| Literature DB >> 19425036 |
Andrea C Montenegro1, Valentín T Amorebieta, Leonardo D Slep, Diego F Martín, Federico Roncaroli, Daniel H Murgida, Sara E Bari, José A Olabe.
Abstract
Not so elusive: [Fe(II)(CN)(5)(HNO)](3-) has been characterized spectroscopically after the two-electron reduction of nitroprusside (see scheme). The complex is stable at pH 6, slowly decomposing to [Fe(CN)(6)](4-) and N(2)O. It is deprotonated at increasing pH value with oxidation of bound NO(-) to [Fe(II)(CN)(5)(NO)](3-). [Fe(II)(CN)(5)(HNO)](3-) is the first non-heme iron-nitroxyl complex prepared in aqueous solution that is reversibly redox-active under biologically relevant conditions.Entities:
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Year: 2009 PMID: 19425036 DOI: 10.1002/anie.200806229
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336