Literature DB >> 21201646

Dichlorido(5,5'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Aida Khalighi, Roya Ahmadi, Vahid Amani, Hamid Reza Khavasi.   

Abstract

The asymmetric unit of the title compound, [ZnCl(2)(C(12)H(12)N(2))], contains two independent mol-ecules. The Zn(II) atoms are four-coordinated in distorted tetra-hedral configurations by two N atoms from 5,5'-dimethyl-2,2'-bipyridine and two terminal Cl atoms. In the crystal structure, inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules. There are C-H⋯π contacts between the methyl groups and the pyridine and five-membered rings containing Zn(II) atoms; π-π contacts also exist between the pyridine rings [centroid-centroid distances = 3.665 (5) and 3.674 (5) Å].

Entities:  

Year:  2008        PMID： 21201646      PMCID： PMC2960607          DOI： 10.1107/S1600536808027104

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN： 1600-5368


Related literature

For related literature, see: Gruia et al. (2007 ▶); Khan & Tuck (1984 ▶); Khavasi et al. (2008 ▶); Kozhevnikov et al. (2006 ▶); Liu et al. (2004 ▶); Lundberg (1966 ▶); Preston & Kennard (1969 ▶); Qin et al. (1999 ▶); Reimann et al. (1966 ▶); Steffen & Palenik (1976 ▶, 1977 ▶).

Experimental

Crystal data

[ZnCl2(C12H12N2)] M = 320.53 Orthorhombic, a = 16.267 (2) Å b = 11.1704 (16) Å c = 14.9328 (14) Å V = 2713.4 (6) Å3 Z = 8 Mo Kα radiation μ = 2.18 mm−1 T = 298 (2) K 0.28 × 0.20 × 0.07 mm

Data collection

Bruker SMART CCD area-detector diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1998 ▶) T min = 0.612, T max = 0.860 14309 measured reflections 7167 independent reflections 4463 reflections with I > 2σ(I) R int = 0.066

Refinement

R[F 2 > 2σ(F 2)] = 0.066 wR(F 2) = 0.150 S = 1.07 7167 reflections 307 parameters 1 restraint H-atom parameters constrained Δρmax = 0.29 e Å−3 Δρmin = −0.30 e Å−3 Absolute structure: Flack (1983 ▶), 3320 Friedel pairs Flack parameter: 0.07 (3) Data collection: SMART (Bruker, 1998 ▶); cell refinement: SAINT (Bruker, 1998 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶). Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808027104/hk2517sup1.cif Structure factors: contains datablocks I. DOI: 10.1107/S1600536808027104/hk2517Isup2.hkl Additional supplementary materials: crystallographic information; 3D view; checkCIF report
[ZnCl2(C12H12N2)]F000 = 1296
Mr = 320.53Dx = 1.569 Mg m−3
Orthorhombic, Pna21Mo Kα radiation λ = 0.71073 Å
Hall symbol: P 2c -2nCell parameters from 2610 reflections
a = 16.267 (2) Åθ = 2.2–29.3º
b = 11.1704 (16) ŵ = 2.18 mm−1
c = 14.9328 (14) ÅT = 298 (2) K
V = 2713.4 (6) Å3Block, colorless
Z = 80.28 × 0.20 × 0.07 mm
Bruker SMART CCD area-detector diffractometer7167 independent reflections
Radiation source: fine-focus sealed tube4463 reflections with I > 2σ(I)
Monochromator: graphiteRint = 0.066
T = 298(2) Kθmax = 29.3º
φ and ω scansθmin = 2.2º
Absorption correction: multi-scan(SADABS; Sheldrick, 1998)h = −22→13
Tmin = 0.612, Tmax = 0.860k = −13→15
14309 measured reflectionsl = −20→20
Refinement on F2Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: fullH-atom parameters constrained
R[F2 > 2σ(F2)] = 0.066  w = 1/[σ2(Fo2) + (0.0545P)2 + 2.0209P] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.150(Δ/σ)max = 0.045
S = 1.08Δρmax = 0.29 e Å−3
7167 reflectionsΔρmin = −0.30 e Å−3
307 parametersExtinction correction: none
1 restraintAbsolute structure: Flack (1983), 3320 Friedel pairs
Primary atom site location: structure-invariant direct methodsFlack parameter: 0.07 (3)
Secondary atom site location: difference Fourier map
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.
xyzUiso*/Ueq
Zn1−0.27268 (5)−0.87606 (8)−0.43784 (5)0.0530 (4)
Zn2−0.77530 (5)−1.11325 (7)−0.47118 (5)0.0521 (3)
Cl1−0.33658 (15)−0.9839 (2)−0.33543 (19)0.0872 (8)
Cl2−0.35350 (12)−0.7899 (2)−0.53825 (16)0.0671 (6)
Cl3−0.84859 (13)−1.0208 (2)−0.36748 (16)0.0644 (6)
Cl4−0.84271 (14)−1.2264 (2)−0.56774 (19)0.0823 (8)
N1−0.1798 (4)−0.7734 (5)−0.3840 (4)0.0508 (16)
N2−0.1730 (4)−0.9564 (5)−0.4975 (4)0.0508 (15)
N3−0.6710 (4)−1.1912 (5)−0.4188 (4)0.0521 (14)
N4−0.6855 (4)−1.0095 (6)−0.5312 (5)0.0503 (15)
C1−0.1882 (5)−0.6828 (7)−0.3260 (5)0.0541 (18)
H1−0.2408−0.6608−0.30810.065*
C2−0.1206 (6)−0.6198 (7)−0.2909 (6)0.060 (2)
C3−0.1361 (7)−0.5168 (8)−0.2285 (6)0.089 (3)
H3A−0.1689−0.4576−0.25840.107*
H3B−0.0846−0.4819−0.21080.107*
H3C−0.1648−0.5449−0.17640.107*
C4−0.0441 (6)−0.6540 (9)−0.3175 (6)0.071 (2)
H40.0018−0.6146−0.29490.085*
C5−0.0340 (5)−0.7457 (9)−0.3773 (6)0.062 (2)
H50.0183−0.7674−0.39630.075*
C6−0.1031 (5)−0.8063 (7)−0.4095 (5)0.0524 (19)
C7−0.1007 (4)−0.9082 (7)−0.4741 (6)0.0459 (17)
C8−0.0275 (5)−0.9510 (8)−0.5090 (5)0.061 (2)
H80.0226−0.9168−0.49300.073*
C9−0.0309 (5)−1.0467 (9)−0.5686 (6)0.069 (3)
H90.0177−1.0773−0.59210.082*
C10−0.1045 (7)−1.0967 (8)−0.5934 (6)0.062 (3)
C11−0.1117 (7)−1.1986 (8)−0.6598 (6)0.082 (3)
H11A−0.1368−1.2664−0.63110.098*
H11B−0.0579−1.2202−0.68070.098*
H11C−0.1449−1.1739−0.70960.098*
C12−0.1746 (5)−1.0486 (7)−0.5547 (6)0.057 (2)
H12−0.2252−1.0820−0.56940.068*
C13−0.6682 (5)−1.2826 (7)−0.3606 (6)0.059 (2)
H13−0.7178−1.3166−0.34290.071*
C14−0.5966 (6)−1.3302 (9)−0.3250 (6)0.067 (2)
C15−0.5985 (7)−1.4306 (9)−0.2602 (6)0.089 (3)
H15A−0.6285−1.4068−0.20780.107*
H15B−0.5434−1.4516−0.24380.107*
H15C−0.6251−1.4985−0.28710.107*
C16−0.5243 (6)−1.2783 (9)−0.3560 (7)0.074 (3)
H16−0.4741−1.3087−0.33700.089*
C17−0.5255 (5)−1.1830 (9)−0.4141 (6)0.074 (2)
H17−0.4765−1.1473−0.43220.089*
C18−0.6005 (5)−1.1398 (8)−0.4458 (7)0.0552 (19)
C19−0.6087 (4)−1.0390 (7)−0.5074 (5)0.0501 (17)
C20−0.5433 (5)−0.9743 (9)−0.5441 (7)0.072 (3)
H20−0.4894−0.9962−0.53100.086*
C21−0.5580 (6)−0.8791 (8)−0.5990 (5)0.069 (2)
H21−0.5140−0.8339−0.61990.083*
C22−0.6369 (6)−0.8486 (7)−0.6240 (5)0.0578 (19)
C23−0.6548 (6)−0.7477 (8)−0.6847 (6)0.080 (3)
H23A−0.6848−0.7765−0.73570.096*
H23B−0.6042−0.7120−0.70420.096*
H23C−0.6871−0.6891−0.65360.096*
C24−0.6992 (5)−0.9174 (7)−0.5874 (5)0.0572 (18)
H24−0.7533−0.8990−0.60230.069*
U11U22U33U12U13U23
Zn10.0310 (4)0.0557 (5)0.0721 (10)−0.0013 (4)0.0036 (4)0.0035 (4)
Zn20.0336 (4)0.0550 (5)0.0678 (9)0.0005 (4)−0.0026 (4)−0.0006 (4)
Cl10.0615 (14)0.0871 (16)0.113 (2)0.0035 (12)0.0292 (13)0.0328 (14)
Cl20.0426 (10)0.0783 (13)0.0805 (15)0.0030 (9)−0.0096 (9)0.0048 (11)
Cl30.0490 (11)0.0682 (12)0.0759 (14)−0.0025 (9)0.0060 (9)−0.0081 (10)
Cl40.0550 (13)0.0829 (15)0.109 (2)0.0089 (11)−0.0215 (12)−0.0355 (14)
N10.038 (3)0.049 (3)0.065 (4)−0.002 (3)−0.007 (3)0.012 (3)
N20.037 (3)0.047 (3)0.069 (4)−0.003 (3)0.011 (3)0.009 (3)
N30.041 (3)0.057 (3)0.058 (4)−0.001 (3)−0.001 (3)−0.011 (3)
N40.034 (3)0.063 (4)0.055 (4)−0.002 (3)0.003 (3)−0.008 (3)
C10.045 (4)0.057 (4)0.061 (4)−0.002 (3)−0.008 (3)0.002 (3)
C20.065 (5)0.062 (5)0.053 (5)−0.006 (4)−0.016 (4)0.013 (4)
C30.135 (10)0.068 (6)0.066 (6)−0.018 (6)−0.023 (6)0.001 (4)
C40.067 (6)0.080 (6)0.066 (5)−0.028 (5)−0.016 (4)0.006 (5)
C50.035 (4)0.088 (6)0.063 (5)−0.004 (4)−0.002 (3)0.010 (5)
C60.046 (4)0.058 (4)0.054 (4)−0.010 (3)−0.005 (3)0.021 (3)
C70.027 (3)0.056 (4)0.055 (5)0.003 (3)0.007 (3)0.017 (4)
C80.046 (4)0.073 (5)0.065 (5)0.012 (4)0.008 (3)0.014 (4)
C90.051 (5)0.093 (7)0.062 (5)0.025 (5)0.021 (4)0.027 (5)
C100.081 (7)0.057 (4)0.048 (5)0.023 (5)0.013 (4)0.022 (4)
C110.102 (8)0.073 (6)0.071 (6)0.026 (5)0.017 (5)0.005 (5)
C120.041 (4)0.059 (5)0.071 (5)−0.002 (3)0.000 (3)0.017 (4)
C130.058 (5)0.056 (5)0.064 (5)0.001 (4)−0.009 (4)−0.008 (4)
C140.069 (6)0.070 (5)0.061 (5)0.029 (5)−0.013 (4)−0.019 (4)
C150.112 (9)0.082 (7)0.073 (6)0.028 (6)−0.029 (6)−0.006 (5)
C160.052 (5)0.093 (7)0.078 (6)0.032 (5)−0.014 (4)−0.013 (5)
C170.037 (4)0.098 (7)0.089 (6)0.006 (4)−0.012 (4)−0.016 (5)
C180.048 (4)0.059 (4)0.058 (5)0.008 (4)0.010 (4)−0.020 (4)
C190.033 (3)0.068 (4)0.049 (4)0.001 (3)0.002 (3)−0.018 (3)
C200.039 (4)0.098 (7)0.078 (6)−0.011 (4)0.005 (4)−0.032 (5)
C210.078 (6)0.076 (6)0.053 (5)−0.021 (5)0.005 (4)−0.006 (4)
C220.077 (6)0.054 (4)0.042 (4)−0.005 (4)0.008 (3)−0.008 (3)
C230.093 (7)0.076 (6)0.071 (6)−0.018 (5)0.013 (5)−0.007 (5)
C240.050 (4)0.066 (5)0.055 (4)0.005 (4)0.002 (3)−0.002 (4)
Zn1—Cl12.206 (2)C11—H11B0.9600
Zn1—Cl22.215 (2)C11—H11C0.9600
Zn2—Cl32.211 (2)C12—N21.338 (10)
Zn2—Cl42.207 (3)C12—H120.9300
Zn1—N12.058 (6)C13—N31.341 (10)
Zn1—N22.057 (6)C13—C141.386 (11)
Zn2—N32.063 (6)C13—H130.9300
Zn2—N42.066 (6)C14—C161.389 (13)
C1—N11.339 (10)C14—C151.482 (13)
C1—C21.406 (12)C15—H15A0.9600
C1—H10.9300C15—H15B0.9600
C2—C41.362 (14)C15—H15C0.9600
C2—C31.502 (12)C16—C171.374 (13)
C3—H3A0.9600C16—H160.9300
C3—H3B0.9600C17—C181.397 (11)
C3—H3C0.9600C17—H170.9300
C4—C51.369 (13)C18—N31.343 (10)
C4—H40.9300C18—C191.460 (12)
C5—C61.396 (11)C19—N41.341 (9)
C5—H50.9300C19—C201.397 (11)
C6—N11.357 (10)C20—C211.364 (13)
C6—C71.491 (11)C20—H200.9300
C7—N21.339 (9)C21—C221.379 (14)
C7—C81.387 (10)C21—H210.9300
C8—C91.392 (12)C22—C241.384 (12)
C8—H80.9300C22—C231.476 (12)
C9—C101.372 (14)C23—H23A0.9600
C9—H90.9300C23—H23B0.9600
C10—C121.386 (13)C23—H23C0.9600
C10—C111.514 (13)C24—N41.348 (10)
C11—H11A0.9600C24—H240.9300
N1—Zn1—N280.5 (2)N3—C13—C14124.8 (8)
N1—Zn1—Cl1112.2 (2)N3—C13—H13117.6
N1—Zn1—Cl2117.23 (18)C14—C13—H13117.6
N2—Zn1—Cl1115.64 (18)C13—C14—C16115.0 (9)
N2—Zn1—Cl2111.4 (2)C13—C14—C15121.6 (9)
Cl1—Zn1—Cl2115.28 (10)C16—C14—C15123.4 (9)
N3—Zn2—N479.7 (3)C14—C15—H15A109.4
N3—Zn2—Cl3112.09 (18)C14—C15—H15B109.5
N3—Zn2—Cl4114.47 (17)H15A—C15—H15B109.5
N4—Zn2—Cl4112.8 (2)C14—C15—H15C109.5
N4—Zn2—Cl3115.01 (18)H15A—C15—H15C109.5
Cl4—Zn2—Cl3117.19 (9)H15B—C15—H15C109.5
N1—C1—C2122.6 (8)C17—C16—C14121.4 (8)
N1—C1—H1118.7C17—C16—H16119.3
C2—C1—H1118.7C14—C16—H16119.3
C4—C2—C1117.7 (8)C16—C17—C18119.6 (9)
C4—C2—C3123.4 (9)C16—C17—H17120.2
C1—C2—C3118.9 (9)C18—C17—H17120.2
C2—C3—H3A109.5N3—C18—C17119.7 (9)
C2—C3—H3B109.5N3—C18—C19116.2 (7)
H3A—C3—H3B109.5C17—C18—C19124.1 (8)
C2—C3—H3C109.5N4—C19—C20118.6 (8)
H3A—C3—H3C109.5N4—C19—C18116.2 (7)
H3B—C3—H3C109.5C20—C19—C18125.2 (8)
C2—C4—C5120.8 (8)C21—C20—C19120.3 (9)
C2—C4—H4119.6C21—C20—H20119.9
C5—C4—H4119.6C19—C20—H20119.9
C4—C5—C6119.4 (8)C20—C21—C22121.4 (9)
C4—C5—H5120.3C20—C21—H21119.3
C6—C5—H5120.3C22—C21—H21119.3
N1—C6—C5120.8 (8)C21—C22—C24115.9 (8)
N1—C6—C7114.4 (7)C21—C22—C23122.7 (9)
C5—C6—C7124.8 (8)C24—C22—C23121.3 (9)
N2—C7—C8121.1 (8)C22—C23—H23A109.5
N2—C7—C6116.9 (7)C22—C23—H23B109.5
C8—C7—C6122.0 (8)H23A—C23—H23B109.5
C7—C8—C9118.2 (8)C22—C23—H23C109.5
C7—C8—H8120.9H23A—C23—H23C109.5
C9—C8—H8120.9H23B—C23—H23C109.5
C10—C9—C8121.3 (8)N4—C24—C22123.2 (8)
C10—C9—H9119.4N4—C24—H24118.4
C8—C9—H9119.4C22—C24—H24118.4
C9—C10—C12116.6 (9)C1—N1—C6118.8 (7)
C9—C10—C11123.3 (9)C1—N1—Zn1126.7 (5)
C12—C10—C11120.2 (10)C6—N1—Zn1114.5 (5)
C10—C11—H11A109.4C12—N2—C7119.4 (7)
C10—C11—H11B109.5C12—N2—Zn1126.8 (5)
H11A—C11—H11B109.5C7—N2—Zn1113.8 (5)
C10—C11—H11C109.5C13—N3—C18119.4 (7)
H11A—C11—H11C109.5C13—N3—Zn2126.6 (5)
H11B—C11—H11C109.5C18—N3—Zn2114.0 (6)
N2—C12—C10123.4 (8)C19—N4—C24120.5 (7)
N2—C12—H12118.3C19—N4—Zn2114.0 (5)
C10—C12—H12118.3C24—N4—Zn2125.5 (5)
N1—C1—C2—C4−0.3 (13)N2—Zn1—N1—C1−179.1 (6)
N1—C1—C2—C3177.9 (7)Cl1—Zn1—N1—C1−65.2 (7)
C1—C2—C4—C50.8 (13)Cl2—Zn1—N1—C171.6 (7)
C3—C2—C4—C5−177.4 (9)N2—Zn1—N1—C6−1.4 (5)
C2—C4—C5—C6−1.5 (14)Cl1—Zn1—N1—C6112.5 (5)
C4—C5—C6—N11.7 (12)Cl2—Zn1—N1—C6−110.7 (5)
C4—C5—C6—C7−179.5 (8)C10—C12—N2—C7−1.2 (12)
N1—C6—C7—N2−1.5 (9)C10—C12—N2—Zn1178.9 (6)
C5—C6—C7—N2179.6 (8)C8—C7—N2—C120.8 (12)
N1—C6—C7—C8178.1 (7)C6—C7—N2—C12−179.6 (6)
C5—C6—C7—C8−0.8 (11)C8—C7—N2—Zn1−179.3 (6)
N2—C7—C8—C9−0.6 (12)C6—C7—N2—Zn10.3 (9)
C6—C7—C8—C9179.8 (7)N1—Zn1—N2—C12−179.6 (7)
C7—C8—C9—C100.8 (13)Cl1—Zn1—N2—C1270.3 (7)
C8—C9—C10—C12−1.2 (12)Cl2—Zn1—N2—C12−64.0 (7)
C8—C9—C10—C11178.3 (8)N1—Zn1—N2—C70.5 (6)
C9—C10—C12—N21.4 (12)Cl1—Zn1—N2—C7−109.6 (5)
C11—C10—C12—N2−178.1 (8)Cl2—Zn1—N2—C7116.2 (6)
N3—C13—C14—C16−1.8 (12)C14—C13—N3—C18−0.1 (12)
N3—C13—C14—C15179.3 (8)C14—C13—N3—Zn2−178.1 (6)
C13—C14—C16—C173.1 (13)C17—C18—N3—C130.8 (13)
C15—C14—C16—C17−178.1 (9)C19—C18—N3—C13−178.5 (7)
C14—C16—C17—C18−2.6 (15)C17—C18—N3—Zn2179.0 (7)
C16—C17—C18—N30.5 (15)C19—C18—N3—Zn2−0.3 (10)
C16—C17—C18—C19179.8 (8)N4—Zn2—N3—C13178.9 (7)
N3—C18—C19—N4−0.8 (11)Cl4—Zn2—N3—C13−70.6 (7)
C17—C18—C19—N4179.9 (8)Cl3—Zn2—N3—C1366.0 (6)
N3—C18—C19—C20−179.3 (7)N4—Zn2—N3—C180.8 (6)
C17—C18—C19—C201.4 (14)Cl4—Zn2—N3—C18111.3 (6)
N4—C19—C20—C213.6 (12)Cl3—Zn2—N3—C18−112.1 (6)
C18—C19—C20—C21−178.0 (8)C20—C19—N4—C24−1.7 (10)
C19—C20—C21—C22−4.0 (13)C18—C19—N4—C24179.7 (7)
C20—C21—C22—C242.4 (12)C20—C19—N4—Zn2−179.9 (6)
C20—C21—C22—C23−178.8 (8)C18—C19—N4—Zn21.5 (8)
C21—C22—C24—N4−0.5 (11)C22—C24—N4—C190.3 (11)
C23—C22—C24—N4−179.4 (7)C22—C24—N4—Zn2178.3 (5)
C2—C1—N1—C60.5 (11)N3—Zn2—N4—C19−1.3 (5)
C2—C1—N1—Zn1178.2 (6)Cl4—Zn2—N4—C19−113.6 (5)
C5—C6—N1—C1−1.2 (10)Cl3—Zn2—N4—C19108.4 (5)
C7—C6—N1—C1179.8 (6)N3—Zn2—N4—C24−179.4 (6)
C5—C6—N1—Zn1−179.1 (6)Cl4—Zn2—N4—C2468.3 (6)
C7—C6—N1—Zn11.9 (7)Cl3—Zn2—N4—C24−69.7 (6)
D—H···AD—HH···AD···AD—H···A
C1—H1···Cl3i0.932.823.516 (8)132
C16—H16···Cl3ii0.932.833.638 (10)146
C3—H3A···Cg50.963.103.719 (6)124
C11—H11A···Cg2iii0.962.833.688 (5)150
C15—H15C···Cg1iv0.962.843.704 (6)150
C23—H23C···Cg40.963.113.690 (6)120
Zn1—Cl12.206 (2)
Zn1—Cl22.215 (2)
Zn2—Cl32.211 (2)
Zn2—Cl42.207 (3)
Zn1—N12.058 (6)
Zn1—N22.057 (6)
Zn2—N32.063 (6)
Zn2—N42.066 (6)
N1—Zn1—N280.5 (2)
N1—Zn1—Cl1112.2 (2)
N1—Zn1—Cl2117.23 (18)
N2—Zn1—Cl1115.64 (18)
N2—Zn1—Cl2111.4 (2)
Cl1—Zn1—Cl2115.28 (10)
N3—Zn2—N479.7 (3)
N3—Zn2—Cl3112.09 (18)
N3—Zn2—Cl4114.47 (17)
N4—Zn2—Cl4112.8 (2)
N4—Zn2—Cl3115.01 (18)
Cl4—Zn2—Cl3117.19 (9)
Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯AD—HH⋯AD⋯AD—H⋯A
C1—H1⋯Cl3i0.932.823.516 (8)132
C16—H16⋯Cl3ii0.932.833.638 (10)146
C3—H3A⋯Cg50.963.103.719 (6)124
C11—H11A⋯Cg2iii0.962.833.688 (5)150
C15—H15C⋯Cg1iv0.962.843.704 (6)150
C23—H23C⋯Cg40.963.113.690 (6)120

Symmetry codes: (i) ; (ii) ; (iii) ; (iv) . Cg1, Cg2, Cg4 and Cg5 are the centroids of atoms Zn1/N1/C6/C7/N2, N1/C1/C2/C4–C6, Zn2/N3/C18/C19/N4 and N3/C13/C14/C16–C18, respectively.

  3 in total

1.  A short history of SHELX.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A       Date:  2007-12-21       Impact factor: 2.290

2.  The crystal structure of di-imidazole-zinc (II) dichloride.

Authors:  B K Lundberg
Journal:  Acta Crystallogr       Date:  1966-12-10

3.  Blue phosphorescent Zn(II) and orange phosphorescent Pt(II) complexes of 4,4'-diphenyl-6,6'-dimethyl-2,2'-bipyrimidine.

Authors:  Qin-De Liu; Ruiyao Wang; Suning Wang
Journal:  Dalton Trans       Date:  2004-06-09       Impact factor: 4.390
  3 in total
  19 in total

1.  5,5'-Dimethyl-2,2'-bipyridine.

Authors:  Zeinab Khoshtarkib; Amin Ebadi; Roya Ahmadi; Robabeh Alizadeh
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-06-17

2.  Di-μ-bromido-bis-[bromido(4,4'-dimethyl-2,2'-bipyridine-κN,N')mercury(II)].

Authors:  Khadijeh Kalateh; Amin Ebadi; Roya Ahmadi; Vahid Amani; Hamid Reza Khavasi
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-10-15

3.  Trichlorido(4,4'-dimethyl-2,2'-bipyridine-κN,N')(dimethyl sulfoxide-κO)indium(III).

Authors:  Roya Ahmadi; Khadijeh Kalateh; Anita Abedi; Vahid Amani; Hamid Reza Khavasi
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-09-20

4.  Trichlorido(5,5'-dimethyl-2,2'-bipyridine-κN,N')(methanol-κO)indium(III).

Authors:  Khadijeh Kalateh; Roya Ahmadi; Amin Ebadi; Vahid Amani; Hamid Reza Khavasi
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-10-04

5.  catena-Poly[[(5,5'-dimethyl- 2,2'-bipyridine-κN,N')cadmium(II)]-di-μ-chlorido].

Authors:  Roya Ahmadi; Aida Khalighi; Khadijeh Kalateh; Vahid Amani; Hamid Reza Khavasi
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-09-06

6.  (4,7-Diphenyl-1,10-phenanthroline-κN,N')diiodidomercury(II).

Authors:  Mohammad Yousefi; Rabin Rashidi Vahid; Vahid Amani; Mansour Arab Chamjangali; Hamid Reza Khavasi
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-09-27

7.  Dibromido(6,6'-dimethyl-2,2'-bipyridine-κN,N')zinc(II).

Authors:  Robabeh Alizadeh; Zeinab Khoshtarkib; Katayoon Chegeni; Amin Ebadi; Vahid Amani
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-10-07

8.  Dichlorido(6-methyl-2,2'-bipyridine-κN,N')mercury(II).

Authors:  Roya Ahmadi; Amin Ebadi; Khadijeh Kalateh; Ali Norouzi; Vahid Amani
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-10-15

9.  catena-Poly[[(5,5'-dimethyl-2,2'-bi-pyridine-κN,N')cadmium(II)]-di-μ-iodido].

Authors:  Roya Ahmadi; Khadijeh Kalateh; Vahid Amani
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-04-24

10.  Trichlorido(5,5'-dimethyl-2,2'-bipyridine-κ(2) N,N')(dimethyl-formamide-κO)indium(III) hemihydrate.

Authors:  Sadif A Shirvan; Sara Haydari Dezfuli; Fereydoon Khazali; Manouchehr Aghajeri; Ali Borsalani
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-11-03
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