Literature DB >> 18954052

Evolution of solid phase homochirality for a proteinogenic amino acid.

Cristobal Viedma1, José E Ortiz, Trinidad de Torres, Toshiko Izumi, Donna G Blackmond.   

Abstract

The inexorable evolution of solid-phase single chirality is demonstrated for the first time for a proteinogenic amino acid. Enantioenrichment is observed both under attrition-enhanced conditions and without the aid of particle grinding. Differences in the form of the conversion profiles for the process under the two sets of conditions provide suggestions concerning the mechanism of the transformation.

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Year:  2008        PMID： 18954052     DOI： 10.1021/ja8074506

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  20 in total

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