Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II).

The title compound, [Cd(NO(3))(2)(C(11)H(13)N(3))(2)], was synthesized by hydro-thermal reaction of Cd(NO(3))(2) and S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole. The Cd atom lies on an inversion centre. The distorted octa-hedral Cd environment contains two planar trans-related N,N-chelating S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in one plane and two monodentate nitrate ligands. N-H⋯O hydrogen bonds involving a nitrate O atom build up an infinite chain parallel to the a axis.

Related literature

For physical properties such as fluorescence and dielectric behaviors of metal–organic coordination compounds, see: Aminabhavi et al. (1986 ▶); Ye et al. (2008 ▶).

Experimental

Crystal data

[Cd(NO3)2(C11H12N3)2]

M = 610.91

Triclinic,

a = 8.1487 (16) Å

b = 9.1459 (18) Å

c = 9.7439 (19) Å

α = 111.67 (3)°

β = 112.32 (3)°

γ = 93.80 (3)°

V = 606.0 (2) Å3

Z = 1

Mo Kα radiation

μ = 0.96 mm−1

T = 293 (2) K

0.12 × 0.10 × 0.06 mm

Data collection

Rigaku Mercury2 diffractometer

Absorption correction: multi-scan (CrystalClear; Rigaku, 2005 ▶) T min = 0.889, T max = 0.944

6172 measured reflections

2692 independent reflections

2258 reflections with I > 2σ(I)

R int = 0.057

Refinement

R[F 2 > 2σ(F 2)] = 0.053

wR(F 2) = 0.114

S = 1.07

2692 reflections

169 parameters

H-atom parameters constrained

Δρmax = 0.69 e Å−3

Δρmin = −0.45 e Å−3

Data collection: CrystalClear (Rigaku, 2005 ▶); cell refinement: CrystalClear; data reduction: CrystalClear program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536808006454/dn2315sup1.cif

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808006454/dn2315Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Cd(NO3)2(C11H12N3)2]	Z = 1
Mr = 610.91	F000 = 310
Triclinic, P1	Dx = 1.674 Mg m−3
Hall symbol: -P1	Mo Kα radiation λ = 0.71073 Å
a = 8.1487 (16) Å	Cell parameters from 2061 reflections
b = 9.1459 (18) Å	θ = 3.3–27.5º
c = 9.7439 (19) Å	µ = 0.96 mm−1
α = 111.67 (3)º	T = 293 (2) K
β = 112.32 (3)º	Prism, colorless
γ = 93.80 (3)º	0.12 × 0.10 × 0.06 mm
V = 606.0 (2) Å3

Rigaku Mercury2 diffractometer	2692 independent reflections
Radiation source: fine-focus sealed tube	2258 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.057
Detector resolution: 13.6612 pixels mm-1	θmax = 27.3º
T = 293(2) K	θmin = 3.3º
CCD profile fitting scans	h = −10→10
Absorption correction: multi-scan(CrystalClear; Rigaku, 2005)	k = −11→11
Tmin = 0.889, Tmax = 0.944	l = −12→12
6172 measured reflections

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.053	H-atom parameters constrained
wR(F2) = 0.114	w = 1/[σ2(Fo2) + (0.0464P)2 + 0.245P] where P = (Fo2 + 2Fc2)/3
S = 1.07	(Δ/σ)max < 0.001
2692 reflections	Δρmax = 0.69 e Å−3
169 parameters	Δρmin = −0.44 e Å−3
Primary atom site location: structure-invariant direct methods	Extinction correction: none

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq
Cd1	0.0000	0.5000	0.0000	0.03774 (18)
O1	0.1413 (6)	0.8668 (6)	−0.0027 (6)	0.0919 (14)
O2	0.2395 (5)	0.7989 (5)	−0.1864 (5)	0.0701 (11)
O3	0.1342 (6)	0.6144 (5)	−0.1353 (5)	0.0730 (11)
N4	0.1714 (5)	0.7596 (6)	−0.1065 (5)	0.0503 (10)
N3	0.0853 (6)	0.2624 (5)	−0.1240 (5)	0.0585 (11)
H3B	0.0050	0.1820	−0.1322	0.070*
N2	0.2902 (4)	0.5267 (4)	0.1908 (4)	0.0376 (8)
N1	0.5347 (5)	0.4236 (5)	0.2503 (5)	0.0470 (9)
H1A	0.6040	0.3577	0.2384	0.056*
C3	0.5789 (7)	0.8578 (6)	0.6093 (6)	0.0557 (13)
H3A	0.5818	0.9564	0.6869	0.067*
C5	0.7348 (6)	0.6476 (6)	0.5341 (5)	0.0453 (11)
H5A	0.8365	0.6041	0.5576	0.054*
C6	0.5793 (6)	0.5690 (5)	0.3855 (5)	0.0376 (9)
C4	0.7314 (7)	0.7920 (6)	0.6443 (6)	0.0522 (12)
H4A	0.8331	0.8476	0.7448	0.063*
C7	0.3627 (6)	0.4036 (6)	0.1402 (5)	0.0444 (11)
C2	0.4236 (6)	0.7797 (6)	0.4619 (6)	0.0487 (11)
H2A	0.3221	0.8238	0.4398	0.058*
C8	0.2668 (7)	0.2502 (6)	−0.0174 (6)	0.0524 (12)
H8A	0.2472	0.1603	0.0108	0.063*
C10	0.2213 (6)	0.1190 (6)	−0.2943 (6)	0.0543 (13)
H10A	0.2635	0.1286	−0.3719	0.065*
H10B	0.1804	0.0053	−0.3229	0.065*
C9	0.3685 (7)	0.2075 (8)	−0.1197 (6)	0.0741 (18)
H9A	0.4472	0.1382	−0.0909	0.089*
H9B	0.4424	0.3042	−0.1055	0.089*
C11	0.0726 (9)	0.2075 (9)	−0.2880 (6)	0.085 (2)
H11A	0.0886	0.2992	−0.3131	0.102*
H11B	−0.0463	0.1356	−0.3678	0.102*
C1	0.4241 (6)	0.6332 (5)	0.3478 (5)	0.0360 (9)

	U11	U22	U33	U12	U13	U23
Cd1	0.0274 (3)	0.0437 (3)	0.0305 (3)	0.00864 (18)	0.00878 (18)	0.00795 (19)
O1	0.084 (3)	0.095 (3)	0.080 (3)	0.020 (3)	0.050 (3)	0.005 (3)
O2	0.073 (3)	0.080 (3)	0.092 (3)	0.040 (2)	0.048 (2)	0.057 (2)
O3	0.074 (3)	0.077 (3)	0.092 (3)	0.021 (2)	0.050 (2)	0.045 (2)
N4	0.032 (2)	0.071 (3)	0.046 (2)	0.022 (2)	0.0137 (18)	0.024 (2)
N3	0.043 (2)	0.060 (3)	0.048 (2)	0.012 (2)	0.016 (2)	0.003 (2)
N2	0.0310 (19)	0.044 (2)	0.0297 (17)	0.0114 (15)	0.0110 (15)	0.0098 (15)
N1	0.039 (2)	0.060 (3)	0.044 (2)	0.0233 (18)	0.0198 (18)	0.0208 (19)
C3	0.054 (3)	0.051 (3)	0.040 (3)	0.009 (2)	0.011 (2)	0.008 (2)
C5	0.034 (2)	0.060 (3)	0.041 (2)	0.015 (2)	0.010 (2)	0.027 (2)
C6	0.036 (2)	0.044 (2)	0.032 (2)	0.0081 (18)	0.0126 (19)	0.0183 (19)
C4	0.044 (3)	0.060 (3)	0.034 (2)	0.005 (2)	0.004 (2)	0.016 (2)
C7	0.043 (3)	0.054 (3)	0.035 (2)	0.017 (2)	0.017 (2)	0.018 (2)
C2	0.039 (3)	0.054 (3)	0.044 (3)	0.019 (2)	0.014 (2)	0.015 (2)
C8	0.050 (3)	0.055 (3)	0.044 (3)	0.020 (2)	0.017 (2)	0.015 (2)
C10	0.046 (3)	0.065 (3)	0.036 (3)	0.017 (2)	0.016 (2)	0.007 (2)
C9	0.044 (3)	0.108 (5)	0.038 (3)	0.023 (3)	0.013 (2)	0.002 (3)
C11	0.081 (4)	0.113 (5)	0.034 (3)	0.062 (4)	0.016 (3)	0.008 (3)
C1	0.031 (2)	0.044 (2)	0.033 (2)	0.0113 (18)	0.0107 (18)	0.0181 (19)

Cd1—N2i	2.314 (3)	C3—H3A	0.9300
Cd1—N2	2.314 (3)	C5—C4	1.370 (7)
Cd1—N3i	2.359 (4)	C5—C6	1.391 (6)
Cd1—N3	2.359 (4)	C5—H5A	0.9300
Cd1—O3	2.448 (4)	C6—C1	1.409 (6)
Cd1—O3i	2.448 (4)	C4—H4A	0.9300
O1—N4	1.238 (5)	C7—C8	1.513 (7)
O2—N4	1.245 (5)	C2—C1	1.391 (6)
O3—N4	1.241 (5)	C2—H2A	0.9300
N3—C11	1.447 (7)	C8—C9	1.488 (7)
N3—C8	1.490 (6)	C8—H8A	0.9800
N3—H3B	0.9100	C10—C11	1.509 (7)
N2—C7	1.327 (6)	C10—C9	1.514 (7)
N2—C1	1.403 (5)	C10—H10A	0.9700
N1—C7	1.352 (6)	C10—H10B	0.9700
N1—C6	1.384 (6)	C9—H9A	0.9700
N1—H1A	0.8600	C9—H9B	0.9700
C3—C2	1.385 (7)	C11—H11A	0.9700
C3—C4	1.397 (7)	C11—H11B	0.9700
N2i—Cd1—N2	180.00 (18)	N1—C6—C1	105.2 (4)
N2i—Cd1—N3i	75.24 (13)	C5—C6—C1	122.3 (4)
N2—Cd1—N3i	104.76 (13)	C5—C4—C3	121.6 (4)
N2i—Cd1—N3	104.76 (13)	C5—C4—H4A	119.2
N2—Cd1—N3	75.24 (13)	C3—C4—H4A	119.2
N3i—Cd1—N3	180.0	N2—C7—N1	112.7 (4)
N2i—Cd1—O3	90.22 (13)	N2—C7—C8	125.9 (4)
N2—Cd1—O3	89.78 (13)	N1—C7—C8	121.4 (4)
N3i—Cd1—O3	94.44 (15)	C3—C2—C1	117.9 (4)
N3—Cd1—O3	85.56 (15)	C3—C2—H2A	121.1
N2i—Cd1—O3i	89.78 (13)	C1—C2—H2A	121.1
N2—Cd1—O3i	90.22 (13)	N3—C8—C9	106.3 (4)
N3i—Cd1—O3i	85.56 (15)	N3—C8—C7	111.2 (4)
N3—Cd1—O3i	94.44 (15)	C9—C8—C7	114.6 (5)
O3—Cd1—O3i	180.0	N3—C8—H8A	108.2
N4—O3—Cd1	126.5 (3)	C9—C8—H8A	108.2
O1—N4—O3	122.5 (5)	C7—C8—H8A	108.2
O1—N4—O2	118.7 (5)	C11—C10—C9	101.8 (4)
O3—N4—O2	118.9 (4)	C11—C10—H10A	111.4
C11—N3—C8	107.4 (4)	C9—C10—H10A	111.4
C11—N3—Cd1	122.4 (4)	C11—C10—H10B	111.4
C8—N3—Cd1	113.9 (3)	C9—C10—H10B	111.4
C11—N3—H3B	103.7	H10A—C10—H10B	109.3
C8—N3—H3B	103.7	C8—C9—C10	104.6 (4)
Cd1—N3—H3B	103.7	C8—C9—H9A	110.8
C7—N2—C1	105.2 (3)	C10—C9—H9A	110.8
C7—N2—Cd1	113.3 (3)	C8—C9—H9B	110.8
C1—N2—Cd1	141.5 (3)	C10—C9—H9B	110.8
C7—N1—C6	107.9 (4)	H9A—C9—H9B	108.9
C7—N1—H1A	126.1	N3—C11—C10	107.5 (4)
C6—N1—H1A	126.1	N3—C11—H11A	110.2
C2—C3—C4	121.5 (5)	C10—C11—H11A	110.2
C2—C3—H3A	119.2	N3—C11—H11B	110.2
C4—C3—H3A	119.2	C10—C11—H11B	110.2
C4—C5—C6	117.0 (4)	H11A—C11—H11B	108.5
C4—C5—H5A	121.5	C2—C1—N2	131.3 (4)
C6—C5—H5A	121.5	C2—C1—C6	119.7 (4)
N1—C6—C5	132.5 (4)	N2—C1—C6	109.0 (4)
N2i—Cd1—O3—N4	88.5 (4)	C2—C3—C4—C5	0.3 (8)
N2—Cd1—O3—N4	−91.5 (4)	C1—N2—C7—N1	−1.5 (5)
N3i—Cd1—O3—N4	13.3 (4)	Cd1—N2—C7—N1	177.7 (3)
N3—Cd1—O3—N4	−166.7 (4)	C1—N2—C7—C8	175.2 (5)
O3i—Cd1—O3—N4	−136 (100)	Cd1—N2—C7—C8	−5.6 (6)
Cd1—O3—N4—O1	−0.9 (6)	C6—N1—C7—N2	1.2 (5)
Cd1—O3—N4—O2	−179.9 (3)	C6—N1—C7—C8	−175.7 (4)
N2i—Cd1—N3—C11	51.1 (5)	C4—C3—C2—C1	−0.6 (8)
N2—Cd1—N3—C11	−128.9 (5)	C11—N3—C8—C9	7.3 (6)
N3i—Cd1—N3—C11	137 (16)	Cd1—N3—C8—C9	−131.4 (4)
O3—Cd1—N3—C11	−38.0 (5)	C11—N3—C8—C7	132.7 (5)
O3i—Cd1—N3—C11	142.0 (5)	Cd1—N3—C8—C7	−6.0 (5)
N2i—Cd1—N3—C8	−177.1 (3)	N2—C7—C8—N3	8.1 (7)
N2—Cd1—N3—C8	2.9 (3)	N1—C7—C8—N3	−175.4 (4)
N3i—Cd1—N3—C8	−91 (16)	N2—C7—C8—C9	128.7 (5)
O3—Cd1—N3—C8	93.8 (4)	N1—C7—C8—C9	−54.9 (7)
O3i—Cd1—N3—C8	−86.2 (4)	N3—C8—C9—C10	−26.8 (6)
N2i—Cd1—N2—C7	61 (100)	C7—C8—C9—C10	−150.1 (5)
N3i—Cd1—N2—C7	−178.9 (3)	C11—C10—C9—C8	35.0 (7)
N3—Cd1—N2—C7	1.1 (3)	C8—N3—C11—C10	15.2 (7)
O3—Cd1—N2—C7	−84.3 (3)	Cd1—N3—C11—C10	149.7 (4)
O3i—Cd1—N2—C7	95.7 (3)	C9—C10—C11—N3	−31.1 (7)
N2i—Cd1—N2—C1	−120 (100)	C3—C2—C1—N2	179.7 (5)
N3i—Cd1—N2—C1	−0.1 (5)	C3—C2—C1—C6	0.5 (7)
N3—Cd1—N2—C1	179.9 (5)	C7—N2—C1—C2	−178.0 (5)
O3—Cd1—N2—C1	94.5 (5)	Cd1—N2—C1—C2	3.2 (8)
O3i—Cd1—N2—C1	−85.5 (5)	C7—N2—C1—C6	1.3 (5)
C7—N1—C6—C5	178.6 (5)	Cd1—N2—C1—C6	−177.6 (3)
C7—N1—C6—C1	−0.3 (5)	N1—C6—C1—C2	178.8 (4)
C4—C5—C6—N1	−178.7 (5)	C5—C6—C1—C2	−0.3 (7)
C4—C5—C6—C1	0.0 (7)	N1—C6—C1—N2	−0.6 (5)
C6—C5—C4—C3	−0.1 (7)	C5—C6—C1—N2	−179.6 (4)

D—H···A	D—H	H···A	D···A	D—H···A
N3—H3B···O1i	0.91	2.21	2.975 (7)	141
N1—H1A···O2ii	0.86	2.03	2.889 (5)	174

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N3—H3B⋯O1i	0.91	2.21	2.975 (7)	141
N1—H1A⋯O2ii	0.86	2.03	2.889 (5)	174

Symmetry codes: (i) ; (ii) .