Literature DB >> 10814417

A method for the asymmetric hydrosilylation of N-aryl imines.

M C Hansen1, S L Buchwald.   

Abstract

[reaction: see text] The asymmetric reduction of N-aryl imines to yield chiral amines with enantiomeric excesses above 90% was achieved. Ethylenebis(eta5-tetrahydroindenyl)titanium difluoride ((EBTHI)TiF2, 1) was employed as the precatalyst with polymethylhydrosiloxane (PMHS) as the stoichiometric reducing agent. A variety of N-aryl imines derived from nonaromatic ketones were reduced with high ee.

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Year:  2000        PMID： 10814417     DOI： 10.1021/ol005583w

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Enantioselective reduction of ketones and imines catalyzed by (CN-box)Re(V)-oxo complexes.

Authors:  Kristine A Nolin; Richard W Ahn; Yusuke Kobayashi; Joshua J Kennedy-Smith; F Dean Toste
Journal:  Chemistry       Date:  2010-08-16       Impact factor: 5.236

2.  Bifunctional catalysis: direct reductive amination of aliphatic ketones with an iridium-phosphate catalyst.

Authors:  Barbara Villa-Marcos; Chaoqun Li; Keith R Mulholland; Philip J Hogan; Jianliang Xiao
Journal:  Molecules       Date:  2010-04-08       Impact factor: 4.411

3.  Experimental and DFT Study of the Photoluminescent Green Emission Band of Halogenated (-F, -Cl, and -Br) Imines.

Authors:  Francisco J Melendez; María Eugenia Castro; Oscar Portillo-Moreno; Guadalupe Hernández-Téllez; Gloria E Moreno-Morales; Daniela Gutiérrez-Argüelles; Rodolfo Palomino-Merino; Efraín Rubio-Rosas; René Gutiérrez-Pérez
Journal:  Molecules       Date:  2019-09-11       Impact factor: 4.411
  3 in total

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