Literature DB >> 20148557

Palladium-catalyzed intermolecular aminofluorination of styrenes.

Shuifa Qiu1, Tao Xu, Juan Zhou, Yinlong Guo, Guosheng Liu.   

Abstract

A novel palladium-catalyzed intermolecular aminofluorination of styrenes, with N-fluorobenzenesulfonimide (NFSI) functioning not only as a fluorinating reagent but also as an aminating reagent, has been developed. The reaction afforded vicinal fluoroamine products with very high regioselectivity. This transformation may involve fluoropalladation of styrene as a key step for C-F bond formation. The bidental nitrogen ligand is crucial to achieving the transformation successfully.

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Year:  2010        PMID： 20148557     DOI： 10.1021/ja909716k

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  20 in total

1.  Palladium(II)-catalyzed enantio- and diastereoselective synthesis of pyrrolidine derivatives.

Authors:  Ranjan Jana; Tejas P Pathak; Katrina H Jensen; Matthew S Sigman
Journal:  Org Lett       Date:  2012-08-08       Impact factor: 6.005

2.  A palladium-catalyzed three-component cross-coupling of conjugated dienes or terminal alkenes with vinyl triflates and boronic acids.

Authors:  Longyan Liao; Ranjan Jana; Kaveri Balan Urkalan; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2011-03-30       Impact factor: 15.419

3.  Organocatalytic enantioselective olefin aminofluorination.

Authors:  Chandrakumar Appayee; Stacey E Brenner-Moyer
Journal:  Org Lett       Date:  2010-08-06       Impact factor: 6.005

4.  Steric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible.

Authors:  Shu-Bin Zhao; Jennifer J Becker; Michel R Gagné
Journal:  Organometallics       Date:  2011-08-08       Impact factor: 3.876

5.  Copper-Catalyzed 1,2-Aminocyanation of Unactivated Alkenes via Cyano Migration.

Authors:  Yungeun Kwon; Qiu Wang
Journal:  Org Lett       Date:  2020-05-08       Impact factor: 6.005

6.  Catalytic Aminohalogenation of Alkenes and Alkynes.

Authors:  Sherry R Chemler; Michael T Bovino
Journal:  ACS Catal       Date:  2013-06-07       Impact factor: 13.084

7.  Advancing the mechanistic understanding of an enantioselective palladium-catalyzed alkene difunctionalization reaction.

Authors:  Katrina H Jensen; Jonathan D Webb; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2010-11-17       Impact factor: 15.419

8.  Iron(II)-Catalyzed Intermolecular Aminofluorination of Unfunctionalized Olefins Using Fluoride Ion.

Authors:  Deng-Fu Lu; Cheng-Liang Zhu; Jeffrey D Sears; Hao Xu
Journal:  J Am Chem Soc       Date:  2016-08-26       Impact factor: 15.419

9.  Asymmetric chiral ligand-directed alkene dioxygenation.

Authors:  Sharon R Neufeldt; Melanie S Sanford
Journal:  Org Lett       Date:  2012-12-18       Impact factor: 6.005

10.  Catalytic enantioselective cyclization and C3-fluorination of polyenes.

Authors:  Nikki A Cochrane; Ha Nguyen; Michel R Gagne
Journal:  J Am Chem Soc       Date:  2013-01-08       Impact factor: 15.419
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