Literature DB >> 21359929

Counter-ions at charged walls: two-dimensional systems.

L Samaj1, E Trizac.   

Abstract

We study equilibrium statistical mechanics of classical point counter-ions, formulated on 2D Euclidean space with logarithmic Coulomb interactions (infinite number of particles) or on the cylinder surface (finite particle numbers), in the vicinity of a single uniformly charged line (one single double layer), or between two such lines (interacting double layers). The weak-coupling Poisson-Boltzmann theory, which applies when the coupling constant [Formula: see text] is small, is briefly recapitulated (the coupling constant is defined as [Formula: see text] [Formula: see text] [Formula: see text] e (2) , where [Formula: see text] is the inverse temperature, and e the counter-ion charge). The opposite limit ( [Formula: see text] [Formula: see text] ∞ is treated by using a recent method based on an exact expansion around the ground-state Wigner crystal of counter-ions. These two limiting results are compared at intermediary values of the coupling constant [Formula: see text] = 2[Formula: see text] ([Formula: see text] = 1, 2, 3) , to exact results derived within a 1D lattice representation of 2D Coulomb systems in terms of anti-commuting field variables. The models (density profile, pressure) are solved exactly for any particles numbers N at [Formula: see text] = 2 and up to relatively large finite N at [Formula: see text] = 4 and 6. For the one-line geometry, the decay of the density profile at asymptotic distance from the line undergoes a fundamental change with respect to the mean-field behavior at [Formula: see text] = 6 . The like-charge attraction regime, possible for large [Formula: see text] but precluded at mean-field level, survives for [Formula: see text] = 4 and 6, but disappears at [Formula: see text] = 2 .

Year:  2011        PMID: 21359929     DOI: 10.1140/epje/i2011-11020-1

Source DB:  PubMed          Journal:  Eur Phys J E Soft Matter        ISSN: 1292-8941            Impact factor:   1.890


  20 in total

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6.  Computing counterion densities at intermediate coupling.

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7.  Attraction between like-charged walls: Short-ranged simulations using local molecular field theory.

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8.  Weak- and strong-coupling electrostatic interactions between asymmetrically charged planar surfaces.

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9.  Strong-coupling electrostatics in the presence of dielectric inhomogeneities.

Authors:  Y S Jho; M Kanduc; A Naji; R Podgornik; M W Kim; P A Pincus
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10.  Counterions at highly charged interfaces: from one plate to like-charge attraction.

Authors:  Ladislav Samaj; Emmanuel Trizac
Journal:  Phys Rev Lett       Date:  2011-02-18       Impact factor: 9.161

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  2 in total

1.  Counter-ions at single charged wall: Sum rules.

Authors:  Ladislav Samaj
Journal:  Eur Phys J E Soft Matter       Date:  2013-09-19       Impact factor: 1.890

2.  Multivalent counterions induced attraction between DNA polyelectrolytes.

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Journal:  RSC Adv       Date:  2020-01-09       Impact factor: 4.036

  2 in total

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