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Literature DB >> 21604347

Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.

Phong V Pham¹, David A Nagib, David W C MacMillan.

Abstract

Entities: Chemical Gene

Mesh：

Substances：

Year: 2011 PMID： 21604347 PMCID： PMC3310164 DOI： 10.1002/anie.201101861

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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34 in total

1. Rare-earth metal triflates in organic synthesis.

Authors: Shū Kobayashi; Masaharu Sugiura; Hidetoshi Kitagawa; William W-L Lam
Journal: Chem Rev Date: 2002-06 Impact factor: 60.622

Review 2. Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.

Authors: Jun-An Ma; Dominique Cahard
Journal: Chem Rev Date: 2004-12 Impact factor: 60.622

3. Mild electrophilic trifluoromethylation of carbon- and sulfur-centered nucleophiles by a hypervalent iodine(III)-CF3 reagent.

Authors: Iris Kieltsch; Patrick Eisenberger; Antonio Togni
Journal: Angew Chem Int Ed Engl Date: 2007 Impact factor: 15.336

4. Facile radical trifluoromethylation of lithium enolates.

Authors: Yoshimitsu Itoh; Koichi Mikami
Journal: Org Lett Date: 2005-10-27 Impact factor: 6.005

Review 5. Photocatalysis for the formation of the C-C bond.

Authors: Maurizio Fagnoni; Daniele Dondi; Davide Ravelli; Angelo Albini
Journal: Chem Rev Date: 2007-05-27 Impact factor: 60.622

6. Lewis base activation of Lewis acids: catalytic, enantioselective addition of silyl ketene acetals to aldehydes.

Authors: Scott E Denmark; Gregory L Beutner; Thomas Wynn; Martin D Eastgate
Journal: J Am Chem Soc Date: 2005-03-23 Impact factor: 15.419

7. Enantioselective α-benzylation of aldehydes via photoredox organocatalysis.

Authors: Hui-Wen Shih; Mark N Vander Wal; Rebecca L Grange; David W C MacMillan
Journal: J Am Chem Soc Date: 2010-10-06 Impact factor: 15.419

8. Visible light-mediated intermolecular C-H functionalization of electron-rich heterocycles with malonates.

Authors: Laura Furst; Bryan S Matsuura; Jagan M R Narayanam; Joseph W Tucker; Corey R J Stephenson
Journal: Org Lett Date: 2010-07-02 Impact factor: 6.005

9. Synthesis, characterization and biological evaluation of 7 alpha-perfluoroalkylestradiol derivatives.

Authors: Jean-Claude Blazejewski; Martin P Wilmshurst; Matthew D Popkin; Claude Wakselman; Guy Laurent; Denis Nonclercq; Anny Cleeren; Yan Ma; Hye-Sook Seo; Guy Leclercq
Journal: Bioorg Med Chem Date: 2003-02-06 Impact factor: 3.641

10. Electron-transfer photoredox catalysis: development of a tin-free reductive dehalogenation reaction.

Authors: Jagan M R Narayanam; Joseph W Tucker; Corey R J Stephenson
Journal: J Am Chem Soc Date: 2009-07-01 Impact factor: 15.419

34 in total

1. Functionally diverse nucleophilic trapping of iminium intermediates generated utilizing visible light.

Authors: David B Freeman; Laura Furst; Allison G Condie; Corey R J Stephenson
Journal: Org Lett Date: 2011-12-08 Impact factor: 6.005

2. Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.

Authors: Yingda Ye; Melanie S Sanford
Journal: J Am Chem Soc Date: 2012-05-24 Impact factor: 15.419

Photoredox catalysis: a mild, operationally simple approach to the synthesis of α-trifluoromethyl carbonyl compounds.

1. Rare-earth metal triflates in organic synthesis.

Review 2. Asymmetric fluorination, trifluoromethylation, and perfluoroalkylation reactions.

3. Mild electrophilic trifluoromethylation of carbon- and sulfur-centered nucleophiles by a hypervalent iodine(III)-CF3 reagent.

4. Facile radical trifluoromethylation of lithium enolates.

Review 5. Photocatalysis for the formation of the C-C bond.

6. Lewis base activation of Lewis acids: catalytic, enantioselective addition of silyl ketene acetals to aldehydes.

7. Enantioselective α-benzylation of aldehydes via photoredox organocatalysis.

8. Visible light-mediated intermolecular C-H functionalization of electron-rich heterocycles with malonates.

9. Synthesis, characterization and biological evaluation of 7 alpha-perfluoroalkylestradiol derivatives.

10. Electron-transfer photoredox catalysis: development of a tin-free reductive dehalogenation reaction.

1. Functionally diverse nucleophilic trapping of iminium intermediates generated utilizing visible light.

2. Merging visible-light photocatalysis and transition-metal catalysis in the copper-catalyzed trifluoromethylation of boronic acids with CF3I.

3. Investigations into Transition Metal Catalyzed Arene Trifluoromethylation Reactions.

4. Synthesis and applications of α-trifluoromethylated alkylboron compounds.

Review 5. Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.

6. Endoperoxide synthesis by photocatalytic aerobic [2 + 2 + 2] cycloadditions.

7. Visible-light photoredox catalysis in flow.

8. Studies towards the total synthesis of drimentine C. Preparation of the AB and CDEF ring fragments.

9. Radical cation Diels-Alder cycloadditions by visible light photocatalysis.

Review 10. Solar synthesis: prospects in visible light photocatalysis.