(2,2'-Bipyridyl-κN,N')bis-(N-butyl-N-methyl-dithio-carbamato-κS,S')cadmium(II).

The Cd(II) atom in the title compound, [Cd(C(6)H(12)NS(2))(2)(C(10)H(8)N(2))], is hexa-coordinated by two dithio-carbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl mol-ecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N(2)S(4) donor set. Supra-molecular chains, aligned along the a-axis direction, are mediated by C-H⋯S inter-actions and these are connected into layers that stack along the c axis via π-π inter-actions [Cg(pyrid-yl)⋯Cg(pyrid-yl) = 3.6587 (13) Å].

Related literature

For background to supra­molecular polymers of zinc-triad 1,1-dithiol­ates, including dithio­carbamates, see: Chen et al. (2006 ▶); Benson et al. (2007 ▶). For a closely related 2,2′-bipyridyl adduct, see: Song & Tiekink (2009 ▶).

Experimental

Crystal data

[Cd(C6H12NS2)2(C10H8N2)]

M = 593.16

Triclinic,

a = 10.3215 (4) Å

b = 10.6465 (4) Å

c = 12.4546 (5) Å

α = 81.566 (3)°

β = 74.790 (3)°

γ = 83.641 (3)°

V = 1302.64 (9) Å3

Z = 2

Mo Kα radiation

μ = 1.18 mm−1

T = 150 K

0.27 × 0.16 × 0.01 mm

Data collection

Oxford Diffraction Xcaliber Eos Gemini diffractometer

Absorption correction: multi-scan (CrysAlis PRO; Oxford Diffraction, 2010 ▶) T min = 0.829, T max = 0.990

15837 measured reflections

5393 independent reflections

4623 reflections with I > 2σ(I)

R int = 0.042

Refinement

R[F 2 > 2σ(F 2)] = 0.029

wR(F 2) = 0.066

S = 1.06

5393 reflections

284 parameters

H-atom parameters constrained

Δρmax = 0.90 e Å−3

Δρmin = −0.51 e Å−3

Data collection: CrysAlis PRO (Oxford Diffraction, 2010 ▶); cell refinement: CrysAlis PRO; data reduction: CrysAlis PRO; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 (Farrugia, 1997 ▶) and DIAMOND (Brandenburg, 2006 ▶); software used to prepare material for publication: publCIF (Westrip, 2010 ▶).

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536811006878/pk2304sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536811006878/pk2304Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cd(C6H12NS2)2(C10H8N2)]	Z = 2
Mr = 593.16	F(000) = 608
Triclinic, P1	Dx = 1.512 Mg m−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 10.3215 (4) Å	Cell parameters from 8976 reflections
b = 10.6465 (4) Å	θ = 2.0–29.0°
c = 12.4546 (5) Å	µ = 1.18 mm−1
α = 81.566 (3)°	T = 150 K
β = 74.790 (3)°	Plate, colourless
γ = 83.641 (3)°	0.27 × 0.16 × 0.01 mm
V = 1302.64 (9) Å3

Oxford Diffraction Xcaliber Eos Gemini diffractometer	5393 independent reflections
Radiation source: fine-focus sealed tube	4623 reflections with I > 2σ(I)
graphite	Rint = 0.042
Detector resolution: 16.1952 pixels mm-1	θmax = 26.5°, θmin = 2.3°
ω scans	h = −12→12
Absorption correction: multi-scan (CrysAlis PRO; Oxford Diffraction, 2010)	k = −13→13
Tmin = 0.829, Tmax = 0.990	l = −15→15
15837 measured reflections

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.029	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.066	H-atom parameters constrained
S = 1.06	w = 1/[σ2(Fo2) + (0.0248P)2 + 0.0565P] where P = (Fo2 + 2Fc2)/3
5393 reflections	(Δ/σ)max = 0.001
284 parameters	Δρmax = 0.90 e Å−3
0 restraints	Δρmin = −0.51 e Å−3

Geometry. All s.u.'s (except the s.u. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell s.u.'s are taken into account individually in the estimation of s.u.'s in distances, angles and torsion angles; correlations between s.u.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell s.u.'s is used for estimating s.u.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cd	0.669262 (17)	0.668974 (17)	0.664886 (14)	0.02060 (7)
S1	0.60096 (7)	0.69901 (6)	0.47470 (5)	0.02501 (15)
S2	0.73388 (7)	0.90040 (6)	0.53865 (5)	0.02474 (15)
S3	0.47202 (7)	0.54259 (7)	0.80306 (6)	0.02816 (16)
S4	0.56208 (7)	0.77897 (6)	0.85175 (5)	0.02633 (15)
N1	0.6294 (2)	0.93184 (19)	0.36194 (16)	0.0217 (5)
N2	0.3637 (2)	0.6493 (2)	0.98885 (17)	0.0274 (5)
N3	0.8838 (2)	0.62383 (19)	0.70520 (15)	0.0188 (4)
N4	0.7756 (2)	0.46118 (19)	0.61699 (16)	0.0220 (5)
C1	0.6525 (2)	0.8525 (2)	0.44916 (19)	0.0208 (5)
C2	0.6688 (3)	1.0633 (2)	0.3422 (2)	0.0274 (6)
H2A	0.6156	1.1102	0.4032	0.041*
H2B	0.6525	1.1048	0.2708	0.041*
H2C	0.7647	1.0626	0.3393	0.041*
C3	0.5565 (3)	0.9003 (2)	0.2837 (2)	0.0261 (6)
H3A	0.4858	0.9693	0.2754	0.031*
H3B	0.5114	0.8209	0.3156	0.031*
C4	0.6490 (3)	0.8829 (3)	0.1684 (2)	0.0286 (6)
H4A	0.5930	0.8765	0.1162	0.034*
H4B	0.7002	0.9593	0.1401	0.034*
C5	0.7477 (3)	0.7662 (3)	0.1679 (2)	0.0300 (6)
H5A	0.6968	0.6893	0.1940	0.036*
H5B	0.8026	0.7713	0.2212	0.036*
C6	0.8409 (3)	0.7531 (3)	0.0524 (2)	0.0453 (8)
H6A	0.7872	0.7466	−0.0006	0.068*
H6B	0.9021	0.6764	0.0565	0.068*
H6C	0.8933	0.8280	0.0269	0.068*
C7	0.4562 (2)	0.6567 (2)	0.8919 (2)	0.0232 (6)
C8	0.2758 (3)	0.5432 (3)	1.0244 (2)	0.0350 (7)
H8A	0.2020	0.5592	0.9870	0.053*
H8B	0.2387	0.5358	1.1058	0.053*
H8C	0.3281	0.4638	1.0041	0.053*
C9	0.3423 (3)	0.7429 (3)	1.0687 (2)	0.0329 (7)
H9A	0.4118	0.8051	1.0410	0.039*
H9B	0.3536	0.6986	1.1417	0.039*
C11	0.2043 (3)	0.8137 (3)	1.0860 (2)	0.0350 (7)
H11A	0.1347	0.7521	1.1166	0.042*
H11B	0.1916	0.8560	1.0128	0.042*
C12	0.1862 (3)	0.9133 (3)	1.1660 (2)	0.0400 (7)
H12A	0.2177	0.8748	1.2328	0.048*
H12B	0.2427	0.9843	1.1285	0.048*
C13	0.0408 (3)	0.9657 (3)	1.2032 (3)	0.0484 (9)
H13A	0.0119	1.0120	1.1383	0.073*
H13B	0.0329	1.0237	1.2592	0.073*
H13C	−0.0165	0.8953	1.2361	0.073*
C14	0.9307 (3)	0.7054 (2)	0.7554 (2)	0.0249 (6)
H14	0.8736	0.7775	0.7797	0.030*
C15	1.0578 (3)	0.6896 (3)	0.7734 (2)	0.0299 (6)
H15	1.0872	0.7486	0.8106	0.036*
C16	1.1413 (3)	0.5869 (3)	0.7364 (2)	0.0327 (7)
H16	1.2303	0.5749	0.7459	0.039*
C17	1.0942 (3)	0.5005 (2)	0.6848 (2)	0.0257 (6)
H17	1.1504	0.4285	0.6590	0.031*
C18	0.9638 (2)	0.5211 (2)	0.67166 (18)	0.0185 (5)
C19	0.9038 (2)	0.4298 (2)	0.62209 (19)	0.0190 (5)
C20	0.9733 (3)	0.3185 (2)	0.5849 (2)	0.0243 (6)
H20	1.0649	0.2995	0.5867	0.029*
C21	0.9076 (3)	0.2359 (2)	0.5453 (2)	0.0299 (6)
H21	0.9535	0.1592	0.5200	0.036*
C22	0.7746 (3)	0.2662 (3)	0.5428 (2)	0.0304 (6)
H22	0.7265	0.2101	0.5177	0.037*
C23	0.7136 (3)	0.3805 (3)	0.5781 (2)	0.0287 (6)
H23	0.6231	0.4030	0.5744	0.034*

	U11	U22	U33	U12	U13	U23
Cd	0.01478 (10)	0.02502 (11)	0.02106 (10)	0.00349 (7)	−0.00428 (8)	−0.00391 (7)
S1	0.0271 (4)	0.0231 (3)	0.0261 (3)	−0.0007 (3)	−0.0104 (3)	−0.0012 (3)
S2	0.0229 (3)	0.0269 (4)	0.0250 (3)	0.0008 (3)	−0.0077 (3)	−0.0042 (3)
S3	0.0179 (3)	0.0379 (4)	0.0285 (4)	−0.0019 (3)	−0.0040 (3)	−0.0068 (3)
S4	0.0222 (3)	0.0264 (4)	0.0254 (3)	0.0025 (3)	0.0001 (3)	−0.0016 (3)
N1	0.0219 (12)	0.0217 (11)	0.0210 (11)	0.0041 (9)	−0.0064 (9)	−0.0031 (9)
N2	0.0221 (12)	0.0335 (13)	0.0215 (11)	−0.0001 (10)	−0.0003 (10)	0.0018 (9)
N3	0.0158 (11)	0.0228 (11)	0.0161 (10)	−0.0001 (9)	−0.0010 (9)	−0.0037 (8)
N4	0.0172 (11)	0.0250 (12)	0.0240 (11)	−0.0005 (9)	−0.0045 (9)	−0.0050 (9)
C1	0.0137 (12)	0.0230 (13)	0.0221 (13)	0.0065 (10)	0.0000 (10)	−0.0050 (10)
C2	0.0314 (15)	0.0216 (14)	0.0284 (14)	0.0027 (11)	−0.0085 (12)	−0.0022 (11)
C3	0.0248 (14)	0.0284 (15)	0.0270 (14)	0.0011 (12)	−0.0123 (12)	−0.0009 (11)
C4	0.0344 (16)	0.0305 (15)	0.0232 (13)	−0.0031 (12)	−0.0128 (13)	0.0002 (11)
C5	0.0317 (16)	0.0310 (15)	0.0271 (14)	−0.0011 (12)	−0.0055 (13)	−0.0069 (12)
C6	0.048 (2)	0.054 (2)	0.0311 (16)	0.0015 (16)	−0.0035 (15)	−0.0122 (14)
C7	0.0152 (13)	0.0302 (14)	0.0215 (13)	0.0075 (11)	−0.0060 (11)	0.0014 (11)
C8	0.0290 (16)	0.0405 (17)	0.0288 (15)	−0.0032 (13)	−0.0003 (13)	0.0053 (12)
C9	0.0273 (15)	0.0460 (18)	0.0215 (13)	0.0018 (13)	−0.0010 (12)	−0.0041 (12)
C11	0.0304 (16)	0.0350 (16)	0.0338 (16)	0.0017 (13)	−0.0018 (13)	−0.0003 (13)
C12	0.0358 (18)	0.0343 (17)	0.0392 (17)	−0.0016 (14)	0.0066 (15)	−0.0009 (13)
C13	0.0395 (19)	0.0323 (18)	0.061 (2)	0.0016 (15)	0.0080 (17)	−0.0069 (15)
C14	0.0211 (14)	0.0278 (14)	0.0253 (13)	0.0004 (11)	−0.0039 (11)	−0.0073 (11)
C15	0.0240 (15)	0.0383 (17)	0.0312 (15)	−0.0058 (13)	−0.0098 (13)	−0.0086 (12)
C16	0.0184 (14)	0.0440 (18)	0.0383 (16)	−0.0010 (13)	−0.0133 (13)	−0.0032 (13)
C17	0.0200 (14)	0.0277 (14)	0.0282 (14)	0.0059 (11)	−0.0071 (12)	−0.0036 (11)
C18	0.0153 (12)	0.0236 (13)	0.0136 (11)	−0.0004 (10)	−0.0012 (10)	0.0022 (10)
C19	0.0173 (13)	0.0191 (13)	0.0172 (12)	0.0008 (10)	−0.0007 (10)	0.0005 (9)
C20	0.0189 (13)	0.0248 (14)	0.0242 (13)	0.0002 (11)	0.0009 (11)	0.0003 (11)
C21	0.0354 (16)	0.0219 (14)	0.0283 (14)	−0.0002 (12)	−0.0004 (13)	−0.0054 (11)
C22	0.0337 (16)	0.0295 (15)	0.0290 (14)	−0.0090 (13)	−0.0048 (13)	−0.0064 (12)
C23	0.0217 (14)	0.0325 (16)	0.0325 (15)	−0.0020 (12)	−0.0057 (12)	−0.0075 (12)

Cd—S1	2.6104 (7)	C6—H6C	0.9800
Cd—S2	2.7685 (7)	C8—H8A	0.9800
Cd—S3	2.6468 (7)	C8—H8B	0.9800
Cd—S4	2.6783 (7)	C8—H8C	0.9800
Cd—N3	2.379 (2)	C9—C11	1.514 (4)
Cd—N4	2.441 (2)	C9—H9A	0.9900
S1—C1	1.733 (3)	C9—H9B	0.9900
S2—C1	1.721 (2)	C11—C12	1.522 (4)
S3—C7	1.727 (3)	C11—H11A	0.9900
S4—C7	1.725 (3)	C11—H11B	0.9900
N1—C1	1.332 (3)	C12—C13	1.518 (4)
N1—C2	1.469 (3)	C12—H12A	0.9900
N1—C3	1.471 (3)	C12—H12B	0.9900
N2—C7	1.327 (3)	C13—H13A	0.9800
N2—C9	1.469 (3)	C13—H13B	0.9800
N2—C8	1.472 (3)	C13—H13C	0.9800
N3—C14	1.338 (3)	C14—C15	1.377 (4)
N3—C18	1.344 (3)	C14—H14	0.9500
N4—C23	1.337 (3)	C15—C16	1.372 (4)
N4—C19	1.344 (3)	C15—H15	0.9500
C2—H2A	0.9800	C16—C17	1.389 (4)
C2—H2B	0.9800	C16—H16	0.9500
C2—H2C	0.9800	C17—C18	1.388 (3)
C3—C4	1.526 (3)	C17—H17	0.9500
C3—H3A	0.9900	C18—C19	1.489 (3)
C3—H3B	0.9900	C19—C20	1.390 (3)
C4—C5	1.516 (4)	C20—C21	1.382 (4)
C4—H4A	0.9900	C20—H20	0.9500
C4—H4B	0.9900	C21—C22	1.383 (4)
C5—C6	1.522 (4)	C21—H21	0.9500
C5—H5A	0.9900	C22—C23	1.383 (4)
C5—H5B	0.9900	C22—H22	0.9500
C6—H6A	0.9800	C23—H23	0.9500
C6—H6B	0.9800
N3—Cd—N4	67.00 (7)	N2—C7—S4	121.3 (2)
N3—Cd—S1	130.89 (5)	N2—C7—S3	119.9 (2)
N4—Cd—S1	87.19 (5)	S4—C7—S3	118.79 (14)
N3—Cd—S3	115.46 (5)	N2—C8—H8A	109.5
N4—Cd—S3	86.24 (5)	N2—C8—H8B	109.5
S1—Cd—S3	102.91 (2)	H8A—C8—H8B	109.5
N3—Cd—S4	93.32 (5)	N2—C8—H8C	109.5
N4—Cd—S4	137.16 (5)	H8A—C8—H8C	109.5
S1—Cd—S4	130.38 (2)	H8B—C8—H8C	109.5
S3—Cd—S4	67.82 (2)	N2—C9—C11	112.8 (2)
N3—Cd—S2	94.02 (5)	N2—C9—H9A	109.0
N4—Cd—S2	125.32 (5)	C11—C9—H9A	109.0
S1—Cd—S2	67.03 (2)	N2—C9—H9B	109.0
S3—Cd—S2	144.43 (2)	C11—C9—H9B	109.0
S4—Cd—S2	92.26 (2)	H9A—C9—H9B	107.8
C1—S1—Cd	89.21 (8)	C9—C11—C12	111.9 (3)
C1—S2—Cd	84.39 (8)	C9—C11—H11A	109.2
C7—S3—Cd	87.18 (9)	C12—C11—H11A	109.2
C7—S4—Cd	86.21 (9)	C9—C11—H11B	109.2
C1—N1—C2	120.7 (2)	C12—C11—H11B	109.2
C1—N1—C3	124.2 (2)	H11A—C11—H11B	107.9
C2—N1—C3	114.95 (19)	C13—C12—C11	112.5 (3)
C7—N2—C9	123.5 (2)	C13—C12—H12A	109.1
C7—N2—C8	121.3 (2)	C11—C12—H12A	109.1
C9—N2—C8	115.2 (2)	C13—C12—H12B	109.1
C14—N3—C18	118.6 (2)	C11—C12—H12B	109.1
C14—N3—Cd	120.22 (16)	H12A—C12—H12B	107.8
C18—N3—Cd	121.00 (15)	C12—C13—H13A	109.5
C23—N4—C19	118.4 (2)	C12—C13—H13B	109.5
C23—N4—Cd	122.04 (16)	H13A—C13—H13B	109.5
C19—N4—Cd	119.35 (15)	C12—C13—H13C	109.5
N1—C1—S2	120.62 (19)	H13A—C13—H13C	109.5
N1—C1—S1	120.58 (19)	H13B—C13—H13C	109.5
S2—C1—S1	118.80 (14)	N3—C14—C15	123.0 (2)
N1—C2—H2A	109.5	N3—C14—H14	118.5
N1—C2—H2B	109.5	C15—C14—H14	118.5
H2A—C2—H2B	109.5	C16—C15—C14	118.6 (2)
N1—C2—H2C	109.5	C16—C15—H15	120.7
H2A—C2—H2C	109.5	C14—C15—H15	120.7
H2B—C2—H2C	109.5	C15—C16—C17	119.3 (2)
N1—C3—C4	112.5 (2)	C15—C16—H16	120.3
N1—C3—H3A	109.1	C17—C16—H16	120.3
C4—C3—H3A	109.1	C18—C17—C16	118.9 (2)
N1—C3—H3B	109.1	C18—C17—H17	120.6
C4—C3—H3B	109.1	C16—C17—H17	120.6
H3A—C3—H3B	107.8	N3—C18—C17	121.5 (2)
C5—C4—C3	113.9 (2)	N3—C18—C19	116.3 (2)
C5—C4—H4A	108.8	C17—C18—C19	122.1 (2)
C3—C4—H4A	108.8	N4—C19—C20	121.6 (2)
C5—C4—H4B	108.8	N4—C19—C18	115.3 (2)
C3—C4—H4B	108.8	C20—C19—C18	123.1 (2)
H4A—C4—H4B	107.7	C21—C20—C19	119.2 (2)
C4—C5—C6	112.7 (2)	C21—C20—H20	120.4
C4—C5—H5A	109.1	C19—C20—H20	120.4
C6—C5—H5A	109.1	C20—C21—C22	119.3 (2)
C4—C5—H5B	109.1	C20—C21—H21	120.3
C6—C5—H5B	109.1	C22—C21—H21	120.3
H5A—C5—H5B	107.8	C21—C22—C23	118.0 (2)
C5—C6—H6A	109.5	C21—C22—H22	121.0
C5—C6—H6B	109.5	C23—C22—H22	121.0
H6A—C6—H6B	109.5	N4—C23—C22	123.4 (2)
C5—C6—H6C	109.5	N4—C23—H23	118.3
H6A—C6—H6C	109.5	C22—C23—H23	118.3
H6B—C6—H6C	109.5
N3—Cd—S1—C1	−78.98 (10)	Cd—S2—C1—S1	−7.09 (13)
N4—Cd—S1—C1	−134.92 (9)	Cd—S1—C1—N1	−172.43 (19)
S3—Cd—S1—C1	139.60 (8)	Cd—S1—C1—S2	7.49 (13)
S4—Cd—S1—C1	67.87 (8)	C1—N1—C3—C4	−108.9 (3)
S2—Cd—S1—C1	−4.42 (8)	C2—N1—C3—C4	75.2 (3)
N3—Cd—S2—C1	137.55 (9)	N1—C3—C4—C5	68.0 (3)
N4—Cd—S2—C1	73.04 (10)	C3—C4—C5—C6	−178.6 (2)
S1—Cd—S2—C1	4.47 (8)	C9—N2—C7—S4	0.6 (3)
S3—Cd—S2—C1	−75.42 (9)	C8—N2—C7—S4	−178.37 (19)
S4—Cd—S2—C1	−128.96 (8)	C9—N2—C7—S3	−179.28 (19)
N3—Cd—S3—C7	82.82 (10)	C8—N2—C7—S3	1.8 (3)
N4—Cd—S3—C7	145.11 (9)	Cd—S4—C7—N2	−179.9 (2)
S1—Cd—S3—C7	−128.65 (8)	Cd—S4—C7—S3	−0.02 (13)
S4—Cd—S3—C7	−0.01 (8)	Cd—S3—C7—N2	179.86 (19)
S2—Cd—S3—C7	−60.22 (9)	Cd—S3—C7—S4	0.02 (13)
N3—Cd—S4—C7	−116.17 (9)	C7—N2—C9—C11	116.6 (3)
N4—Cd—S4—C7	−57.04 (11)	C8—N2—C9—C11	−64.4 (3)
S1—Cd—S4—C7	88.29 (8)	N2—C9—C11—C12	−178.0 (2)
S3—Cd—S4—C7	0.01 (8)	C9—C11—C12—C13	−168.1 (3)
S2—Cd—S4—C7	149.67 (8)	C18—N3—C14—C15	0.6 (4)
N4—Cd—N3—C14	−176.21 (19)	Cd—N3—C14—C15	−174.99 (19)
S1—Cd—N3—C14	119.77 (16)	N3—C14—C15—C16	1.2 (4)
S3—Cd—N3—C14	−102.54 (17)	C14—C15—C16—C17	−1.7 (4)
S4—Cd—N3—C14	−35.56 (17)	C15—C16—C17—C18	0.3 (4)
S2—Cd—N3—C14	56.94 (17)	C14—N3—C18—C17	−2.1 (3)
N4—Cd—N3—C18	8.28 (16)	Cd—N3—C18—C17	173.52 (17)
S1—Cd—N3—C18	−55.74 (19)	C14—N3—C18—C19	176.7 (2)
S3—Cd—N3—C18	81.95 (17)	Cd—N3—C18—C19	−7.7 (3)
S4—Cd—N3—C18	148.92 (16)	C16—C17—C18—N3	1.6 (4)
S2—Cd—N3—C18	−118.57 (16)	C16—C17—C18—C19	−177.1 (2)
N3—Cd—N4—C23	176.6 (2)	C23—N4—C19—C20	2.0 (3)
S1—Cd—N4—C23	−46.31 (18)	Cd—N4—C19—C20	−173.34 (17)
S3—Cd—N4—C23	56.83 (18)	C23—N4—C19—C18	−177.0 (2)
S4—Cd—N4—C23	107.98 (18)	Cd—N4—C19—C18	7.6 (3)
S2—Cd—N4—C23	−105.41 (18)	N3—C18—C19—N4	−0.2 (3)
N3—Cd—N4—C19	−8.27 (16)	C17—C18—C19—N4	178.6 (2)
S1—Cd—N4—C19	128.86 (17)	N3—C18—C19—C20	−179.2 (2)
S3—Cd—N4—C19	−128.00 (17)	C17—C18—C19—C20	−0.4 (4)
S4—Cd—N4—C19	−76.85 (19)	N4—C19—C20—C21	−2.3 (4)
S2—Cd—N4—C19	69.76 (18)	C18—C19—C20—C21	176.7 (2)
C2—N1—C1—S2	−2.0 (3)	C19—C20—C21—C22	0.4 (4)
C3—N1—C1—S2	−177.74 (18)	C20—C21—C22—C23	1.5 (4)
C2—N1—C1—S1	177.93 (18)	C19—N4—C23—C22	0.1 (4)
C3—N1—C1—S1	2.2 (3)	Cd—N4—C23—C22	175.32 (19)
Cd—S2—C1—N1	172.83 (19)	C21—C22—C23—N4	−1.9 (4)

D—H···A	D—H	H···A	D···A	D—H···A
C16—H16···S3i	0.95	2.74	3.685 (3)	172

Table 1

Selected bond lengths (Å)

Cd—S1	2.6104 (7)
Cd—S2	2.7685 (7)
Cd—S3	2.6468 (7)
Cd—S4	2.6783 (7)
Cd—N3	2.379 (2)
Cd—N4	2.441 (2)

Table 2

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
C16—H16⋯S3i	0.95	2.74	3.685 (3)	172

Symmetry code: (i) .