Literature DB >> 20623567

Enantioselective reduction of ketones and imines catalyzed by (CN-box)Re(V)-oxo complexes.

Kristine A Nolin1, Richard W Ahn, Yusuke Kobayashi, Joshua J Kennedy-Smith, F Dean Toste.   

Abstract

The development and application of chiral, non-racemic Re(V)-oxo complexes to the enantioselective reduction of prochiral ketones is described. In addition to the enantioselective reduction of prochiral ketones, we report the application of these complexes to 1) a tandem Meyer-Schuster rearrangement/reduction to access enantioenriched allylic alcohols and 2) the enantioselective reduction of imines.

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Year:  2010        PMID： 20623567      PMCID： PMC3517119          DOI： 10.1002/chem.201001164

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  29 in total

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2.  Hydrogen production from hydrolytic oxidation of organosilanes using a cationic oxorhenium catalyst.

Authors:  Elon A Ison; Rex A Corbin; Mahdi M Abu-Omar
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4.  Iron-catalyzed enantioselective hydrosilylation of ketones.

Authors:  Nadim S Shaikh; Stephan Enthaler; Kathrin Junge; Matthias Beller
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5.  Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex.

Authors:  Kristine A Nolin; Richard W Ahn; F Dean Toste
Journal:  J Am Chem Soc       Date:  2005-09-14       Impact factor: 15.419

6.  A Re(V)-catalyzed C-N bond-forming route to human lipoxygenase inhibitors.

Authors:  Rachana V Ohri; Alexander T Radosevich; K James Hrovat; Christine Musich; David Huang; Theodore R Holman; F Dean Toste
Journal:  Org Lett       Date:  2005-06-09       Impact factor: 6.005

7.  A method for the asymmetric hydrosilylation of N-aryl imines.

Authors:  M C Hansen; S L Buchwald
Journal:  Org Lett       Date:  2000-03-09       Impact factor: 6.005

8.  Catalytic enantioselective Strecker reaction of ketoimines.

Authors:  Shuji Masumoto; Hiroyuki Usuda; Masato Suzuki; Motomu Kanai; Masakatsu Shibasaki
Journal:  J Am Chem Soc       Date:  2003-05-14       Impact factor: 15.419

9.  Enantioselective borohydride reduction catalyzed by optically active cobalt complexes.

Authors:  Tohru Yamada; Takushi Nagata; Kiyoaki D Sugi; Kiyotaka Yorozu; Taketo Ikeno; Yuhki Ohtsuka; Daichi Miyazaki; Teruaki Mukaiyama
Journal:  Chemistry       Date:  2003-09-22       Impact factor: 5.236

10.  Highly chemo- and regioselective reduction of aromatic nitro compounds using the system silane/oxo-rhenium complexes.

Authors:  Rita G de Noronha; Carlos C Romão; Ana C Fernandes
Journal:  J Org Chem       Date:  2009-09-18       Impact factor: 4.354
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  5 in total

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2.  Mechanistic analysis and optimization of the copper-catalyzed enantioselective intramolecular alkene aminooxygenation.

Authors:  Monissa C Paderes; Jerome B Keister; Sherry R Chemler
Journal:  J Org Chem       Date:  2012-12-28       Impact factor: 4.354

Review 3.  Hydrosilylation Reactions Catalyzed by Rhenium.

Authors:  Duo Wei; Ruqaya Buhaibeh; Yves Canac; Jean-Baptiste Sortais
Journal:  Molecules       Date:  2021-04-29       Impact factor: 4.411

4.  Enantioselective hydrosilylation of unsaturated carbon-heteroatom bonds (C[double bond, length as m-dash]N, C[double bond, length as m-dash]O) catalyzed by [Ru-S] complexes: a theoretical study.

Authors:  Miao-Miao Zhou; Guanghui Chen; Li Dang
Journal:  RSC Adv       Date:  2020-03-04       Impact factor: 4.036

5.  Bifunctional thiosquaramide catalyzed asymmetric reduction of dihydro-β-carbolines and enantioselective synthesis of (-)-coerulescine and (-)-horsfiline by oxidative rearrangement.

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  5 in total

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