Literature DB >> 21359345

Solvent-hindered intramolecular vibrational redistribution.

John T King1, Jessica M Anna, Kevin J Kubarych.   

Abstract

Ultrafast two-dimensional infrared spectroscopy and molecular dynamics simulations of Mn(2)(CO)(10) in a series of linear alcohols reveal that the rate of intramolecular vibrational redistribution among the terminal carbonyl stretches is dictated by the average number of hydrogen bonds formed between the solute and solvent. The presence of hydrogen bonds was found to hinder vibrational redistribution between eigenstates, while leaving the overall T(1) relaxation rate unchanged.

Entities:  

Year:  2011        PMID： 21359345     DOI： 10.1039/c0cp02138e

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN： 1463-9076            Impact factor:   3.676


  7 in total

Review 1.  Vibrational Spectroscopic Map, Vibrational Spectroscopy, and Intermolecular Interaction.

Authors:  Carlos R Baiz; Bartosz Błasiak; Jens Bredenbeck; Minhaeng Cho; Jun-Ho Choi; Steven A Corcelli; Arend G Dijkstra; Chi-Jui Feng; Sean Garrett-Roe; Nien-Hui Ge; Magnus W D Hanson-Heine; Jonathan D Hirst; Thomas L C Jansen; Kijeong Kwac; Kevin J Kubarych; Casey H Londergan; Hiroaki Maekawa; Mike Reppert; Shinji Saito; Santanu Roy; James L Skinner; Gerhard Stock; John E Straub; Megan C Thielges; Keisuke Tominaga; Andrei Tokmakoff; Hajime Torii; Lu Wang; Lauren J Webb; Martin T Zanni
Journal:  Chem Rev       Date:  2020-06-29       Impact factor: 60.622

2.  Site-specific hydration dynamics of globular proteins and the role of constrained water in solvent exchange with amphiphilic cosolvents.

Authors:  John T King; Evan J Arthur; Charles L Brooks; Kevin J Kubarych
Journal:  J Phys Chem B       Date:  2012-05-07       Impact factor: 2.991

3.  Quantum process tomography quantifies coherence transfer dynamics in vibrational exciton.

Authors:  Lev Chuntonov; Jianqiang Ma
Journal:  J Phys Chem B       Date:  2013-10-16       Impact factor: 2.991

4.  Tuning Molecular Vibrational Energy Flow within an Aromatic Scaffold via Anharmonic Coupling.

Authors:  Andrew J Schmitz; Hari Datt Pandey; Farzaneh Chalyavi; Tianjiao Shi; Edward E Fenlon; Scott H Brewer; David M Leitner; Matthew J Tucker
Journal:  J Phys Chem A       Date:  2019-12-03       Impact factor: 2.781

5.  Kinetic Isotope Effect Provides Insight into the Vibrational Relaxation Mechanism of Aromatic Molecules: Application to Cyano-phenylalanine.

Authors:  Jeffrey M Rodgers; Wenkai Zhang; Christopher G Bazewicz; Jianxin Chen; Scott H Brewer; Feng Gai
Journal:  J Phys Chem Lett       Date:  2016-03-22       Impact factor: 6.475

6.  Direct observation of the intermediate in an ultrafast isomerization.

Authors:  Tyler M Porter; Jiaxi Wang; Yingmin Li; Bo Xiang; Catherine Salsman; Joel S Miller; Wei Xiong; Clifford P Kubiak
Journal:  Chem Sci       Date:  2018-10-08       Impact factor: 9.825

7.  Direct local solvent probing by transient infrared spectroscopy reveals the mechanism of hydrogen-bond induced nonradiative deactivation.

Authors:  Bogdan Dereka; Eric Vauthey
Journal:  Chem Sci       Date:  2017-05-16       Impact factor: 9.825
  7 in total

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