Literature DB >> 18399233

Water-soluble and stable dinitrogen phosphine complexes trans-[ReCl(N2)(PTA-H)n(PTA)4-n]n+ (n = 0-4), the first with 1,3,5-triaza-7-phosphaadamantane.

Piotr Smoleński1, Armando J L Pombeiro.   

Abstract

The first dinitrogen complexes with the hydrosoluble PTA ligand, or its protonated form PTA-H, trans-[ReCl(N2)(PTA-H)n(PTA)(4-n)]n+ (n = 0-4), are prepared, shown to be soluble and stable in water, interconvertible by stepwise protonation/deprotonation and to form, upon N2 loss, the corresponding penta-coordinate compounds. Dinitrogen displacement by CO affords trans-[ReCl(CO)(PTA)4].

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Year:  2008        PMID： 18399233     DOI： 10.1039/b712360d

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

1.  Synthesis and Characterization of Novel [2 + 1] Tricarbonyl Rhenium Complexes with the Hydrophilic Phosphine Ligands PTA and CAP.

Authors:  Ioanna Roupa; Charalampos Flampouraris; Antonio Shegani; Myrto Ischyropoulou; Konstantina Makrypidi; Catherine Raptopoulou; Ioannis Pirmettis; Minas S Papadopoulos; Vassilis Psycharis; Aristeidis Chiotellis
Journal:  Bioinorg Chem Appl       Date:  2022-06-13       Impact factor: 4.724

2.  1-Methyl-1-azonia-3,5-diaza-7-phospha-tricyclo-[3.3.1.1]decane 7-oxide triiodide.

Authors:  Alexander M Kirillov; Piotr Smoleński; M Fátima C Guedes da Silva; Armando J L Pombeiro
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-01-23

3.  1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.1]decane tetra-fluoro-borate.

Authors:  Piotr Smoleński; Alexander M Kirillov; M Fátima C Guedes da Silva; Armando J L Pombeiro
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-02-06

4.  Pentafluorophenyl Platinum(II) Complexes of PTA and its N-Allyl and N-Benzyl Derivatives: Synthesis, Characterization and Biological Activity.

Authors:  Paolo Sgarbossa; Urszula Śliwińska-Hill; M Fátima C Guedes da Ilva; Barbara Bażanów; Aleksandra Pawlak; Natalia Jackulak; Dominik Poradowski; Armando J L Pombeiro; Piotr Smoleński
Journal:  Materials (Basel)       Date:  2019-11-26       Impact factor: 3.623
  4 in total

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