Literature DB >> 20364834

Cationic Pd(II)-catalyzed Fujiwara-Moritani reactions at room temperature in water.

Takashi Nishikata1, Bruce H Lipshutz.   

Abstract

Pd(II)-catalyzed Fujiwara-Moritani reactions can be carried out without external acid at room temperature and in water as the only medium. A highly active cationic Pd(II) catalyst, [Pd(MeCN)(4)](BF(4))(2), easily activates aromatic C-H bonds to produce electron-rich cinnamates in good yields.

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Year:  2010        PMID: 20364834      PMCID: PMC3152461          DOI: 10.1021/ol100331h

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  35 in total

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Journal:  J Am Chem Soc       Date:  2002-02-27       Impact factor: 15.419

4.  Palladium-catalyzed direct arylation of simple arenes in synthesis of biaryl molecules.

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Journal:  Chem Commun (Camb)       Date:  2006-01-30       Impact factor: 6.222

5.  Palladium-catalyzed C-H functionalization of pyridine N-oxides: highly selective alkenylation and direct arylation with unactivated arenes.

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7.  Zn-mediated, Pd-catalyzed cross-couplings in water at room temperature without prior formation of organozinc reagents.

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Review 8.  Organic synthesis "on water".

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9.  Direct and regioselective C-H alkenylation of tetrahydropyrido[1,2-a]pyrimidines.

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Journal:  Org Lett       Date:  2009-06-18       Impact factor: 6.005

10.  Direct coupling of benzene with olefin catalyzed by Pd(OAc)(2) combined with heteropolyoxometalate under dioxygen.

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  10 in total

1.  "Designer"-Surfactant-Enabled Cross-Couplings in Water at Room Temperature.

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2.  Ligand-Accelerated ortho-C-H Olefination of Phenylacetic Acids.

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3.  Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation.

Authors:  Andy S Tsai; Mikaël Brasse; Robert G Bergman; Jonathan A Ellman
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4.  Manipulating micellar environments for enhancing transition metal-catalyzed cross-couplings in water at room temperature.

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5.  Ligand-accelerated C-H activation reactions: evidence for a switch of mechanism.

Authors:  Keary M Engle; Dong-Hui Wang; Jin-Quan Yu
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6.  N-acylsulfonamide assisted tandem C-H olefination/annulation: synthesis of isoindolinones.

Authors:  Chen Zhu; J R Falck
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7.  Palladium(II)-catalyzed dehydrogenative alkenylation of cyclic enaminones via the Fujiwara-Moritani reaction.

Authors:  Yi-Yun Yu; Micah J Niphakis; Gunda I Georg
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8.  Aerobic Pd-catalyzed sp3 C-H olefination: a route to both N-heterocyclic scaffolds and alkenes.

Authors:  Kara J Stowers; Kevin C Fortner; Melanie S Sanford
Journal:  J Am Chem Soc       Date:  2011-04-08       Impact factor: 15.419

9.  para-Selective C-H Olefination of Aniline Derivatives via Pd/S,O-Ligand Catalysis.

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10.  Cationic Pd(II)-catalyzed C-H activation/cross-coupling reactions at room temperature: synthetic and mechanistic studies.

Authors:  Takashi Nishikata; Alexander R Abela; Shenlin Huang; Bruce H Lipshutz
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  10 in total

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