Literature DB >> 21582213

3-(2-Acetamido-phen-yl)sydnone.

David A Grossie1, Kenneth Turnbull, Sandra Felix-Balderrama, Shravanthi Raghavapuram.   

Abstract

Sydnones are unusual mesoionic compounds containing a five-membered heterocyclic ring. Generally for stability, substitution at the N-3 position by an aromatic fragment is necessary. In the title compound, C(10)H(9)N(3)O(3), the aromatic substitutent is 2-acetamido-phenyl. The two planar ring fragments are twisted relative to one another, with a inter-planar angle of 63.13 (5)°. The mol-ecules are packed into the unit cell via π-π inter-actions between the phenyl rings [inter-planar separation = 3.4182 (4) Å] and between the sydnone rings [inter-planar separation = 3.2095 (4) Å]. N-H⋯O and C-H⋯O hydrogen bonding is also found inter-nally and externally to the mol-ecule.

Entities:  

Year:  2009        PMID: 21582213      PMCID: PMC2968512          DOI: 10.1107/S1600536809005066

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


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2.  4-Formyl-3-p-tolyl-sydnone.

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Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2010-05-08
  2 in total

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