Literature DB >> 18688412

Using pyridine amidoximes in 3d-metal cluster chemistry: a novel ferromagnetic Ni12 complex from the use of pyridine-2-amidoxime.

Constantina Papatriantafyllopoulou1, Leigh F Jones, Tuyen D Nguyen, Nuria Matamoros-Salvador, Luís Cunha-Silva, Filipe A Almeida Paz, João Rocha, Marco Evangelisti, Euan K Brechin, Spyros P Perlepes.   

Abstract

The use of pyridine-2-amidoxime in reaction with NiCl2.6H2O in the presence of NaOMe has led to a cationic NiII 12 cluster with novel structural features; each cluster molecule is a ferromagnet with a spin ground state of S = 6 arising from ferromagnetic exchange between the six octahedral NiII ions, but with intercationic interactions also affecting the magnetic properties.

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Year:  2008        PMID： 18688412     DOI： 10.1039/b802927j

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  5 in total

1.  Bis(μ(2)-pyridine-2-carboxamide oximato)bis-[(pyridine-2-carboxamide oxime)zinc] dinitrate.

Authors:  Xiao-Hui Deng; Jing-Wen Ran
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-08-31

2.  Bis[μ(3)-N'-oxidopyridine-2-carbox-imidamidato(2-)]bis-[μ(2)-N'-oxido-pyridine-2-carboximidamidato(1-)]tetra-pyridine-tetra-nickel(II) dinitrate.

Authors:  Xiao-Hui Deng; Jing-Wen Ran
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-12-10

3.  ZnII and CuII-Based Coordination Polymers and Metal Organic Frameworks by the of Use of 2-Pyridyl Oximes and 1,3,5-Benzenetricarboxylic Acid.

Authors:  Ioannis Mylonas-Margaritis; Julia Mayans; Patrick McArdle; Constantina Papatriantafyllopoulou
Journal:  Molecules       Date:  2021-01-18       Impact factor: 4.411

4.  Novel Co5 and Ni4 Metal Complexes and Ferromagnets by the Combination of 2-Pyridyl Oximes with Polycarboxylic Ligands.

Authors:  Foteini Dimakopoulou; Costantinos G Efthymiou; Ciaran O'Malley; Andreas Kourtellaris; Eleni Moushi; Anastasios Tasiopooulos; Spyros P Perlepes; Patrick McArdle; Ernesto Costa-Villén; Julia Mayans; Constantina Papatriantafyllopoulou
Journal:  Molecules       Date:  2022-07-22       Impact factor: 4.927

5.  From 1D Coordination Polymers to Metal Organic Frameworks by the Use of 2-Pyridyl Oximes.

Authors:  Ioannis Mylonas-Margaritis; Auban Gérard; Katerina Skordi; Julia Mayans; Anastasios Tasiopoulos; Patrick McArdle; Constantina Papatriantafyllopoulou
Journal:  Materials (Basel)       Date:  2020-09-14       Impact factor: 3.623
  5 in total

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