2-(1H-Benzotriazol-1-yl)acetohydrazide.

The title compound, C(8)H(9)N(5)O, was synthesized by the reaction of ethyl 2-(benzotriazol-1-yl)acetate with hydrazine hydrate in ethanol. In the amide group, the C-N bond is relatively short [1.3283 (16) Å], suggesting some degree of electronic delocalization in the mol-ecule. In the crystal structure, mol-ecules are linked into infinite chains along the a axis by inter-molecular O-H⋯N hydrogen bonding.

Related literature

For general background to multiple-hydrogen-bonding N-heterocyclic systems as potential supra­molecular reagents, see: Portalone (2007 ▶); Portalone & Colapietro (2007 ▶, 2008 ▶); For related structures, see: Shi et al. (2007a ▶,b ▶); Ji et al. (2008 ▶); For bond-length data, see: Allen et al. (1987 ▶).

Experimental

Crystal data

C8H9N5O

M = 191.20

Monoclinic,

a = 5.1434 (9) Å

b = 6.5885 (12) Å

c = 25.754 (5) Å

β = 94.227 (3)°

V = 870.4 (3) Å3

Z = 4

Mo Kα radiation

μ = 0.11 mm−1

T = 295 K

0.12 × 0.10 × 0.06 mm

Data collection

Bruker APEXII CCD area-detector diffractometer

Absorption correction: multi-scan (SADABS; Bruker, 2005 ▶) T min = 0.988, T max = 0.994

4367 measured reflections

1528 independent reflections

1364 reflections with I > 2σ(I)

R int = 0.015

Refinement

R[F 2 > 2σ(F 2)] = 0.030

wR(F 2) = 0.079

S = 1.04

1528 reflections

135 parameters

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.13 e Å−3

Δρmin = −0.15 e Å−3

Data collection: APEX2 (Bruker, 2005 ▶); cell refinement: SAINT (Bruker, 2005 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809021199/bg2267sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809021199/bg2267Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C8H9N5O	F(000) = 400
Mr = 191.20	Dx = 1.459 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 2593 reflections
a = 5.1434 (9) Å	θ = 2.4–28.0°
b = 6.5885 (12) Å	µ = 0.11 mm−1
c = 25.754 (5) Å	T = 295 K
β = 94.227 (3)°	Block, colorless
V = 870.4 (3) Å3	0.12 × 0.10 × 0.06 mm
Z = 4

Bruker APEXII CCD area-detector diffractometer	1528 independent reflections
Radiation source: fine-focus sealed tube	1364 reflections with I > 2σ(I)
graphite	Rint = 0.015
φ and ω scans	θmax = 25.1°, θmin = 3.2°
Absorption correction: multi-scan (SADABS; Bruker, 2005)	h = −4→6
Tmin = 0.988, Tmax = 0.994	k = −7→7
4367 measured reflections	l = −28→30

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.030	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.079	H atoms treated by a mixture of independent and constrained refinement
S = 1.04	w = 1/[σ2(Fo2) + (0.0333P)2 + 0.233P] where P = (Fo2 + 2Fc2)/3
1528 reflections	(Δ/σ)max < 0.001
135 parameters	Δρmax = 0.13 e Å−3
0 restraints	Δρmin = −0.15 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
O1	1.08675 (16)	0.24854 (14)	0.01128 (4)	0.0432 (3)
N1	1.3431 (2)	0.14371 (19)	0.16751 (5)	0.0505 (3)
N2	1.2038 (2)	0.05513 (19)	0.12958 (5)	0.0496 (3)
N3	0.9953 (2)	0.17411 (18)	0.11547 (4)	0.0422 (3)
N4	0.65313 (19)	0.25384 (17)	−0.00905 (4)	0.0419 (3)
H1	0.5024	0.2240	0.0012	0.050*
N5	0.6667 (2)	0.3428 (2)	−0.05866 (5)	0.0503 (3)
C1	1.2246 (2)	0.3253 (2)	0.17817 (5)	0.0406 (3)
C2	1.2914 (3)	0.4759 (2)	0.21540 (5)	0.0496 (4)
H2	1.4385	0.4637	0.2384	0.060*
C3	1.1312 (3)	0.6408 (2)	0.21632 (6)	0.0537 (4)
H3	1.1698	0.7424	0.2407	0.064*
C4	0.9094 (3)	0.6612 (2)	0.18138 (6)	0.0534 (4)
H4	0.8067	0.7768	0.1832	0.064*
C5	0.8397 (3)	0.5166 (2)	0.14492 (5)	0.0466 (3)
H5	0.6933	0.5306	0.1218	0.056*
C6	1.0018 (2)	0.3468 (2)	0.14460 (5)	0.0377 (3)
C7	0.8079 (3)	0.1139 (2)	0.07360 (5)	0.0460 (3)
H7A	0.6341	0.1507	0.0825	0.055*
H7B	0.8133	−0.0323	0.0695	0.055*
C8	0.8630 (2)	0.21429 (19)	0.02251 (5)	0.0356 (3)
H9	0.723 (3)	0.250 (2)	−0.0799 (6)	0.073 (6)*
H8	0.785 (3)	0.441 (2)	−0.0551 (8)	0.078 (6)*

	U11	U22	U33	U12	U13	U23
O1	0.0277 (5)	0.0555 (6)	0.0466 (5)	−0.0038 (4)	0.0045 (4)	−0.0023 (4)
N1	0.0450 (7)	0.0599 (8)	0.0460 (7)	0.0030 (6)	−0.0010 (5)	0.0029 (6)
N2	0.0472 (7)	0.0518 (7)	0.0500 (7)	0.0030 (6)	0.0051 (5)	0.0005 (6)
N3	0.0399 (6)	0.0508 (7)	0.0358 (6)	−0.0038 (5)	0.0024 (5)	−0.0031 (5)
N4	0.0272 (5)	0.0526 (7)	0.0457 (6)	−0.0030 (5)	0.0021 (4)	−0.0043 (5)
N5	0.0434 (7)	0.0582 (8)	0.0483 (7)	0.0013 (6)	−0.0040 (6)	0.0003 (6)
C1	0.0351 (7)	0.0530 (8)	0.0342 (7)	−0.0047 (6)	0.0054 (5)	0.0039 (6)
C2	0.0394 (7)	0.0720 (10)	0.0372 (7)	−0.0136 (7)	0.0009 (6)	−0.0029 (7)
C3	0.0515 (9)	0.0611 (10)	0.0497 (9)	−0.0159 (7)	0.0114 (7)	−0.0143 (7)
C4	0.0499 (9)	0.0521 (9)	0.0598 (9)	−0.0013 (7)	0.0145 (7)	−0.0043 (7)
C5	0.0382 (7)	0.0574 (9)	0.0441 (8)	−0.0003 (6)	0.0025 (6)	0.0020 (7)
C6	0.0346 (7)	0.0484 (8)	0.0303 (6)	−0.0061 (6)	0.0053 (5)	0.0010 (6)
C7	0.0387 (7)	0.0582 (9)	0.0412 (7)	−0.0125 (6)	0.0044 (6)	−0.0072 (6)
C8	0.0292 (6)	0.0384 (7)	0.0392 (7)	−0.0035 (5)	0.0027 (5)	−0.0110 (5)

O1—C8	1.2280 (14)	C1—C2	1.405 (2)
N1—N2	1.3057 (16)	C2—C3	1.365 (2)
N1—C1	1.3795 (19)	C2—H2	0.9300
N2—N3	1.3559 (16)	C3—C4	1.407 (2)
N3—C6	1.3620 (17)	C3—H3	0.9300
N3—C7	1.4478 (16)	C4—C5	1.367 (2)
N4—C8	1.3283 (16)	C4—H4	0.9300
N4—N5	1.4120 (17)	C5—C6	1.3957 (19)
N4—H1	0.8600	C5—H5	0.9300
N5—H9	0.884 (9)	C7—C8	1.5179 (18)
N5—H8	0.888 (9)	C7—H7A	0.9700
C1—C6	1.3909 (18)	C7—H7B	0.9700
N2—N1—C1	108.09 (11)	C4—C3—H3	119.1
N1—N2—N3	108.75 (11)	C5—C4—C3	122.15 (14)
N2—N3—C6	110.41 (10)	C5—C4—H4	118.9
N2—N3—C7	120.74 (12)	C3—C4—H4	118.9
C6—N3—C7	128.83 (12)	C4—C5—C6	115.87 (13)
C8—N4—N5	122.88 (10)	C4—C5—H5	122.1
C8—N4—H1	118.6	C6—C5—H5	122.1
N5—N4—H1	118.6	N3—C6—C1	104.05 (11)
N4—N5—H9	108.2 (12)	N3—C6—C5	133.05 (12)
N4—N5—H8	106.8 (13)	C1—C6—C5	122.90 (12)
H9—N5—H8	108.4 (17)	N3—C7—C8	111.69 (10)
N1—C1—C6	108.69 (12)	N3—C7—H7A	109.3
N1—C1—C2	131.22 (13)	C8—C7—H7A	109.3
C6—C1—C2	120.08 (13)	N3—C7—H7B	109.3
C3—C2—C1	117.16 (13)	C8—C7—H7B	109.3
C3—C2—H2	121.4	H7A—C7—H7B	107.9
C1—C2—H2	121.4	O1—C8—N4	123.60 (12)
C2—C3—C4	121.83 (14)	O1—C8—C7	121.49 (11)
C2—C3—H3	119.1	N4—C8—C7	114.87 (10)
C1—N1—N2—N3	−0.50 (14)	C7—N3—C6—C5	0.5 (2)
N1—N2—N3—C6	0.98 (15)	N1—C1—C6—N3	0.71 (13)
N1—N2—N3—C7	179.30 (11)	C2—C1—C6—N3	−178.58 (12)
N2—N1—C1—C6	−0.15 (14)	N1—C1—C6—C5	−179.03 (12)
N2—N1—C1—C2	179.04 (14)	C2—C1—C6—C5	1.68 (19)
N1—C1—C2—C3	−179.77 (14)	C4—C5—C6—N3	178.92 (13)
C6—C1—C2—C3	−0.66 (19)	C4—C5—C6—C1	−1.43 (19)
C1—C2—C3—C4	−0.5 (2)	N2—N3—C7—C8	−97.25 (14)
C2—C3—C4—C5	0.7 (2)	C6—N3—C7—C8	80.72 (16)
C3—C4—C5—C6	0.2 (2)	N5—N4—C8—O1	−1.0 (2)
N2—N3—C6—C1	−1.02 (13)	N5—N4—C8—C7	−178.60 (12)
C7—N3—C6—C1	−179.17 (12)	N3—C7—C8—O1	34.61 (18)
N2—N3—C6—C5	178.67 (14)	N3—C7—C8—N4	−147.76 (12)

D—H···A	D—H	H···A	D···A	D—H···A
N4—H1···O1i	0.86	2.18	2.9977 (14)	159

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N4—H1⋯O1i	0.86	2.18	2.9977 (14)	159

Symmetry code: (i) .