Literature DB >> 16711814

Computing counterion densities at intermediate coupling.

Christian D Santangelo1.   

Abstract

By decomposing the Coulomb interaction into a long-distance component appropriate for mean-field theory, and a non-mean-field short distance component, we compute the counterion density near a charged surface for all values of the counterion coupling parameter. A modified strong-coupling expansion that is manifestly finite at all coupling strengths is used to treat the short-distance component. We find a nonperturbative correction related to the lateral counterion correlations that modifies the density at intermediate coupling.

Year:  2006        PMID: 16711814     DOI: 10.1103/PhysRevE.73.041512

Source DB:  PubMed          Journal:  Phys Rev E Stat Nonlin Soft Matter Phys        ISSN: 1539-3755


  5 in total

1.  One-dimensional counterion gas between charged surfaces: exact results compared with weak- and strong-coupling analyses.

Authors:  David S Dean; Ron R Horgan; Ali Naji; Rudolf Podgornik
Journal:  J Chem Phys       Date:  2009-03-07       Impact factor: 3.488

2.  Lamellar phase coexistence induced by electrostatic interactions.

Authors:  Y S Jho; M W Kim; S A Safran; P A Pincus
Journal:  Eur Phys J E Soft Matter       Date:  2010-02-18       Impact factor: 1.890

3.  Counter-ions at charged walls: two-dimensional systems.

Authors:  L Samaj; E Trizac
Journal:  Eur Phys J E Soft Matter       Date:  2011-02-28       Impact factor: 1.890

Review 4.  Molecular Mean-Field Theory of Ionic Solutions: A Poisson-Nernst-Planck-Bikerman Model.

Authors:  Jinn-Liang Liu; Bob Eisenberg
Journal:  Entropy (Basel)       Date:  2020-05-14       Impact factor: 2.524

5.  The Role of Energy Scales for the Structure of Ionic Liquids at Electrified Interfaces: A Theory-Based Approach.

Authors:  Max Schammer; Arnulf Latz; Birger Horstmann
Journal:  J Phys Chem B       Date:  2022-04-01       Impact factor: 3.466

  5 in total

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