High versus low: The high-yield generation of a synthetic high-spin oxoiron(IV) complex, [Fe(IV)(O)(TMG(3)tren)](2+) (see picture, TMG(3)tren = 1,1,1-tris{2-[N2-(1,1,3,3-tetramethylguanidino)]ethyl}amine), has been achieved by using the very bulky tetradentate TMG(3)tren ligand, in order to both sterically protect the oxoiron(IV) moiety and enforce a trigonal bipyramidal geometry at the iron center, for which an S = 2 ground state is favored.
High versus low: The high-yield generation of a synthetic high-spin oxoiron(IV) complex, [n class="Chemical">Fe(IV)(O)(TMG(3)tren)](2+) (see picture, TMG(3)tren = 1,1,1-tris{2-[N2-(1,1,3,3-tetramethylguanidino)]ethyl}amine), has been achieved by using the very bulky tetradentate TMG(3)tren ligand, in order to both sterically protect the oxoiron(IV) moiety and enforce a trigonal bipyramidal geometry at the iron center, for which an S = 2 ground state is favored.
Authors: József Kaizer; Eric J Klinker; Na Young Oh; Jan-Uwe Rohde; Woon Ju Song; Audria Stubna; Jinheung Kim; Eckard Münck; Wonwoo Nam; Lawrence Que Journal: J Am Chem Soc Date: 2004-01-21 Impact factor: 15.419
Authors: Eric J Klinker; József Kaizer; William W Brennessel; Nathaniel L Woodrum; Christopher J Cramer; Lawrence Que Journal: Angew Chem Int Ed Engl Date: 2005-06-13 Impact factor: 15.336
Authors: Jan-Uwe Rohde; Stéphane Torelli; Xiaopeng Shan; Mi Hee Lim; Eric J Klinker; József Kaizer; Kui Chen; Wonwoo Nam; Lawrence Que Journal: J Am Chem Soc Date: 2004-12-29 Impact factor: 15.419
Authors: Mi Hee Lim; Jan-Uwe Rohde; Audria Stubna; Michael R Bukowski; Miquel Costas; Raymond Y N Ho; Eckard Munck; Wonwoo Nam; Lawrence Que Journal: Proc Natl Acad Sci U S A Date: 2003-03-18 Impact factor: 11.205
Authors: Pamela J Riggs-Gelasco; John C Price; Robert B Guyer; Jessica H Brehm; Eric W Barr; J Martin Bollinger; Carsten Krebs Journal: J Am Chem Soc Date: 2004-07-07 Impact factor: 15.419
Authors: Denis A Proshlyakov; Timothy F Henshaw; Greta R Monterosso; Matthew J Ryle; Robert P Hausinger Journal: J Am Chem Soc Date: 2004-02-04 Impact factor: 15.419
Authors: Sonja Herres-Pawlis; Pratik Verma; Roxana Haase; Peng Kang; Christopher T Lyons; Erik C Wasinger; Ulrich Flörke; Gerald Henkel; T Daniel P Stack Journal: J Am Chem Soc Date: 2009-01-28 Impact factor: 15.419
Authors: P Chandrasekaran; S Chantal E Stieber; Terrence J Collins; Lawrence Que; Frank Neese; Serena DeBeer Journal: Dalton Trans Date: 2011-09-29 Impact factor: 4.390
Authors: Dong Wang; Kallol Ray; Michael J Collins; Erik R Farquhar; Jonathan R Frisch; Laura Gómez; Timothy A Jackson; Marion Kerscher; Arkadius Waleska; Peter Comba; Miquel Costas; Lawrence Que Journal: Chem Sci Date: 2013-01 Impact factor: 9.825