157 (9)	0.85152 (9)	0.01611 (18)
C12	0.36198 (14)	0.37357 (12)	1.05686 (10)	0.0241 (2)
H12A	0.2559	0.3404	1.0665	0.029*
H12B	0.3706	0.4614	1.0804	0.029*
C13	0.48935 (16)	0.31170 (14)	1.13135 (11)	0.0306 (3)
H13A	0.4835	0.3301	1.2152	0.046*
H13B	0.5933	0.3406	1.1158	0.046*
H13C	0.4741	0.2242	1.1115	0.046*
C14	0.62754 (12)	0.42337 (10)	0.64436 (10)	0.0191 (2)
H14A	0.5534	0.4484	0.5818	0.023*
C15	0.59282 (12)	0.33141 (9)	0.71527 (9)	0.01463 (18)
C16	0.73356 (12)	0.32572 (9)	0.79400 (9)	0.01473 (18)
C17	0.77961 (12)	0.25038 (9)	0.89185 (9)	0.01571 (18)
C18	0.87821 (13)	0.29968 (10)	0.99559 (9)	0.01787 (19)
H18A	0.9163	0.3820	1.0023	0.021*
C19	0.92046 (13)	0.22914 (11)	1.08843 (9)	0.0211 (2)
H19A	0.9872	0.2634	1.1583	0.025*
C20	0.86537 (13)	0.10797 (11)	1.07957 (10)	0.0216 (2)
C21	0.77058 (14)	0.05728 (11)	0.97597 (10)	0.0229 (2)
H21A	0.7349	−0.0256	0.9687	0.027*
C22	0.72820 (13)	0.12868 (10)	0.88280 (10)	0.0202 (2)
H22A	0.6634	0.0938	0.8123	0.024*
C23	0.85276 (17)	−0.07678 (13)	1.16952 (13)	0.0332 (3)
H23A	0.8849	−0.1095	1.2458	0.050*
H23B	0.8972	−0.1230	1.1081	0.050*
H23C	0.7371	−0.0827	1.1497	0.050*
H1N2	0.941 (2)	0.4250 (14)	0.7995 (14)	0.027 (4)*
H1N1	0.218 (2)	0.4093 (15)	0.4667 (15)	0.031 (4)*

	U11	U22	U33	U12	U13	U23
O1	0.0142 (4)	0.0257 (4)	0.0235 (4)	0.0027 (3)	0.0025 (3)	−0.0017 (3)
O2	0.0162 (4)	0.0277 (4)	0.0152 (3)	0.0038 (3)	0.0015 (3)	0.0024 (3)
O3	0.0270 (4)	0.0188 (4)	0.0375 (5)	0.0045 (3)	−0.0108 (4)	0.0004 (3)
O4	0.0196 (4)	0.0168 (4)	0.0268 (4)	−0.0008 (3)	−0.0033 (3)	0.0003 (3)
O5	0.0293 (5)	0.0338 (5)	0.0243 (4)	0.0007 (4)	−0.0021 (3)	0.0156 (4)
N1	0.0141 (4)	0.0181 (4)	0.0178 (4)	0.0012 (3)	0.0003 (3)	0.0051 (3)
N2	0.0121 (4)	0.0185 (4)	0.0191 (4)	0.0004 (3)	−0.0004 (3)	0.0056 (3)
N3	0.0141 (4)	0.0230 (4)	0.0225 (4)	0.0011 (3)	−0.0003 (3)	0.0096 (3)
C1	0.0130 (4)	0.0187 (5)	0.0182 (4)	−0.0013 (3)	0.0011 (3)	0.0019 (3)
C2	0.0130 (4)	0.0160 (4)	0.0177 (4)	−0.0001 (3)	0.0009 (3)	0.0010 (3)
C3	0.0120 (4)	0.0159 (4)	0.0158 (4)	0.0010 (3)	0.0012 (3)	0.0026 (3)
C4	0.0117 (4)	0.0158 (4)	0.0178 (4)	0.0005 (3)	0.0019 (3)	0.0026 (3)
C5	0.0109 (4)	0.0172 (4)	0.0196 (4)	−0.0002 (3)	0.0015 (3)	0.0033 (3)
C6	0.0165 (5)	0.0197 (5)	0.0249 (5)	0.0043 (4)	0.0020 (4)	0.0053 (4)
C7	0.0232 (5)	0.0254 (5)	0.0167 (4)	0.0007 (4)	−0.0012 (4)	0.0017 (4)
C8	0.0161 (5)	0.0174 (5)	0.0207 (5)	0.0002 (4)	0.0018 (4)	0.0002 (4)
C9	0.0244 (6)	0.0166 (5)	0.0314 (6)	0.0004 (4)	−0.0008 (4)	0.0011 (4)
C10	0.0231 (6)	0.0229 (5)	0.0307 (6)	−0.0012 (4)	0.0007 (4)	−0.0014 (4)
C11	0.0126 (4)	0.0160 (4)	0.0188 (4)	−0.0019 (3)	0.0006 (3)	0.0011 (3)
C12	0.0201 (5)	0.0360 (6)	0.0162 (5)	0.0006 (4)	0.0038 (4)	0.0005 (4)
C13	0.0261 (6)	0.0466 (8)	0.0188 (5)	0.0018 (5)	0.0006 (4)	0.0064 (5)
C14	0.0134 (4)	0.0225 (5)	0.0214 (5)	0.0011 (4)	−0.0003 (4)	0.0088 (4)
C15	0.0120 (4)	0.0156 (4)	0.0161 (4)	0.0009 (3)	0.0009 (3)	0.0030 (3)
C16	0.0135 (4)	0.0150 (4)	0.0156 (4)	0.0017 (3)	0.0014 (3)	0.0028 (3)
C17	0.0134 (4)	0.0174 (4)	0.0162 (4)	0.0020 (3)	0.0010 (3)	0.0031 (3)
C18	0.0162 (5)	0.0189 (5)	0.0178 (4)	0.0010 (4)	0.0004 (3)	0.0020 (4)
C19	0.0186 (5)	0.0264 (5)	0.0169 (4)	0.0009 (4)	−0.0019 (4)	0.0037 (4)
C20	0.0184 (5)	0.0268 (5)	0.0203 (5)	0.0026 (4)	0.0012 (4)	0.0103 (4)
C21	0.0212 (5)	0.0198 (5)	0.0263 (5)	−0.0013 (4)	−0.0023 (4)	0.0080 (4)
C22	0.0188 (5)	0.0194 (5)	0.0206 (5)	0.0001 (4)	−0.0030 (4)	0.0042 (4)
C23	0.0304 (6)	0.0343 (7)	0.0372 (7)	0.0016 (5)	0.0040 (5)	0.0219 (6)

O1—C11	1.2275 (13)	C7—H7C	0.9800
O2—C11	1.3430 (12)	C9—C10	1.5017 (17)
O2—C12	1.4565 (13)	C9—H9A	0.9900
O3—C8	1.2093 (13)	C9—H9B	0.9900
O4—C8	1.3398 (13)	C10—H10A	0.9800
O4—C9	1.4530 (14)	C10—H10B	0.9800
O5—C20	1.3655 (13)	C10—H10C	0.9800
O5—C23	1.4282 (17)	C12—C13	1.5075 (17)
N1—C5	1.3810 (14)	C12—H12A	0.9900
N1—C1	1.3896 (14)	C12—H12B	0.9900
N1—H1N1	0.880 (17)	C13—H13A	0.9800
N2—N3	1.3584 (12)	C13—H13B	0.9800
N2—C16	1.3604 (13)	C13—H13C	0.9800
N2—H1N2	0.906 (17)	C14—C15	1.4056 (14)
N3—C14	1.3317 (14)	C14—H14A	0.9500
C1—C2	1.3574 (14)	C15—C16	1.3963 (14)
C1—C7	1.5021 (15)	C16—C17	1.4708 (13)
C2—C8	1.4746 (14)	C17—C22	1.3931 (15)
C2—C3	1.5254 (14)	C17—C18	1.4029 (14)
C3—C15	1.5165 (14)	C18—C19	1.3867 (14)
C3—C4	1.5258 (14)	C18—H18A	0.9500
C3—H3A	1.0000	C19—C20	1.3960 (17)
C4—C5	1.3627 (13)	C19—H19A	0.9500
C4—C11	1.4602 (14)	C20—C21	1.3921 (16)
C5—C6	1.4988 (15)	C21—C22	1.3959 (14)
C6—H6A	0.9800	C21—H21A	0.9500
C6—H6B	0.9800	C22—H22A	0.9500
C6—H6C	0.9800	C23—H23A	0.9800
C7—H7A	0.9800	C23—H23B	0.9800
C7—H7B	0.9800	C23—H23C	0.9800
C11—O2—C12	116.61 (8)	C9—C10—H10C	109.5
C8—O4—C9	115.93 (9)	H10A—C10—H10C	109.5
C20—O5—C23	116.58 (10)	H10B—C10—H10C	109.5
C5—N1—C1	121.27 (9)	O1—C11—O2	121.98 (10)
C5—N1—H1N1	116.6 (11)	O1—C11—C4	126.11 (9)
C1—N1—H1N1	119.6 (11)	O2—C11—C4	111.89 (9)
N3—N2—C16	112.67 (8)	O2—C12—C13	106.44 (10)
N3—N2—H1N2	120.6 (10)	O2—C12—H12A	110.4
C16—N2—H1N2	126.6 (10)	C13—C12—H12A	110.4
C14—N3—N2	103.98 (8)	O2—C12—H12B	110.4
C2—C1—N1	117.80 (9)	C13—C12—H12B	110.4
C2—C1—C7	127.83 (10)	H12A—C12—H12B	108.6
N1—C1—C7	114.37 (9)	C12—C13—H13A	109.5
C1—C2—C8	124.03 (9)	C12—C13—H13B	109.5
C1—C2—C3	119.30 (9)	H13A—C13—H13B	109.5
C8—C2—C3	116.54 (8)	C12—C13—H13C	109.5
C15—C3—C2	114.71 (8)	H13A—C13—H13C	109.5
C15—C3—C4	109.82 (8)	H13B—C13—H13C	109.5
C2—C3—C4	106.30 (8)	N3—C14—C15	113.01 (9)
C15—C3—H3A	108.6	N3—C14—H14A	123.5
C2—C3—H3A	108.6	C15—C14—H14A	123.5
C4—C3—H3A	108.6	C16—C15—C14	103.80 (9)
C5—C4—C11	121.66 (9)	C16—C15—C3	129.74 (9)
C5—C4—C3	118.34 (9)	C14—C15—C3	126.03 (9)
C11—C4—C3	119.91 (8)	N2—C16—C15	106.53 (9)
C4—C5—N1	118.28 (9)	N2—C16—C17	120.75 (9)
C4—C5—C6	127.35 (10)	C15—C16—C17	132.71 (9)
N1—C5—C6	114.32 (9)	C22—C17—C18	118.77 (9)
C5—C6—H6A	109.5	C22—C17—C16	120.81 (9)
C5—C6—H6B	109.5	C18—C17—C16	120.41 (9)
H6A—C6—H6B	109.5	C19—C18—C17	120.51 (10)
C5—C6—H6C	109.5	C19—C18—H18A	119.7
H6A—C6—H6C	109.5	C17—C18—H18A	119.7
H6B—C6—H6C	109.5	C18—C19—C20	120.28 (10)
C1—C7—H7A	109.5	C18—C19—H19A	119.9
C1—C7—H7B	109.5	C20—C19—H19A	119.9
H7A—C7—H7B	109.5	O5—C20—C21	124.32 (11)
C1—C7—H7C	109.5	O5—C20—C19	115.95 (10)
H7A—C7—H7C	109.5	C21—C20—C19	119.73 (10)
H7B—C7—H7C	109.5	C20—C21—C22	119.77 (10)
O3—C8—O4	122.38 (10)	C20—C21—H21A	120.1
O3—C8—C2	124.30 (10)	C22—C21—H21A	120.1
O4—C8—C2	113.15 (9)	C17—C22—C21	120.91 (10)
O4—C9—C10	106.00 (9)	C17—C22—H22A	119.5
O4—C9—H9A	110.5	C21—C22—H22A	119.5
C10—C9—H9A	110.5	O5—C23—H23A	109.5
O4—C9—H9B	110.5	O5—C23—H23B	109.5
C10—C9—H9B	110.5	H23A—C23—H23B	109.5
H9A—C9—H9B	108.7	O5—C23—H23C	109.5
C9—C10—H10A	109.5	H23A—C23—H23C	109.5
C9—C10—H10B	109.5	H23B—C23—H23C	109.5
H10A—C10—H10B	109.5
C16—N2—N3—C14	0.59 (12)	C5—C4—C11—O2	−163.27 (9)
C5—N1—C1—C2	−23.57 (14)	C3—C4—C11—O2	13.14 (13)
C5—N1—C1—C7	156.10 (10)	C11—O2—C12—C13	175.86 (10)
N1—C1—C2—C8	165.32 (10)	N2—N3—C14—C15	−0.41 (13)
C7—C1—C2—C8	−14.30 (17)	N3—C14—C15—C16	0.10 (13)
N1—C1—C2—C3	−10.26 (14)	N3—C14—C15—C3	173.13 (10)
C7—C1—C2—C3	170.12 (10)	C2—C3—C15—C16	−124.23 (11)
C1—C2—C3—C15	−81.50 (12)	C4—C3—C15—C16	116.16 (11)
C8—C2—C3—C15	102.59 (10)	C2—C3—C15—C14	64.59 (14)
C1—C2—C3—C4	40.06 (12)	C4—C3—C15—C14	−55.03 (13)
C8—C2—C3—C4	−135.85 (9)	N3—N2—C16—C15	−0.54 (12)
C15—C3—C4—C5	82.46 (11)	N3—N2—C16—C17	−179.99 (9)
C2—C3—C4—C5	−42.18 (12)	C14—C15—C16—N2	0.26 (11)
C15—C3—C4—C11	−94.07 (11)	C3—C15—C16—N2	−172.41 (10)
C2—C3—C4—C11	141.30 (9)	C14—C15—C16—C17	179.61 (11)
C11—C4—C5—N1	−168.89 (9)	C3—C15—C16—C17	6.94 (19)
C3—C4—C5—N1	14.65 (14)	N2—C16—C17—C22	−141.80 (11)
C11—C4—C5—C6	13.84 (16)	C15—C16—C17—C22	38.92 (17)
C3—C4—C5—C6	−162.62 (10)	N2—C16—C17—C18	37.31 (15)
C1—N1—C5—C4	21.24 (14)	C15—C16—C17—C18	−141.96 (12)
C1—N1—C5—C6	−161.14 (9)	C22—C17—C18—C19	−1.53 (16)
C9—O4—C8—O3	1.75 (17)	C16—C17—C18—C19	179.34 (10)
C9—O4—C8—C2	−173.77 (9)	C17—C18—C19—C20	0.08 (17)
C1—C2—C8—O3	159.34 (12)	C23—O5—C20—C21	−0.38 (18)
C3—C2—C8—O3	−24.97 (16)	C23—O5—C20—C19	179.30 (11)
C1—C2—C8—O4	−25.24 (15)	C18—C19—C20—O5	−178.22 (10)
C3—C2—C8—O4	150.45 (9)	C18—C19—C20—C21	1.47 (18)
C8—O4—C9—C10	178.33 (10)	O5—C20—C21—C22	178.13 (11)
C12—O2—C11—O1	0.11 (15)	C19—C20—C21—C22	−1.54 (18)
C12—O2—C11—C4	−178.22 (9)	C18—C17—C22—C21	1.46 (17)
C5—C4—C11—O1	18.49 (17)	C16—C17—C22—C21	−179.41 (10)
C3—C4—C11—O1	−165.10 (10)	C20—C21—C22—C17	0.06 (18)

D—H···A	D—H	H···A	D···A	D—H···A
N2—H1N2···O1i	0.906 (17)	1.981 (17)	2.8858 (12)	176.3 (14)
N1—H1N1···N3ii	0.880 (17)	2.173 (17)	2.9969 (13)	155.7 (16)
C6—H6B···N3iii	0.98	2.50	3.4076 (15)	154
C7—H7A···O3iv	0.98	2.59	3.5561 (15)	167
C14—H14A···N1	0.95	2.60	3.2484 (14)	126
C18—H18A···O1v	0.95	2.48	3.1594 (14)	128
C22—H22A···O3	0.95	2.28	3.2210 (15)	170

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N2—H1N2⋯O1i	0.906 (17)	1.981 (17)	2.8858 (12)	176.3 (14)
N1—H1N1⋯N3ii	0.880 (17)	2.173 (17)	2.9969 (13)	155.7 (16)
C6—H6B⋯N3iii	0.98	2.50	3.4076 (15)	154
C7—H7A⋯O3iv	0.98	2.59	3.5561 (15)	167
C14—H14A⋯N1	0.95	2.60	3.2484 (14)	126
C18—H18A⋯O1v	0.95	2.48	3.1594 (14)	128
C22—H22A⋯O3	0.95	2.28	3.2210 (15)	170

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) ; (v) .