| Literature DB >> 19459617 |
Sayan Bagchi1, Adam K Charnley, Amos B Smith Iii, Robin M Hochstrasser.
Abstract
The tryptophan dipeptide (NATMA) in D2O shows two conformers having distinctive acetyl end amide-I' transition frequencies. In 2D echo spectroscopy, cross peaks between these conformer transitions are used to show that they are undergoing exchange on the 1.5 ps time scale. Simulations suggest that the accessibility of the amide group to water is restricted in one of the conformations.Entities:
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Year: 2009 PMID: 19459617 PMCID: PMC2929808 DOI: 10.1021/jp811168x
Source DB: PubMed Journal: J Phys Chem B ISSN: 1520-5207 Impact factor: 2.991