Literature DB >> 19275406

One-dimensional counterion gas between charged surfaces: exact results compared with weak- and strong-coupling analyses.

David S Dean1, Ron R Horgan, Ali Naji, Rudolf Podgornik.   

Abstract

We evaluate exactly the statistical integral for an inhomogeneous one-dimensional (1D) counterion-only Coulomb gas between two charged boundaries and from this compute the effective interaction, or disjoining pressure, between the bounding surfaces. Our exact results are compared to the limiting cases of weak and strong couplings which are the same for 1D and three-dimensional (3D) systems. For systems with a large number of counterions it is found that the weak-coupling (mean-field) approximation for the disjoining pressure works perfectly and that fluctuations around the mean-field in 1D are much smaller than in 3D. In the case of few counterions it works less well and strong-coupling approximation performs much better as it takes into account properly the discreteness of the counterion charges.

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Year:  2009        PMID: 19275406      PMCID: PMC2671686          DOI: 10.1063/1.3078492

Source DB:  PubMed          Journal:  J Chem Phys        ISSN: 0021-9606            Impact factor:   3.488


  13 in total

1.  Modes of counterion density fluctuations and counterion-mediated attractions between like-charged fluid membranes.

Authors:  B Y Ha
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2001-08-30

2.  Field theoretic derivation of the contact value theorem in planar geometries and its modification by the Casimir effect.

Authors:  D S Dean; R R Horgan
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2003-12-24

3.  Counterion condensation and fluctuation-induced attraction.

Authors:  A W C Lau; P Pincus
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2002-10-07

4.  Simulations of counterions at charged plates.

Authors:  A G Moreira; R R Netz
Journal:  Eur Phys J E Soft Matter       Date:  2002-05       Impact factor: 1.890

5.  Effects of dielectric discontinuities on two charged plates.

Authors:  Y S Jho; G Park; C S Chang; P A Pincus; M W Kim
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2007-07-26

6.  Local molecular field theory for effective attractions between like charged objects in systems with strong Coulomb interactions.

Authors:  Yng-Gwei Chen; John D Weeks
Journal:  Proc Natl Acad Sci U S A       Date:  2006-05-02       Impact factor: 11.205

7.  Computing counterion densities at intermediate coupling.

Authors:  Christian D Santangelo
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2006-04-25

8.  Attraction between like-charged walls: Short-ranged simulations using local molecular field theory.

Authors:  Jocelyn M Rodgers; Charanbir Kaur; Yng-Gwei Chen; John D Weeks
Journal:  Phys Rev Lett       Date:  2006-08-28       Impact factor: 9.161

9.  Electrostatic image effects for counterions between charged planar walls.

Authors:  M Kanduc; R Podgornik
Journal:  Eur Phys J E Soft Matter       Date:  2007-07-20       Impact factor: 1.890

10.  Weak- and strong-coupling electrostatic interactions between asymmetrically charged planar surfaces.

Authors:  M Kanduc; M Trulsson; A Naji; Y Burak; J Forsman; R Podgornik
Journal:  Phys Rev E Stat Nonlin Soft Matter Phys       Date:  2008-12-05
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  2 in total

1.  Counter-ions at single charged wall: Sum rules.

Authors:  Ladislav Samaj
Journal:  Eur Phys J E Soft Matter       Date:  2013-09-19       Impact factor: 1.890

2.  Counter-ions at charged walls: two-dimensional systems.

Authors:  L Samaj; E Trizac
Journal:  Eur Phys J E Soft Matter       Date:  2011-02-28       Impact factor: 1.890

  2 in total

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