Literature DB >> 20441208

One-pot synthesis of a new magnetically coupled heterometallic Cu(2)Mn(2) [2 x 2] molecular grid.

Yurii S Moroz1, Łukasz Szyrwiel, Serhiy Demeshko, Henryk Kozłowski, Franc Meyer, Igor O Fritsky.   

Abstract

The heterometallic [2 x 2] grid-type complex [Cu(2)Mn(2)(pop)(4)(OAc)(4)].7H(2)O (1) has been selectively synthesized in a targeted one-pot reaction. Single-crystal X-ray analysis shows the expected structure with identical metal ions located at diagonal vertices of the grid. Magnetochemical studies reveal that 1 has a ferrimagnetic spin ground state with some admixture of low-lying excited states.

Entities:  

Mesh：

Substances：

Year:  2010        PMID： 20441208     DOI： 10.1021/ic100555s

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  24 in total

1.  Bis(2,2'-bipyridyl-κ(2) N,N')(sulfato-κ(2) O,O')nickel(II) 2.5-hydrate.

Authors:  Turganbay Iskenderov
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-05-31

2.  [Di-aqua-sesqui(nitrato-κO)hemi(perchlorato-κO)copper(II)]-μ-{bis-[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl] selenide}-[tri-aqua-(perchlorato-κO)copper(II)] nitrate monohydrate.

Authors:  Maksym Seredyuk; Vadim A Pavlenko; Kateryna O Znovjyak; Elzbieta Gumienna-Kontecka; Turganbay S Iskenderov
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-05-15

3.  Pyridinium bis-(pyridine-κN)tetra-kis-(thio-cyanato-κN)ferrate(III).

Authors:  Sergii I Shylin; Il'ya A Gural'skiy; Matti Haukka; Anatoliy A Kapshuk; Elena V Prisyazhnaya
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-05-04

4.  Tris(2,2'-bipyridine-κ(2)N,N')cobalt(III) bis-[bis-(pyridine-2,6-dicarboxyl-ato-κ(3)O(2),N,O(6))cobaltate(III)] perchlorate dimethyl-formamide hemisolvate 1.3-hydrate.

Authors:  Irina A Golenya; Alexander N Boyko; Natalia V Kotova; Matti Haukka; Turganbay S Iskenderov
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-09-01

5.  Poly[μ-aqua-diaquabis-[μ-2-cyano-2-(oxidoimino)-acetato]-copper(II)dipotassium].

Authors:  Irina A Golenya; Yulia A Izotova; Natalia I Usenko; Valentina A Kalibabchuk; Natalia V Kotova
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-09-26

6.  Diammine{N-[2-(hy-droxy-imino)-propion-yl]-N'-[2-(oxidoimino)-propion-yl]propane-1,3-diaminido-κ(4) N,N',N'',N'''}iron(III).

Authors:  Stefania Tomyn; Matti Haukka; Ruslan Nedelkov
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-11-30

7.  [Aqua-bis-(nitrato-κO)copper(II)]-μ-{bis-[5-methyl-3-(pyridin-2-yl)-1H-pyrazol-4-yl]selenide}-[diaqua-(nitrato-κO)copper(II)] nitrate monohydrate.

Authors:  Maksym Seredyuk; Vadim A Pavlenko; Elzbieta Gumienna-Kontecka; Turganbay S Iskenderov
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-11-14

8.  Bis-{(E)-3-[2-(hy-droxy-imino)-propan-amido]-2,2-dimethyl-propan-1-aminium} bis[μ-(E)-N-(3-amino-2,2-dimethyl-prop-yl)-2-(hy-droxy-imino)-propanamido-(2-)]bis-{[(E)-N-(3-amino-2,2-dimethyl-prop-yl)-2-(hy-droxy-imino)-propanamide]-copper(II)} bis-((E)-{3-[2-(hy-droxy-imino)-propanamido]-2,2-dimethyl-prop-yl}carbamate) acetonitrile disolvate.

Authors:  Andrii I Buvailo; Anna V Pavlishchuk; Larysa V Penkova; Natalia V Kotova; Matti Haukka
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-11-14

9.  A second monoclinic polymorph of 2-(3,5-dimethyl-1H-pyrazol-1-yl)-2-hy-droxy-imino-N'-[1-(pyridin-2-yl)ethyl-idene]acetohydrazide.

Authors:  Maxym O Plutenko; Rostislav D Lampeka; Matti Haukka; Ebbe Nordlander
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-04-20

10.  Pyridinium bis-(pyridine-κN)tetra-kis-(thio-cyanato-κN)ferrate(III)-pyrazine-2-carbo-nitrile-pyridine (1/4/1).

Authors:  Sergii I Shylin; Il'ya A Gural'skiy; Matti Haukka; Irina A Golenya
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-04-20
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.