(2,2'-Bipyrid-yl)bis-[N-(2-hydroxy-ethyl)-N-n-propyl-dithio-carbamato-κS,S']cadmium(II) acetonitrile solvate.

The title complex, [Cd(C(6)H(12)NOS(2))(2)(C(10)H(8)N(2))]·CH(3)CN, features a distorted octa-hedral N(2)S(4) geometry for the Cd(II) centre defined by a pair of asymmetrically chelating dithio-carbamate ligands as well as a 2,2'-bipyridine ligand. Supra-molecular chains along [001] are formed in the crystal structure, mediated by O-H⋯S hydrogen bonds; the acetonitrile solvent mol-ecules are associated with the chains via O-H⋯N hydrogen bonds.

Related literature

For background to supra­molecular polymers of zinc-triad 1,1-dithiol­ates, see: Tiekink (2003 ▶); Lai et al. (2002 ▶); Chen et al. (2006 ▶); Benson et al. (2007 ▶). For the synthesis, see: Lai & Tiekink (2004 ▶).

Experimental

Crystal data

[Cd(C6H12NOS2)2(C10H8N2)]·C2H3N

M = 666.21

Monoclinic,

a = 7.3277 (7) Å

b = 23.822 (2) Å

c = 17.1159 (18) Å

β = 99.786 (1)°

V = 2944.2 (5) Å3

Z = 4

Mo Kα radiation

μ = 1.06 mm−1

T = 98 K

0.36 × 0.22 × 0.11 mm

Data collection

Rigaku AFC12K/SATURN724 diffractometer

Absorption correction: multi-scan (ABSCOR; Higashi, 1995 ▶) T min = 0.828, T max = 1

18201 measured reflections

6043 independent reflections

5711 reflections with I > 2σ(I)

R int = 0.027

Refinement

R[F 2 > 2σ(F 2)] = 0.030

wR(F 2) = 0.080

S = 1.09

6043 reflections

331 parameters

2 restraints

H-atom parameters constrained

Δρmax = 0.70 e Å−3

Δρmin = −0.69 e Å−3

Data collection: CrystalClear (Rigaku/MSC, 2005 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: PATTY in DIRDIF92 (Beurskens et al., 1992 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEPII (Johnson, 1976 ▶) and DIAMOND (Brandenburg, 2006 ▶); software used to prepare material for publication: publCIF (Westrip, 2009 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809049666/hb5240sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809049666/hb5240Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cd(C6H12NOS2)2(C10H8N2)]·C2H3N	F(000) = 1368
Mr = 666.21	Dx = 1.503 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71069 Å
Hall symbol: -P 2ybc	Cell parameters from 18141 reflections
a = 7.3277 (7) Å	θ = 2.1–40.6°
b = 23.822 (2) Å	µ = 1.06 mm−1
c = 17.1159 (18) Å	T = 98 K
β = 99.786 (1)°	Block, colourless
V = 2944.2 (5) Å3	0.36 × 0.22 × 0.11 mm
Z = 4

Rigaku AFC12K/SATURN724 diffractometer	6043 independent reflections
Radiation source: fine-focus sealed tube	5711 reflections with I > 2σ(I)
graphite	Rint = 0.027
ω scans	θmax = 26.5°, θmin = 2.1°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −9→9
Tmin = 0.828, Tmax = 1	k = −25→29
18201 measured reflections	l = −21→21

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.030	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.080	H-atom parameters constrained
S = 1.09	w = 1/[σ2(Fo2) + (0.0396P)2 + 3.165P] where P = (Fo2 + 2Fc2)/3
6043 reflections	(Δ/σ)max = 0.004
331 parameters	Δρmax = 0.70 e Å−3
2 restraints	Δρmin = −0.69 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cd	0.22264 (2)	0.757722 (7)	0.046853 (9)	0.01758 (7)
S1	0.17585 (8)	0.85953 (3)	0.09227 (3)	0.01984 (13)
S2	0.54757 (9)	0.82033 (3)	0.06550 (4)	0.02253 (13)
S3	0.35255 (9)	0.69177 (3)	0.16861 (4)	0.02338 (14)
S4	−0.04308 (9)	0.69484 (3)	0.09167 (3)	0.02234 (13)
O1	0.7384 (3)	0.95516 (8)	0.26074 (11)	0.0274 (4)
H1O	0.8084	0.9465	0.3031	0.041*
O2	0.4126 (3)	0.60342 (9)	0.39861 (11)	0.0356 (5)
H2O	0.4471	0.6205	0.4415	0.053*
N1	0.4822 (3)	0.92222 (9)	0.11936 (11)	0.0184 (4)
N2	0.0887 (3)	0.62810 (9)	0.21271 (12)	0.0215 (4)
N3	0.3447 (3)	0.70592 (9)	−0.04998 (12)	0.0205 (4)
N4	0.0208 (3)	0.76057 (8)	−0.07961 (12)	0.0177 (4)
N5	0.9711 (4)	0.93255 (13)	0.41198 (16)	0.0471 (8)
C1	0.4102 (3)	0.87219 (10)	0.09512 (13)	0.0183 (5)
C2	0.6792 (3)	0.93562 (11)	0.12198 (14)	0.0212 (5)
H2A	0.6918	0.9762	0.1116	0.025*
H2B	0.7258	0.9146	0.0795	0.025*
C3	0.7967 (4)	0.92111 (12)	0.20105 (15)	0.0250 (5)
H3A	0.7818	0.8809	0.2132	0.030*
H3B	0.9290	0.9282	0.1991	0.030*
C4	0.3645 (3)	0.96886 (10)	0.13808 (13)	0.0195 (5)
H4A	0.4397	0.9948	0.1758	0.023*
H4B	0.2640	0.9538	0.1640	0.023*
C5	0.2802 (4)	1.00116 (11)	0.06364 (14)	0.0218 (5)
H5A	0.3806	1.0175	0.0388	0.026*
H5B	0.2086	0.9750	0.0251	0.026*
C6	0.1535 (4)	1.04789 (12)	0.08326 (16)	0.0263 (5)
H6A	0.1014	1.0680	0.0346	0.039*
H6B	0.2248	1.0741	0.1207	0.039*
H6C	0.0530	1.0317	0.1071	0.039*
C7	0.1289 (3)	0.66779 (11)	0.16308 (14)	0.0198 (5)
C8	0.2339 (4)	0.60092 (11)	0.27098 (14)	0.0227 (5)
H8A	0.3515	0.6003	0.2498	0.027*
H8B	0.1977	0.5616	0.2792	0.027*
C9	0.2634 (4)	0.63157 (12)	0.34969 (14)	0.0241 (5)
H9A	0.2952	0.6714	0.3424	0.029*
H9B	0.1500	0.6300	0.3739	0.029*
C10	−0.1000 (4)	0.60685 (11)	0.21058 (15)	0.0232 (5)
H10A	−0.1895	0.6373	0.1930	0.028*
H10B	−0.1155	0.5956	0.2648	0.028*
C11	−0.1435 (4)	0.55671 (12)	0.15499 (17)	0.0293 (6)
H11A	−0.1319	0.5680	0.1004	0.035*
H11B	−0.0530	0.5264	0.1717	0.035*
C12	−0.3363 (4)	0.53524 (15)	0.15584 (18)	0.0370 (7)
H12A	−0.3612	0.5032	0.1198	0.056*
H12B	−0.4261	0.5651	0.1386	0.056*
H12C	−0.3472	0.5235	0.2097	0.056*
C13	−0.1430 (3)	0.78695 (11)	−0.09045 (15)	0.0223 (5)
H13	−0.1766	0.8074	−0.0474	0.027*
C14	−0.2656 (4)	0.78577 (12)	−0.16151 (16)	0.0267 (6)
H14	−0.3805	0.8051	−0.1672	0.032*
C15	−0.2165 (4)	0.75569 (11)	−0.22421 (16)	0.0267 (6)
H15	−0.2978	0.7540	−0.2737	0.032*
C16	−0.0475 (4)	0.72821 (11)	−0.21382 (14)	0.0230 (5)
H16	−0.0107	0.7078	−0.2562	0.028*
C17	0.0676 (3)	0.73098 (10)	−0.14026 (14)	0.0179 (5)
C18	0.2499 (3)	0.70174 (10)	−0.12429 (14)	0.0193 (5)
C19	0.5105 (4)	0.68052 (12)	−0.03162 (16)	0.0274 (6)
H19	0.5775	0.6842	0.0207	0.033*
C20	0.5869 (4)	0.64932 (13)	−0.08592 (18)	0.0342 (6)
H20	0.7039	0.6316	−0.0714	0.041*
C21	0.4884 (4)	0.64455 (14)	−0.16209 (18)	0.0370 (7)
H21	0.5371	0.6231	−0.2006	0.044*
C22	0.3192 (4)	0.67099 (12)	−0.18219 (16)	0.0286 (6)
H22	0.2511	0.6683	−0.2345	0.034*
C23	1.0929 (4)	0.93296 (12)	0.46333 (17)	0.0319 (6)
C24	1.2471 (4)	0.93447 (15)	0.52810 (18)	0.0371 (7)
H24A	1.2018	0.9298	0.5784	0.056*
H24B	1.3111	0.9706	0.5280	0.056*
H24C	1.3333	0.9040	0.5219	0.056*

	U11	U22	U33	U12	U13	U23
Cd	0.01970 (10)	0.01859 (11)	0.01415 (10)	−0.00001 (6)	0.00205 (7)	−0.00045 (6)
S1	0.0183 (3)	0.0203 (3)	0.0206 (3)	0.0005 (2)	0.0026 (2)	−0.0025 (2)
S2	0.0221 (3)	0.0212 (3)	0.0254 (3)	0.0018 (2)	0.0072 (2)	−0.0035 (2)
S3	0.0212 (3)	0.0273 (3)	0.0199 (3)	−0.0013 (2)	−0.0016 (2)	0.0036 (2)
S4	0.0203 (3)	0.0270 (3)	0.0190 (3)	−0.0008 (2)	0.0012 (2)	0.0055 (2)
O1	0.0331 (11)	0.0274 (10)	0.0200 (9)	−0.0029 (8)	−0.0002 (7)	−0.0002 (7)
O2	0.0453 (12)	0.0394 (12)	0.0185 (9)	0.0197 (10)	−0.0048 (8)	−0.0023 (8)
N1	0.0191 (10)	0.0201 (11)	0.0160 (9)	0.0003 (8)	0.0036 (7)	−0.0002 (7)
N2	0.0249 (11)	0.0221 (11)	0.0173 (10)	0.0020 (8)	0.0032 (8)	0.0022 (8)
N3	0.0193 (10)	0.0221 (11)	0.0201 (10)	−0.0003 (8)	0.0033 (8)	−0.0016 (8)
N4	0.0209 (10)	0.0146 (10)	0.0177 (10)	0.0002 (8)	0.0035 (8)	0.0016 (7)
N5	0.0482 (17)	0.0513 (18)	0.0362 (14)	−0.0215 (14)	−0.0089 (12)	0.0155 (12)
C1	0.0203 (12)	0.0222 (13)	0.0122 (10)	0.0008 (9)	0.0025 (8)	0.0015 (8)
C2	0.0206 (12)	0.0237 (13)	0.0200 (11)	−0.0041 (10)	0.0058 (9)	0.0008 (9)
C3	0.0217 (13)	0.0285 (14)	0.0244 (13)	−0.0020 (10)	0.0030 (10)	0.0030 (10)
C4	0.0222 (12)	0.0192 (12)	0.0174 (11)	−0.0006 (9)	0.0042 (9)	−0.0033 (9)
C5	0.0239 (12)	0.0223 (13)	0.0190 (11)	0.0004 (10)	0.0034 (9)	−0.0016 (9)
C6	0.0260 (13)	0.0255 (14)	0.0287 (13)	0.0059 (10)	0.0082 (10)	0.0010 (10)
C7	0.0228 (12)	0.0204 (13)	0.0161 (11)	0.0012 (9)	0.0036 (9)	−0.0015 (9)
C8	0.0297 (13)	0.0191 (13)	0.0191 (11)	0.0073 (10)	0.0041 (10)	0.0011 (9)
C9	0.0288 (13)	0.0252 (14)	0.0184 (11)	0.0071 (10)	0.0042 (10)	0.0003 (9)
C10	0.0273 (13)	0.0235 (13)	0.0202 (11)	−0.0002 (10)	0.0077 (9)	0.0021 (9)
C11	0.0292 (14)	0.0274 (15)	0.0317 (14)	−0.0008 (11)	0.0064 (11)	−0.0028 (11)
C12	0.0318 (16)	0.0453 (19)	0.0338 (15)	−0.0093 (13)	0.0051 (12)	−0.0038 (13)
C13	0.0211 (12)	0.0233 (14)	0.0234 (12)	0.0031 (10)	0.0064 (9)	0.0023 (9)
C14	0.0233 (13)	0.0287 (15)	0.0273 (13)	0.0044 (10)	0.0013 (10)	0.0061 (10)
C15	0.0285 (14)	0.0263 (14)	0.0227 (13)	−0.0028 (10)	−0.0032 (11)	0.0037 (10)
C16	0.0286 (14)	0.0233 (13)	0.0166 (11)	−0.0040 (10)	0.0021 (10)	−0.0001 (9)
C17	0.0184 (12)	0.0192 (12)	0.0167 (11)	−0.0038 (9)	0.0047 (9)	0.0006 (9)
C18	0.0214 (12)	0.0192 (12)	0.0180 (11)	−0.0002 (9)	0.0052 (9)	−0.0007 (9)
C19	0.0198 (12)	0.0322 (15)	0.0293 (13)	0.0055 (11)	0.0017 (10)	0.0006 (11)
C20	0.0232 (14)	0.0375 (17)	0.0433 (17)	0.0086 (12)	0.0099 (12)	0.0007 (13)
C21	0.0359 (16)	0.0408 (18)	0.0381 (16)	0.0100 (13)	0.0171 (13)	−0.0078 (13)
C22	0.0315 (14)	0.0320 (16)	0.0238 (13)	0.0009 (11)	0.0087 (11)	−0.0069 (11)
C23	0.0374 (16)	0.0254 (15)	0.0330 (15)	−0.0055 (12)	0.0062 (12)	0.0069 (11)
C24	0.0341 (16)	0.0395 (18)	0.0361 (16)	0.0007 (13)	0.0013 (12)	0.0090 (13)

Cd—N3	2.361 (2)	C6—H6B	0.9800
Cd—N4	2.406 (2)	C6—H6C	0.9800
Cd—S1	2.5872 (7)	C8—C9	1.515 (3)
Cd—S3	2.6539 (7)	C8—H8A	0.9900
Cd—S4	2.6704 (7)	C8—H8B	0.9900
Cd—S2	2.7816 (7)	C9—H9A	0.9900
S1—C1	1.736 (2)	C9—H9B	0.9900
S2—C1	1.723 (2)	C10—C11	1.527 (4)
S3—C7	1.723 (3)	C10—H10A	0.9900
S4—C7	1.724 (2)	C10—H10B	0.9900
O1—C3	1.426 (3)	C11—C12	1.505 (4)
O1—H1O	0.8400	C11—H11A	0.9900
O2—C9	1.427 (3)	C11—H11B	0.9900
O2—H2O	0.8400	C12—H12A	0.9800
N1—C1	1.340 (3)	C12—H12B	0.9800
N1—C2	1.472 (3)	C12—H12C	0.9800
N1—C4	1.475 (3)	C13—C14	1.384 (4)
N2—C7	1.337 (3)	C13—H13	0.9500
N2—C10	1.467 (3)	C14—C15	1.388 (4)
N2—C8	1.478 (3)	C14—H14	0.9500
N3—C19	1.345 (3)	C15—C16	1.385 (4)
N3—C18	1.345 (3)	C15—H15	0.9500
N4—C13	1.340 (3)	C16—C17	1.393 (3)
N4—C17	1.346 (3)	C16—H16	0.9500
N5—C23	1.141 (4)	C17—C18	1.490 (3)
C2—C3	1.515 (3)	C18—C22	1.395 (3)
C2—H2A	0.9900	C19—C20	1.381 (4)
C2—H2B	0.9900	C19—H19	0.9500
C3—H3A	0.9900	C20—C21	1.383 (4)
C3—H3B	0.9900	C20—H20	0.9500
C4—C5	1.526 (3)	C21—C22	1.381 (4)
C4—H4A	0.9900	C21—H21	0.9500
C4—H4B	0.9900	C22—H22	0.9500
C5—C6	1.523 (3)	C23—C24	1.443 (4)
C5—H5A	0.9900	C24—H24A	0.9800
C5—H5B	0.9900	C24—H24B	0.9800
C6—H6A	0.9800	C24—H24C	0.9800
N3—Cd—N4	68.37 (7)	S3—C7—S4	119.26 (14)
N3—Cd—S1	141.84 (5)	N2—C8—C9	111.5 (2)
N4—Cd—S1	98.70 (5)	N2—C8—H8A	109.3
N3—Cd—S3	96.53 (5)	C9—C8—H8A	109.3
N4—Cd—S3	143.78 (5)	N2—C8—H8B	109.3
S1—Cd—S3	111.54 (2)	C9—C8—H8B	109.3
N3—Cd—S4	106.87 (5)	H8A—C8—H8B	108.0
N4—Cd—S4	84.70 (5)	O2—C9—C8	105.9 (2)
S1—Cd—S4	107.40 (2)	O2—C9—H9A	110.5
S3—Cd—S4	67.92 (2)	C8—C9—H9A	110.6
N3—Cd—S2	86.66 (5)	O2—C9—H9B	110.5
N4—Cd—S2	118.12 (5)	C8—C9—H9B	110.5
S1—Cd—S2	67.51 (2)	H9A—C9—H9B	108.7
S3—Cd—S2	92.38 (2)	N2—C10—C11	112.4 (2)
S4—Cd—S2	156.855 (19)	N2—C10—H10A	109.1
C1—S1—Cd	89.45 (8)	C11—C10—H10A	109.1
C1—S2—Cd	83.49 (9)	N2—C10—H10B	109.1
C7—S3—Cd	86.69 (8)	C11—C10—H10B	109.1
C7—S4—Cd	86.13 (9)	H10A—C10—H10B	107.9
C3—O1—H1O	105.4	C12—C11—C10	110.9 (2)
C9—O2—H2O	111.9	C12—C11—H11A	109.5
C1—N1—C2	122.3 (2)	C10—C11—H11A	109.5
C1—N1—C4	121.6 (2)	C12—C11—H11B	109.5
C2—N1—C4	115.9 (2)	C10—C11—H11B	109.5
C7—N2—C10	122.5 (2)	H11A—C11—H11B	108.0
C7—N2—C8	121.8 (2)	C11—C12—H12A	109.5
C10—N2—C8	115.6 (2)	C11—C12—H12B	109.5
C19—N3—C18	119.2 (2)	H12A—C12—H12B	109.5
C19—N3—Cd	120.38 (17)	C11—C12—H12C	109.5
C18—N3—Cd	120.40 (16)	H12A—C12—H12C	109.5
C13—N4—C17	118.6 (2)	H12B—C12—H12C	109.5
C13—N4—Cd	122.48 (16)	N4—C13—C14	123.0 (2)
C17—N4—Cd	118.74 (16)	N4—C13—H13	118.5
N1—C1—S2	120.62 (18)	C14—C13—H13	118.5
N1—C1—S1	119.92 (18)	C13—C14—C15	118.4 (2)
S2—C1—S1	119.46 (14)	C13—C14—H14	120.8
N1—C2—C3	112.5 (2)	C15—C14—H14	120.8
N1—C2—H2A	109.1	C16—C15—C14	119.2 (2)
C3—C2—H2A	109.1	C16—C15—H15	120.4
N1—C2—H2B	109.1	C14—C15—H15	120.4
C3—C2—H2B	109.1	C15—C16—C17	119.0 (2)
H2A—C2—H2B	107.8	C15—C16—H16	120.5
O1—C3—C2	108.4 (2)	C17—C16—H16	120.5
O1—C3—H3A	110.0	N4—C17—C16	121.8 (2)
C2—C3—H3A	110.0	N4—C17—C18	116.2 (2)
O1—C3—H3B	110.0	C16—C17—C18	122.0 (2)
C2—C3—H3B	110.0	N3—C18—C22	121.2 (2)
H3A—C3—H3B	108.4	N3—C18—C17	116.2 (2)
N1—C4—C5	111.54 (19)	C22—C18—C17	122.6 (2)
N1—C4—H4A	109.3	N3—C19—C20	122.6 (3)
C5—C4—H4A	109.3	N3—C19—H19	118.7
N1—C4—H4B	109.3	C20—C19—H19	118.7
C5—C4—H4B	109.3	C19—C20—C21	118.2 (3)
H4A—C4—H4B	108.0	C19—C20—H20	120.9
C6—C5—C4	111.1 (2)	C21—C20—H20	120.9
C6—C5—H5A	109.4	C22—C21—C20	120.0 (3)
C4—C5—H5A	109.4	C22—C21—H21	120.0
C6—C5—H5B	109.4	C20—C21—H21	120.0
C4—C5—H5B	109.4	C21—C22—C18	118.8 (3)
H5A—C5—H5B	108.0	C21—C22—H22	120.6
C5—C6—H6A	109.5	C18—C22—H22	120.6
C5—C6—H6B	109.5	N5—C23—C24	179.1 (3)
H6A—C6—H6B	109.5	C23—C24—H24A	109.5
C5—C6—H6C	109.5	C23—C24—H24B	109.5
H6A—C6—H6C	109.5	H24A—C24—H24B	109.5
H6B—C6—H6C	109.5	C23—C24—H24C	109.5
N2—C7—S3	120.65 (19)	H24A—C24—H24C	109.5
N2—C7—S4	120.09 (19)	H24B—C24—H24C	109.5
N3—Cd—S1—C1	−52.88 (11)	Cd—S1—C1—S2	3.16 (13)
N4—Cd—S1—C1	−118.76 (9)	C1—N1—C2—C3	−90.2 (3)
S3—Cd—S1—C1	81.54 (8)	C4—N1—C2—C3	95.2 (3)
S4—Cd—S1—C1	154.10 (8)	N1—C2—C3—O1	−63.7 (3)
S2—Cd—S1—C1	−1.85 (7)	C1—N1—C4—C5	−83.9 (3)
N3—Cd—S2—C1	153.10 (9)	C2—N1—C4—C5	90.8 (2)
N4—Cd—S2—C1	89.84 (9)	N1—C4—C5—C6	177.9 (2)
S1—Cd—S2—C1	1.87 (8)	C10—N2—C7—S3	179.42 (18)
S3—Cd—S2—C1	−110.49 (8)	C8—N2—C7—S3	−3.5 (3)
S4—Cd—S2—C1	−79.80 (9)	C10—N2—C7—S4	−1.5 (3)
N3—Cd—S3—C7	−105.50 (10)	C8—N2—C7—S4	175.58 (18)
N4—Cd—S3—C7	−43.64 (12)	Cd—S3—C7—N2	178.9 (2)
S1—Cd—S3—C7	100.87 (8)	Cd—S3—C7—S4	−0.15 (14)
S4—Cd—S3—C7	0.09 (8)	Cd—S4—C7—N2	−178.9 (2)
S2—Cd—S3—C7	167.59 (8)	Cd—S4—C7—S3	0.15 (13)
N3—Cd—S4—C7	90.20 (10)	C7—N2—C8—C9	91.3 (3)
N4—Cd—S4—C7	155.69 (10)	C10—N2—C8—C9	−91.5 (3)
S1—Cd—S4—C7	−106.83 (8)	N2—C8—C9—O2	−176.7 (2)
S3—Cd—S4—C7	−0.09 (8)	C7—N2—C10—C11	89.8 (3)
S2—Cd—S4—C7	−33.49 (10)	C8—N2—C10—C11	−87.4 (3)
N4—Cd—N3—C19	178.4 (2)	N2—C10—C11—C12	178.6 (2)
S1—Cd—N3—C19	102.4 (2)	C17—N4—C13—C14	−0.8 (4)
S3—Cd—N3—C19	−35.7 (2)	Cd—N4—C13—C14	−175.62 (19)
S4—Cd—N3—C19	−104.5 (2)	N4—C13—C14—C15	0.2 (4)
S2—Cd—N3—C19	56.3 (2)	C13—C14—C15—C16	−0.2 (4)
N4—Cd—N3—C18	−1.17 (17)	C14—C15—C16—C17	0.8 (4)
S1—Cd—N3—C18	−77.2 (2)	C13—N4—C17—C16	1.4 (4)
S3—Cd—N3—C18	144.74 (18)	Cd—N4—C17—C16	176.40 (18)
S4—Cd—N3—C18	75.88 (18)	C13—N4—C17—C18	−179.0 (2)
S2—Cd—N3—C18	−123.25 (18)	Cd—N4—C17—C18	−4.0 (3)
N3—Cd—N4—C13	177.6 (2)	C15—C16—C17—N4	−1.4 (4)
S1—Cd—N4—C13	−39.79 (19)	C15—C16—C17—C18	179.0 (2)
S3—Cd—N4—C13	107.09 (19)	C19—N3—C18—C22	0.9 (4)
S4—Cd—N4—C13	67.05 (19)	Cd—N3—C18—C22	−179.6 (2)
S2—Cd—N4—C13	−108.88 (19)	C19—N3—C18—C17	−179.9 (2)
N3—Cd—N4—C17	2.78 (17)	Cd—N3—C18—C17	−0.3 (3)
S1—Cd—N4—C17	145.43 (16)	N4—C17—C18—N3	2.9 (3)
S3—Cd—N4—C17	−67.7 (2)	C16—C17—C18—N3	−177.5 (2)
S4—Cd—N4—C17	−107.73 (17)	N4—C17—C18—C22	−177.9 (2)
S2—Cd—N4—C17	76.34 (18)	C16—C17—C18—C22	1.7 (4)
C2—N1—C1—S2	0.1 (3)	C18—N3—C19—C20	−1.0 (4)
C4—N1—C1—S2	174.40 (16)	Cd—N3—C19—C20	179.4 (2)
C2—N1—C1—S1	−179.15 (17)	N3—C19—C20—C21	0.4 (5)
C4—N1—C1—S1	−4.8 (3)	C19—C20—C21—C22	0.5 (5)
Cd—S2—C1—N1	177.82 (19)	C20—C21—C22—C18	−0.7 (5)
Cd—S2—C1—S1	−2.96 (12)	N3—C18—C22—C21	0.0 (4)
Cd—S1—C1—N1	−177.61 (18)	C17—C18—C22—C21	−179.2 (3)

D—H···A	D—H	H···A	D···A	D—H···A
O1—H1o···N5	0.84	2.06	2.898 (3)	174
O2—H2o···S2i	0.84	2.55	3.388 (2)	175

Table 1

Selected bond lengths (Å)

Cd—N3	2.361 (2)
Cd—N4	2.406 (2)
Cd—S1	2.5872 (7)
Cd—S3	2.6539 (7)
Cd—S4	2.6704 (7)
Cd—S2	2.7816 (7)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O1—H1o⋯N5	0.84	2.06	2.898 (3)	174
O2—H2o⋯S2i	0.84	2.55	3.388 (2)	175

Symmetry code: (i) .