Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Hydrosilylation Reactions Catalyzed by Rhenium.

Literature DB >> 33946880

Hydrosilylation Reactions Catalyzed by Rhenium.

Duo Wei^1,2, Ruqaya Buhaibeh², Yves Canac², Jean-Baptiste Sortais^2,3.

Abstract

Hydrosilylation is an important process, not only in the silicon industry to produce silicon polymers, but also in fine chemistry. In this review, the development of rhenium-based catalysts for the hydrosilylation of unsaturated bonds in carbonyl-, cyano-, nitro-, carboxylic acid derivatives and alkenes is summarized. Mechanisms of rhenium-catalyzed hydrosilylation are discussed.

Entities: Chemical Disease Gene

Keywords: alkenes; carbonyls; hydrosilylation; rhenium; unsaturated bonds

Year: 2021 PMID： 33946880 DOI： 10.3390/molecules26092598

Source DB: PubMed Journal: Molecules ISSN： 1420-3049 Impact factor: 4.411

25 in total

1. Rhenium(VII) Oxo and Imido Complexes: Synthesis, Structures, and Applications.

Authors: Carlos C. Romão; Fritz E. Kühn; Wolfgang A. Herrmann
Journal: Chem Rev Date: 1997-12-18 Impact factor: 60.622

2. Hydrogen production from hydrolytic oxidation of organosilanes using a cationic oxorhenium catalyst.

Authors: Elon A Ison; Rex A Corbin; Mahdi M Abu-Omar
Journal: J Am Chem Soc Date: 2005-08-31 Impact factor: 15.419

3. Earth-Abundant Transition Metal Catalysts for Alkene Hydrosilylation and Hydroboration: Opportunities and Assessments.

Authors: Jennifer V Obligacion; Paul J Chirik
Journal: Nat Rev Chem Date: 2018-04-27 Impact factor: 34.035

4. Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex.

Authors: Kristine A Nolin; Richard W Ahn; F Dean Toste
Journal: J Am Chem Soc Date: 2005-09-14 Impact factor: 15.419

5. Cationic rhenium(iii) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes.

Authors: Damaris E Pérez; Jessica L Smeltz; Roger D Sommer; Paul D Boyle; Elon A Ison
Journal: Dalton Trans Date: 2017-04-05 Impact factor: 4.390

6. Mechanistic insight into hydrosilylation reactions catalyzed by high valent ReX (X = O, NAr, or N) complexes: the silane (Si-H) does not add across the metal-ligand multiple bond.

Authors: Guodong Du; Phillip E Fanwick; Mahdi M Abu-Omar
Journal: J Am Chem Soc Date: 2007-03-28 Impact factor: 15.419

Hydrosilylation Reactions Catalyzed by Rhenium.

1. Rhenium(VII) Oxo and Imido Complexes: Synthesis, Structures, and Applications.

2. Hydrogen production from hydrolytic oxidation of organosilanes using a cationic oxorhenium catalyst.

3. Earth-Abundant Transition Metal Catalysts for Alkene Hydrosilylation and Hydroboration: Opportunities and Assessments.

4. Enantioselective reduction of imines catalyzed by a rhenium(V)-oxo complex.

5. Cationic rhenium(iii) complexes: synthesis, characterization, and reactivity for hydrosilylation of aldehydes.

6. Mechanistic insight into hydrosilylation reactions catalyzed by high valent ReX (X = O, NAr, or N) complexes: the silane (Si-H) does not add across the metal-ligand multiple bond.

7. Stereoselective direct reductive amination of ketones with electron-deficient amines using Re2O7/NaPF6 catalyst.

8. Highly chemo- and regioselective reduction of aromatic nitro compounds using the system silane/oxo-rhenium complexes.

9. Synthesis of cationic oxorhenium salen complexes via mu-oxo abstraction and their activity in catalytic reductions.

10. Rhenium-Catalyzed Reduction of Carboxylic Acids with Hydrosilanes.