| Literature DB >> 20121138 |
Thomas W Woolerton1, Sally Sheard, Erwin Reisner, Elizabeth Pierce, Stephen W Ragsdale, Fraser A Armstrong.
Abstract
A hybrid enzyme-nanoparticle system is described for achieving clean reduction of CO(2) to CO using visible light as the energy source. An aqueous dispersion of TiO(2) nanoparticles modified by attachment of carbon monoxide dehydrogenase (CODH) and a Ru photosensitizer produces CO at a rate of 250 mumol of CO (g of TiO(2))(-1) h(-1) when illuminated with visible light at pH 6 and 20 degrees C.Entities:
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Year: 2010 PMID: 20121138 PMCID: PMC2845288 DOI: 10.1021/ja910091z
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419