Literature DB >> 20358569

The fundamental role of exchange-enhanced reactivity in C-H activation by S=2 oxo iron(IV) complexes.

Deepa Janardanan1, Yong Wang, Patric Schyman, Lawrence Que, Sason Shaik.   

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Year:  2010        PMID： 20358569      PMCID： PMC2882195          DOI： 10.1002/anie.201000004

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


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  18 in total

1.  Two-state reactivity in alkane hydroxylation by non-heme iron-oxo complexes.

Authors:  Hajime Hirao; Devesh Kumar; Lawrence Que; Sason Shaik
Journal:  J Am Chem Soc       Date:  2006-07-05       Impact factor: 15.419

Review 2.  High-valent nonheme iron-oxo species in biomimetic oxidations.

Authors:  Xiaopeng Shan; Lawrence Que
Journal:  J Inorg Biochem       Date:  2006-03-13       Impact factor: 4.155

Review 3.  The road to non-heme oxoferryls and beyond.

Authors:  Lawrence Que
Journal:  Acc Chem Res       Date:  2007-06-27       Impact factor: 22.384

4.  Quantifying the effects of the self-interaction error in density functional theory: when do the delocalized states appear? II. Iron-oxo complexes and closed-shell substrate molecules.

Authors:  Adam Johannes Johansson; Margareta R A Blomberg; Per E M Siegbahn
Journal:  J Chem Phys       Date:  2008-10-21       Impact factor: 3.488

5.  Quantum chemical studies of C-H activation reactions by high-valent nonheme iron centers.

Authors:  Shengfa Ye; Frank Neese
Journal:  Curr Opin Chem Biol       Date:  2009-03-09       Impact factor: 8.822

6.  Spectroscopic and computational evaluation of the structure of the high-spin Fe(IV)-oxo intermediates in taurine: alpha-ketoglutarate dioxygenase from Escherichia coli and its His99Ala ligand variant.

Authors:  Sebastian Sinnecker; Nina Svensen; Eric W Barr; Shengfa Ye; J Martin Bollinger; Frank Neese; Carsten Krebs
Journal:  J Am Chem Soc       Date:  2007-04-24       Impact factor: 15.419

7.  Evidence for hydrogen abstraction from C1 of taurine by the high-spin Fe(IV) intermediate detected during oxygen activation by taurine:alpha-ketoglutarate dioxygenase (TauD).

Authors:  John C Price; Eric W Barr; Timothy E Glass; Carsten Krebs; J Martin Bollinger
Journal:  J Am Chem Soc       Date:  2003-10-29       Impact factor: 15.419

8.  A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity.

Authors:  Jason England; Marlène Martinho; Erik R Farquhar; Jonathan R Frisch; Emile L Bominaar; Eckard Münck; Lawrence Que
Journal:  Angew Chem Int Ed Engl       Date:  2009       Impact factor: 15.336

Review 9.  High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions.

Authors:  Wonwoo Nam
Journal:  Acc Chem Res       Date:  2007-05-01       Impact factor: 22.384

10.  The first direct characterization of a high-valent iron intermediate in the reaction of an alpha-ketoglutarate-dependent dioxygenase: a high-spin FeIV complex in taurine/alpha-ketoglutarate dioxygenase (TauD) from Escherichia coli.

Authors:  John C Price; Eric W Barr; Bhramara Tirupati; J Martin Bollinger; Carsten Krebs
Journal:  Biochemistry       Date:  2003-06-24       Impact factor: 3.162
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  20 in total

1.  Exchange-enhanced reactivity in bond activation by metal-oxo enzymes and synthetic reagents.

Authors:  Sason Shaik; Hui Chen; Deepa Janardanan
Journal:  Nat Chem       Date:  2010-12-15       Impact factor: 24.427

2.  Dichotomous hydrogen atom transfer vs proton-coupled electron transfer during activation of X-H bonds (X = C, N, O) by nonheme iron-oxo complexes of variable basicity.

Authors:  Dandamudi Usharani; David C Lacy; A S Borovik; Sason Shaik
Journal:  J Am Chem Soc       Date:  2013-11-04       Impact factor: 15.419

3.  Facile and Reversible Formation of Iron(III)-Oxo-Cerium(IV) Adducts from Nonheme Oxoiron(IV) Complexes and Cerium(III).

Authors:  Apparao Draksharapu; Waqas Rasheed; Johannes E M N Klein; Lawrence Que
Journal:  Angew Chem Int Ed Engl       Date:  2017-06-27       Impact factor: 15.336

4.  A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site.

Authors:  Jason England; Yisong Guo; Katherine M Van Heuvelen; Matthew A Cranswick; Gregory T Rohde; Emile L Bominaar; Eckard Münck; Lawrence Que
Journal:  J Am Chem Soc       Date:  2011-07-19       Impact factor: 15.419

5.  Substrate placement influences reactivity in non-heme Fe(II) halogenases and hydroxylases.

Authors:  Heather J Kulik; Catherine L Drennan
Journal:  J Biol Chem       Date:  2013-02-28       Impact factor: 5.157

6.  Do Spin State and Spin Density Affect Hydrogen Atom Transfer Reactivity?

Authors:  Caroline T Saouma; James M Mayer
Journal:  Chem Sci       Date:  2014-01-01       Impact factor: 9.825

Review 7.  The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes.

Authors:  Johannes Hohenberger; Kallol Ray; Karsten Meyer
Journal:  Nat Commun       Date:  2012-03-06       Impact factor: 14.919

8.  [Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.

Authors:  Samuel A Wilson; Junying Chen; Seungwoo Hong; Yong-Min Lee; Martin Clémancey; Ricardo Garcia-Serres; Takashi Nomura; Takashi Ogura; Jean-Marc Latour; Britt Hedman; Keith O Hodgson; Wonwoo Nam; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2012-07-06       Impact factor: 15.419

9.  Nonheme oxo-iron(IV) intermediates form an oxyl radical upon approaching the C-H bond activation transition state.

Authors:  Shengfa Ye; Frank Neese
Journal:  Proc Natl Acad Sci U S A       Date:  2011-01-10       Impact factor: 11.205

10.  Nuclear resonance vibrational spectroscopy on the Fe(IV)=O S=2 non-heme site in TMG3tren: experimentally calibrated insights into reactivity.

Authors:  Shaun D Wong; Caleb B Bell; Lei V Liu; Yeonju Kwak; Jason England; E Ercan Alp; Jiyong Zhao; Lawrence Que; Edward I Solomon
Journal:  Angew Chem Int Ed Engl       Date:  2011-03-02       Impact factor: 15.336
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