| Literature DB >> 19275406 |
David S Dean1, Ron R Horgan, Ali Naji, Rudolf Podgornik.
Abstract
We evaluate exactly the statistical integral for an inhomogeneous one-dimensional (1D) counterion-only Coulomb gas between two charged boundaries and from this compute the effective interaction, or disjoining pressure, between the bounding surfaces. Our exact results are compared to the limiting cases of weak and strong couplings which are the same for 1D and three-dimensional (3D) systems. For systems with a large number of counterions it is found that the weak-coupling (mean-field) approximation for the disjoining pressure works perfectly and that fluctuations around the mean-field in 1D are much smaller than in 3D. In the case of few counterions it works less well and strong-coupling approximation performs much better as it takes into account properly the discreteness of the counterion charges.Mesh:
Substances:
Year: 2009 PMID: 19275406 PMCID: PMC2671686 DOI: 10.1063/1.3078492
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488