Literature DB >> 21588233

N'-[Bis(benzyl-sulfan-yl)methyl-idene]-4-meth-oxy-benzohydrazide.

Jerry P Jasinski, Ray J Butcher, S K Kushawaha, M K Bharty, N K Singh.   

Abstract

In the title compound, C(23)H(22)N(2)O(2)S(2), the dihedral angles between the 4-meth-oxy-substituted phenyl ring and the other two phenyl rings are 84.4 (4) and 77.7 (1)°, respectively, while the dihedral angle between the two phenyl rings is 57.5 (2)°. The amino group is not involved in an N-H hydrogen bond. The crystal packing is established by inter-molecular C-H⋯O packing inter-actions involving a relatively rare weak three-center hydrogen bond between the keto O atom and H atoms of the two nearby phenyl rings, which link the mol-ecules into chains running along the a axis. Additional weak inter-molecular hydrogen-bond inter-actions between the 4-meth-oxy O atom and one of the phenyl rings and provide added stability to the crystal packing.

Entities:  

Year:  2010        PMID: 21588233      PMCID: PMC3007250          DOI: 10.1107/S1600536810025389

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  3 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  High-yield synthesis of the terminal 188Re triple bond N multiple bond from generator-produced [188ReO4](-).

Authors:  Alessandra Boschi; Cristina Bolzati; Licia Uccelli; Adriano Duatti
Journal:  Nucl Med Biol       Date:  2003-05       Impact factor: 2.408

3.  Structure validation in chemical crystallography.

Authors:  Anthony L Spek
Journal:  Acta Crystallogr D Biol Crystallogr       Date:  2009-01-20
  3 in total
  2 in total

1.  N'-[Bis(benzyl-sulfan-yl)methyl-idene]benzohydrazide.

Authors:  Shahedeh Tayamon; Thahira Begum S A Ravoof; Mohamed Ibrahim Mohamed Tahir; Karen A Crouse; Edward R T Tiekink
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-05-05

2.  Crystal structure of N'-[bis-(ethyl-sulfan-yl)methyl-idene]-2-hy-droxy-4-meth-oxy-benzohydrazide.

Authors:  Paras Nath; Manoj K Bharty; Rahul Chaurasia; Sanyucta Kumari; Sushil K Gupta
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-11-21
  2 in total

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