Literature DB >> 20684538

Cyclic alternating ring-opening metathesis polymerization (CAROMP). Rapid access to functionalized cyclic polymers.

Airong Song1, Kathlyn A Parker, Nicole S Sampson.   

Abstract

Catalysis of alternating ROMP with (H(2)IMes)Cl(2)Ru=CHPh(OiPr), the second generation Hoveyda-Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.

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Year:  2010        PMID： 20684538      PMCID： PMC2933648          DOI： 10.1021/ol101432m

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  15 in total

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  6 in total

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4.  Synthesis of Cis,syndiotactic A-alt-B Copolymers from Two Enantiomerically Pure Trans-2,3-Disubstituted-5,6-Norbornenes.

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6.  Ru-Catalyzed Isomerization Provides Access to Alternating Copolymers via Ring-Opening Metathesis Polymerization.

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