| Literature DB >> 18037970 |
Boaz Shapira1, Kiran Shetty, William W Brey, Zhehong Gan, Lucio Frydman.
Abstract
2D NMR relies on monitoring systematic changes in the phases incurred by spin coherences as a function of an encoding time t(1), whose value changes over the course of independent experiments. The intrinsic multiscan nature of such protocols implies that resistive and/or hybrid magnets, capable of delivering the highest magnetic field strengths but possessing poor temporal stabilities, become unsuitable for 2D NMR acquisitions. It is here shown with a series of homo- and hetero-nuclear examples that such limitations can be bypassed using recently proposed 2D "ultrafast" acquisition schemes, which correlate interactions along all spectral dimensions within a single scan.Year: 2007 PMID: 18037970 PMCID: PMC2084366 DOI: 10.1016/j.cplett.2007.06.016
Source DB: PubMed Journal: Chem Phys Lett ISSN: 0009-2614 Impact factor: 2.328