catena-Poly[[aqua-(5,5'-dimethyl-2,2'-bipyridine-κN,N')copper(II)]-μ-2,2'-oxydibenzoato-κO:O'].

In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is penta-coordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5'-dimethyl-2,2'-bipyridine (dbp) ligand and two O atoms of two different 2,2'-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(2)O(2) donor atoms are nearly coplanar, with a mean deviation from the least-squares plane of 0.0518 (11) Å and the Cu atom is displaced by 0.1507 (11) Å from this plane towards the apical water O atom. Further coordination via the 2,2'-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. In the crystal structure, O-H⋯O hydrogen bonds link the mol-ecules into a two-dimensional supra-molecular structure.

Related literature

For background to the network topologies and applications of coordination polymers, see: Yaghi et al. (1998 ▶). For structures containing odb ligands, see: Gong et al. (2009 ▶); Hong (2008a ▶,b ▶); Wang et al. (2010 ▶); Yu (2008 ▶); Xu et al. (2008a ▶,b ▶). For complexes with 5,5′-dimethyl-2,2′-bipyridine (dbp), see: Zhao & Bai (2009 ▶); Khalighi et al. (2008 ▶); Kalateh et al. (2008 ▶); Dong et al. (2009 ▶); Ahmadi et al. (2008 ▶, 2010 ▶).

Experimental

Crystal data

[Cu(C14H8O5)(C12H12N2)(H2O)]

M = 522.00

Monoclinic,

a = 7.4235 (11) Å

b = 17.475 (3) Å

c = 18.053 (3) Å

β = 98.188 (3)°

V = 2318.0 (6) Å3

Z = 4

Mo Kα radiation

μ = 0.99 mm−1

T = 296 K

0.20 × 0.18 × 0.16 mm

Data collection

Bruker SMART APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2009 ▶) T min = 0.827, T max = 0.858

12080 measured reflections

4071 independent reflections

3150 reflections with I > 2σ(I)

R int = 0.042

Refinement

R[F 2 > 2σ(F 2)] = 0.043

wR(F 2) = 0.097

S = 1.04

4071 reflections

318 parameters

H-atom parameters constrained

Δρmax = 0.32 e Å−3

Δρmin = −0.22 e Å−3

Data collection: APEX2 (Bruker, 2009 ▶); cell refinement: SAINT (Bruker, 2009 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: DIAMOND (Brandenburg, 2010 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S160053681002622X/nk2034sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S160053681002622X/nk2034Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cu(C14H8O5)(C12H12N2)(H2O)]	F(000) = 1076
Mr = 522.00	Dx = 1.496 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 2235 reflections
a = 7.4235 (11) Å	θ = 2.1–25.6°
b = 17.475 (3) Å	µ = 0.99 mm−1
c = 18.053 (3) Å	T = 296 K
β = 98.188 (3)°	Block, blue
V = 2318.0 (6) Å3	0.20 × 0.18 × 0.16 mm
Z = 4

Bruker SMART APEXII CCD area-detector diffractometer	4071 independent reflections
Radiation source: fine-focus sealed tube	3150 reflections with I > 2σ(I)
graphite	Rint = 0.042
ω scans	θmax = 25.0°, θmin = 2.3°
Absorption correction: multi-scan (SADABS; Bruker, 2009)	h = −8→8
Tmin = 0.827, Tmax = 0.858	k = −20→10
12080 measured reflections	l = −21→21

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.043	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.097	H-atom parameters constrained
S = 1.04	w = 1/[σ2(Fo2) + (0.050P)2 + 0.0178P] where P = (Fo2 + 2Fc2)/3
4071 reflections	(Δ/σ)max = 0.001
318 parameters	Δρmax = 0.32 e Å−3
0 restraints	Δρmin = −0.22 e Å−3

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cu1	0.41788 (4)	0.62384 (2)	0.109714 (18)	0.03306 (13)
N1	0.3306 (3)	0.65433 (15)	0.00279 (13)	0.0377 (6)
N2	0.3278 (3)	0.52235 (13)	0.06863 (12)	0.0323 (5)
O1	0.4265 (2)	0.93932 (11)	0.19835 (11)	0.0386 (5)
O2	0.4863 (3)	1.08114 (12)	0.29366 (10)	0.0418 (5)
O3	0.1882 (3)	1.09819 (15)	0.29298 (12)	0.0577 (6)
O4	0.3634 (3)	0.77983 (13)	0.19838 (16)	0.0715 (8)
O5	0.5373 (3)	0.72067 (11)	0.12721 (11)	0.0426 (5)
O1W	0.1358 (3)	0.66083 (13)	0.14824 (12)	0.0539 (6)
H1WA	0.1690	0.7023	0.1708	0.065*
H1WB	0.0485	0.6448	0.1698	0.065*
C1	0.3209 (4)	1.08195 (16)	0.26283 (15)	0.0336 (7)
C2	0.2924 (3)	1.06403 (16)	0.18006 (15)	0.0299 (6)
C3	0.1997 (4)	1.11672 (18)	0.13170 (17)	0.0416 (7)
H3	0.1522	1.1605	0.1510	0.050*
C4	0.1763 (5)	1.1054 (2)	0.05493 (19)	0.0591 (10)
H4	0.1161	1.1419	0.0230	0.071*
C5	0.2424 (5)	1.0401 (3)	0.02647 (19)	0.0661 (11)
H5	0.2284	1.0327	−0.0250	0.079*
C6	0.3294 (4)	0.9855 (2)	0.07367 (19)	0.0532 (9)
H6	0.3713	0.9407	0.0542	0.064*
C7	0.3543 (3)	0.99754 (17)	0.15049 (16)	0.0332 (7)
C8	0.6009 (4)	0.91544 (17)	0.18894 (15)	0.0319 (6)
C9	0.7378 (4)	0.97019 (18)	0.19715 (17)	0.0424 (8)
H9	0.7110	1.0207	0.2076	0.051*
C10	0.9132 (4)	0.9495 (2)	0.18986 (19)	0.0504 (9)
H10	1.0052	0.9860	0.1957	0.060*
C11	0.9531 (4)	0.8748 (2)	0.17389 (18)	0.0500 (9)
H11	1.0716	0.8609	0.1687	0.060*
C12	0.8167 (4)	0.82106 (18)	0.16569 (16)	0.0396 (7)
H12	0.8445	0.7708	0.1546	0.048*
C13	0.6376 (3)	0.83974 (17)	0.17359 (14)	0.0299 (6)
C14	0.4984 (4)	0.77630 (16)	0.16651 (16)	0.0327 (7)
C15	0.3015 (5)	0.8219 (2)	−0.1299 (2)	0.0723 (12)
H15A	0.3508	0.8548	−0.0894	0.108*
H15B	0.1830	0.8399	−0.1509	0.108*
H15C	0.3802	0.8222	−0.1677	0.108*
C16	0.2864 (4)	0.7414 (2)	−0.10098 (19)	0.0529 (9)
C17	0.2245 (5)	0.6804 (3)	−0.14685 (19)	0.0643 (11)
H17	0.1899	0.6886	−0.1978	0.077*
C18	0.2136 (4)	0.6083 (2)	−0.11798 (18)	0.0552 (9)
H18	0.1712	0.5678	−0.1491	0.066*
C19	0.2660 (4)	0.59610 (19)	−0.04244 (16)	0.0381 (7)
C20	0.3397 (4)	0.7244 (2)	−0.02617 (18)	0.0474 (8)
H20	0.3842	0.7639	0.0058	0.057*
C21	0.2604 (4)	0.52224 (18)	−0.00508 (16)	0.0351 (7)
C22	0.1926 (4)	0.4554 (2)	−0.03889 (18)	0.0482 (9)
H22	0.1471	0.4551	−0.0896	0.058*
C23	0.1919 (4)	0.38961 (19)	0.0019 (2)	0.0527 (9)
H23	0.1453	0.3448	−0.0212	0.063*
C24	0.2601 (4)	0.38895 (18)	0.07754 (19)	0.0452 (8)
C25	0.2616 (5)	0.3185 (2)	0.1245 (2)	0.0670 (11)
H25A	0.3677	0.3187	0.1617	0.100*
H25B	0.2637	0.2740	0.0933	0.100*
H25C	0.1544	0.3174	0.1486	0.100*
C26	0.3266 (4)	0.45785 (18)	0.10777 (17)	0.0404 (7)
H26	0.3733	0.4592	0.1584	0.048*

	U11	U22	U33	U12	U13	U23
Cu1	0.0383 (2)	0.0272 (2)	0.0334 (2)	−0.00240 (16)	0.00395 (14)	−0.00399 (17)
N1	0.0390 (14)	0.0389 (15)	0.0359 (14)	−0.0015 (12)	0.0077 (11)	0.0017 (12)
N2	0.0340 (12)	0.0318 (14)	0.0316 (13)	−0.0041 (11)	0.0064 (10)	−0.0061 (11)
O1	0.0331 (11)	0.0267 (11)	0.0592 (13)	0.0026 (9)	0.0180 (9)	0.0021 (10)
O2	0.0402 (12)	0.0403 (13)	0.0417 (12)	0.0130 (10)	−0.0054 (9)	−0.0067 (10)
O3	0.0453 (13)	0.0819 (18)	0.0500 (13)	0.0019 (12)	0.0210 (11)	−0.0035 (13)
O4	0.0533 (14)	0.0459 (15)	0.126 (2)	−0.0231 (12)	0.0493 (15)	−0.0352 (15)
O5	0.0499 (12)	0.0283 (11)	0.0514 (13)	−0.0063 (10)	0.0133 (10)	−0.0108 (10)
O1W	0.0399 (12)	0.0536 (15)	0.0716 (16)	−0.0091 (11)	0.0198 (11)	−0.0203 (13)
C1	0.0371 (17)	0.0235 (15)	0.0408 (17)	0.0012 (13)	0.0078 (14)	0.0056 (14)
C2	0.0235 (13)	0.0295 (16)	0.0369 (16)	−0.0052 (12)	0.0049 (11)	0.0030 (13)
C3	0.0399 (16)	0.0364 (18)	0.0472 (18)	0.0048 (15)	0.0013 (14)	0.0037 (15)
C4	0.056 (2)	0.069 (3)	0.047 (2)	0.0104 (19)	−0.0089 (17)	0.0112 (19)
C5	0.061 (2)	0.098 (3)	0.0355 (19)	−0.001 (2)	−0.0050 (17)	−0.007 (2)
C6	0.0492 (19)	0.060 (2)	0.051 (2)	−0.0011 (18)	0.0081 (16)	−0.0185 (19)
C7	0.0255 (14)	0.0331 (17)	0.0407 (17)	−0.0081 (12)	0.0034 (12)	0.0026 (14)
C8	0.0298 (15)	0.0320 (17)	0.0351 (15)	−0.0048 (13)	0.0086 (12)	0.0002 (14)
C9	0.0422 (18)	0.0319 (17)	0.0544 (19)	−0.0101 (14)	0.0115 (14)	−0.0043 (15)
C10	0.0339 (17)	0.051 (2)	0.066 (2)	−0.0191 (16)	0.0065 (15)	0.0003 (19)
C11	0.0255 (15)	0.064 (2)	0.060 (2)	−0.0004 (17)	0.0041 (14)	0.006 (2)
C12	0.0325 (16)	0.0381 (18)	0.0482 (18)	0.0053 (14)	0.0057 (13)	−0.0021 (15)
C13	0.0275 (15)	0.0310 (16)	0.0308 (15)	0.0000 (12)	0.0027 (11)	−0.0025 (13)
C14	0.0323 (16)	0.0254 (16)	0.0395 (16)	0.0004 (13)	0.0015 (13)	−0.0001 (14)
C15	0.070 (2)	0.075 (3)	0.070 (3)	−0.008 (2)	0.005 (2)	0.034 (2)
C16	0.0409 (18)	0.067 (2)	0.051 (2)	−0.0076 (18)	0.0062 (15)	0.0202 (19)
C17	0.059 (2)	0.092 (3)	0.039 (2)	−0.020 (2)	−0.0020 (16)	0.014 (2)
C18	0.057 (2)	0.069 (3)	0.0380 (19)	−0.0188 (19)	0.0025 (16)	−0.0017 (18)
C19	0.0316 (16)	0.050 (2)	0.0341 (16)	−0.0065 (14)	0.0096 (13)	−0.0049 (15)
C20	0.0485 (19)	0.048 (2)	0.0455 (19)	−0.0052 (16)	0.0052 (15)	0.0036 (17)
C21	0.0258 (14)	0.0451 (19)	0.0357 (17)	−0.0042 (13)	0.0090 (12)	−0.0073 (15)
C22	0.0474 (19)	0.058 (2)	0.0389 (18)	−0.0118 (17)	0.0065 (14)	−0.0176 (18)
C23	0.056 (2)	0.038 (2)	0.064 (2)	−0.0134 (16)	0.0109 (17)	−0.0206 (18)
C24	0.0435 (18)	0.0355 (19)	0.058 (2)	−0.0045 (15)	0.0119 (15)	−0.0116 (16)
C25	0.083 (3)	0.034 (2)	0.082 (3)	−0.0090 (19)	0.008 (2)	−0.003 (2)
C26	0.0398 (16)	0.0388 (19)	0.0421 (18)	−0.0015 (15)	0.0046 (13)	−0.0065 (16)

Cu1—O5	1.915 (2)	C9—H9	0.9300
Cu1—O2i	1.9370 (19)	C10—C11	1.377 (5)
Cu1—N2	2.000 (2)	C10—H10	0.9300
Cu1—N1	2.018 (2)	C11—C12	1.374 (4)
Cu1—O1W	2.388 (2)	C11—H11	0.9300
N1—C20	1.336 (4)	C12—C13	1.396 (4)
N1—C19	1.349 (4)	C12—H12	0.9300
N2—C26	1.331 (4)	C13—C14	1.508 (4)
N2—C21	1.353 (4)	C15—C16	1.510 (5)
O1—C7	1.392 (3)	C15—H15A	0.9600
O1—C8	1.394 (3)	C15—H15B	0.9600
O2—C1	1.274 (3)	C15—H15C	0.9600
O2—Cu1ii	1.9371 (19)	C16—C20	1.384 (4)
O3—C1	1.225 (3)	C16—C17	1.388 (5)
O4—C14	1.226 (3)	C17—C18	1.371 (5)
O5—C14	1.261 (3)	C17—H17	0.9300
O1W—H1WA	0.8500	C18—C19	1.380 (4)
O1W—H1WB	0.8500	C18—H18	0.9300
C1—C2	1.512 (4)	C19—C21	1.460 (4)
C2—C3	1.383 (4)	C20—H20	0.9300
C2—C7	1.384 (4)	C21—C22	1.380 (4)
C3—C4	1.386 (4)	C22—C23	1.366 (5)
C3—H3	0.9300	C22—H22	0.9300
C4—C5	1.370 (5)	C23—C24	1.387 (5)
C4—H4	0.9300	C23—H23	0.9300
C5—C6	1.378 (5)	C24—C26	1.384 (4)
C5—H5	0.9300	C24—C25	1.494 (5)
C6—C7	1.389 (4)	C25—H25A	0.9600
C6—H6	0.9300	C25—H25B	0.9600
C8—C13	1.386 (4)	C25—H25C	0.9600
C8—C9	1.388 (4)	C26—H26	0.9300
C9—C10	1.376 (4)
O5—Cu1—O2i	95.15 (8)	C12—C11—H11	120.2
O5—Cu1—N2	165.19 (9)	C10—C11—H11	120.2
O2i—Cu1—N2	93.03 (9)	C11—C12—C13	121.8 (3)
O5—Cu1—N1	90.14 (10)	C11—C12—H12	119.1
O2i—Cu1—N1	171.74 (10)	C13—C12—H12	119.1
N2—Cu1—N1	80.48 (10)	C8—C13—C12	117.4 (3)
O5—Cu1—O1W	96.74 (8)	C8—C13—C14	124.5 (2)
O2i—Cu1—O1W	93.83 (8)	C12—C13—C14	118.1 (3)
N2—Cu1—O1W	95.01 (8)	O4—C14—O5	124.8 (3)
N1—Cu1—O1W	91.83 (9)	O4—C14—C13	121.3 (3)
C20—N1—C19	119.2 (3)	O5—C14—C13	113.9 (2)
C20—N1—Cu1	126.1 (2)	C16—C15—H15A	109.5
C19—N1—Cu1	114.7 (2)	C16—C15—H15B	109.5
C26—N2—C21	119.4 (3)	H15A—C15—H15B	109.5
C26—N2—Cu1	125.53 (19)	C16—C15—H15C	109.5
C21—N2—Cu1	115.0 (2)	H15A—C15—H15C	109.5
C7—O1—C8	115.2 (2)	H15B—C15—H15C	109.5
C1—O2—Cu1ii	126.63 (18)	C20—C16—C17	116.2 (3)
C14—O5—Cu1	129.49 (18)	C20—C16—C15	120.8 (4)
Cu1—O1W—H1WA	99.4	C17—C16—C15	123.0 (3)
Cu1—O1W—H1WB	143.3	C18—C17—C16	120.8 (3)
H1WA—O1W—H1WB	104.5	C18—C17—H17	119.6
O3—C1—O2	126.5 (3)	C16—C17—H17	119.6
O3—C1—C2	118.6 (3)	C17—C18—C19	119.6 (3)
O2—C1—C2	114.8 (2)	C17—C18—H18	120.2
C3—C2—C7	118.6 (3)	C19—C18—H18	120.2
C3—C2—C1	118.2 (3)	N1—C19—C18	120.5 (3)
C7—C2—C1	123.2 (3)	N1—C19—C21	114.7 (2)
C2—C3—C4	121.1 (3)	C18—C19—C21	124.8 (3)
C2—C3—H3	119.5	N1—C20—C16	123.7 (3)
C4—C3—H3	119.5	N1—C20—H20	118.1
C5—C4—C3	119.5 (3)	C16—C20—H20	118.1
C5—C4—H4	120.2	N2—C21—C22	119.8 (3)
C3—C4—H4	120.2	N2—C21—C19	115.0 (3)
C4—C5—C6	120.4 (3)	C22—C21—C19	125.2 (3)
C4—C5—H5	119.8	C23—C22—C21	120.2 (3)
C6—C5—H5	119.8	C23—C22—H22	119.9
C5—C6—C7	119.8 (3)	C21—C22—H22	119.9
C5—C6—H6	120.1	C22—C23—C24	120.6 (3)
C7—C6—H6	120.1	C22—C23—H23	119.7
C2—C7—C6	120.5 (3)	C24—C23—H23	119.7
C2—C7—O1	119.6 (2)	C26—C24—C23	116.2 (3)
C6—C7—O1	119.6 (3)	C26—C24—C25	121.3 (3)
C13—C8—C9	121.2 (3)	C23—C24—C25	122.5 (3)
C13—C8—O1	121.5 (2)	C24—C25—H25A	109.5
C9—C8—O1	117.3 (3)	C24—C25—H25B	109.5
C10—C9—C8	119.8 (3)	H25A—C25—H25B	109.5
C10—C9—H9	120.1	C24—C25—H25C	109.5
C8—C9—H9	120.1	H25A—C25—H25C	109.5
C9—C10—C11	120.3 (3)	H25B—C25—H25C	109.5
C9—C10—H10	119.9	N2—C26—C24	123.8 (3)
C11—C10—H10	119.9	N2—C26—H26	118.1
C12—C11—C10	119.5 (3)	C24—C26—H26	118.1
O5—Cu1—N1—C20	−10.9 (3)	C10—C11—C12—C13	−0.4 (5)
N2—Cu1—N1—C20	−179.3 (3)	C9—C8—C13—C12	−0.9 (4)
O1W—Cu1—N1—C20	85.9 (3)	O1—C8—C13—C12	−179.5 (2)
O5—Cu1—N1—C19	165.91 (19)	C9—C8—C13—C14	177.8 (3)
N2—Cu1—N1—C19	−2.56 (19)	O1—C8—C13—C14	−0.8 (4)
O1W—Cu1—N1—C19	−97.33 (19)	C11—C12—C13—C8	1.0 (4)
O5—Cu1—N2—C26	131.0 (3)	C11—C12—C13—C14	−177.7 (3)
O2i—Cu1—N2—C26	7.5 (2)	Cu1—O5—C14—O4	−4.9 (4)
N1—Cu1—N2—C26	−177.6 (2)	Cu1—O5—C14—C13	173.43 (17)
O1W—Cu1—N2—C26	−86.6 (2)	C8—C13—C14—O4	−26.1 (4)
O5—Cu1—N2—C21	−50.3 (4)	C12—C13—C14—O4	152.6 (3)
O2i—Cu1—N2—C21	−173.76 (19)	C8—C13—C14—O5	155.5 (3)
N1—Cu1—N2—C21	1.10 (18)	C12—C13—C14—O5	−25.8 (4)
O1W—Cu1—N2—C21	92.12 (19)	C20—C16—C17—C18	1.6 (5)
O2i—Cu1—O5—C14	−76.3 (3)	C15—C16—C17—C18	179.9 (3)
N2—Cu1—O5—C14	160.5 (3)	C16—C17—C18—C19	−0.4 (5)
N1—Cu1—O5—C14	110.1 (3)	C20—N1—C19—C18	1.4 (4)
O1W—Cu1—O5—C14	18.2 (3)	Cu1—N1—C19—C18	−175.6 (2)
Cu1ii—O2—C1—O3	−13.0 (4)	C20—N1—C19—C21	−179.5 (3)
Cu1ii—O2—C1—C2	164.26 (18)	Cu1—N1—C19—C21	3.5 (3)
O3—C1—C2—C3	53.5 (4)	C17—C18—C19—N1	−1.2 (5)
O2—C1—C2—C3	−124.0 (3)	C17—C18—C19—C21	179.9 (3)
O3—C1—C2—C7	−126.4 (3)	C19—N1—C20—C16	−0.2 (5)
O2—C1—C2—C7	56.2 (4)	Cu1—N1—C20—C16	176.5 (2)
C7—C2—C3—C4	−3.1 (4)	C17—C16—C20—N1	−1.3 (5)
C1—C2—C3—C4	177.0 (3)	C15—C16—C20—N1	−179.6 (3)
C2—C3—C4—C5	1.5 (5)	C26—N2—C21—C22	−0.4 (4)
C3—C4—C5—C6	0.9 (6)	Cu1—N2—C21—C22	−179.2 (2)
C4—C5—C6—C7	−1.6 (5)	C26—N2—C21—C19	179.2 (2)
C3—C2—C7—C6	2.4 (4)	Cu1—N2—C21—C19	0.4 (3)
C1—C2—C7—C6	−177.8 (3)	N1—C19—C21—N2	−2.6 (4)
C3—C2—C7—O1	−171.6 (2)	C18—C19—C21—N2	176.4 (3)
C1—C2—C7—O1	8.3 (4)	N1—C19—C21—C22	177.0 (3)
C5—C6—C7—C2	0.0 (5)	C18—C19—C21—C22	−4.0 (5)
C5—C6—C7—O1	173.9 (3)	N2—C21—C22—C23	0.5 (4)
C8—O1—C7—C2	−125.2 (3)	C19—C21—C22—C23	−179.1 (3)
C8—O1—C7—C6	60.8 (3)	C21—C22—C23—C24	−0.4 (5)
C7—O1—C8—C13	−123.0 (3)	C22—C23—C24—C26	0.1 (5)
C7—O1—C8—C9	58.4 (3)	C22—C23—C24—C25	179.8 (3)
C13—C8—C9—C10	0.2 (4)	C21—N2—C26—C24	0.1 (4)
O1—C8—C9—C10	178.8 (3)	Cu1—N2—C26—C24	178.8 (2)
C8—C9—C10—C11	0.5 (5)	C23—C24—C26—N2	0.0 (5)
C9—C10—C11—C12	−0.4 (5)	C25—C24—C26—N2	−179.7 (3)

D—H···A	D—H	H···A	D···A	D—H···A
O1W—H1WA···O4	0.85	1.99	2.750 (3)	148
O1W—H1WB···O3iii	0.85	2.13	2.972 (3)	171

Cu1—O5	1.915 (2)
Cu1—O2i	1.9370 (19)
Cu1—N2	2.000 (2)
Cu1—N1	2.018 (2)
Cu1—O1W	2.388 (2)
O2—Cu1ii	1.9371 (19)

O5—Cu1—O2i	95.15 (8)
O5—Cu1—N2	165.19 (9)
O2i—Cu1—N2	93.03 (9)
O5—Cu1—N1	90.14 (10)
O2i—Cu1—N1	171.74 (10)
N2—Cu1—N1	80.48 (10)
O5—Cu1—O1W	96.74 (8)
O2i—Cu1—O1W	93.83 (8)
N2—Cu1—O1W	95.01 (8)
N1—Cu1—O1W	91.83 (9)

Symmetry codes: (i) ; (ii) .

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1W—H1WA⋯O4	0.85	1.99	2.750 (3)	148
O1W—H1WB⋯O3iii	0.85	2.13	2.972 (3)	171

Symmetry code: (iii) .