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Literature DB >> 17973481

Cu(I)-catalyzed intermolecular diamination of activated terminal olefins.

Baoguo Zhao¹, Weicheng Yuan, Haifeng Du, Yian Shi.

Abstract

This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions.

Entities: Chemical

Mesh：

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Year: 2007 PMID： 17973481 DOI： 10.1021/ol702061s

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

22 in total

1. Complementary regioselectivity in the Cu(I)-catalyzed diamination of conjugated dienes to form cyclic sulfamides.

Authors: Richard G Cornwall; Baoguo Zhao; Yian Shi
Journal: Org Lett Date: 2010-12-30 Impact factor: 6.005

2. A palladium-catalyzed dehydrogenative diamination of terminal olefins.

Authors: Bin Wang; Haifeng Du; Yian Shi
Journal: Angew Chem Int Ed Engl Date: 2008 Impact factor: 15.336

3. An effective C-C double bond formation via Cu(I)-catalyzed dehydrogenation.

Authors: Thomas A Ramirez; Baoguo Zhao; Yian Shi
Journal: Tetrahedron Lett Date: 2010-04-07 Impact factor: 2.415

Review 4. Cross-Coupling of Heteroatomic Electrophiles.

Authors: Katerina M Korch; Donald A Watson
Journal: Chem Rev Date: 2019-06-11 Impact factor: 60.622

5. Copper-Catalyzed Alkene Aminoazidation as a Rapid Entry to 1,2-Diamines and Installation of an Azide Reporter onto Azahetereocycles.

Authors: Kun Shen; Qiu Wang
Journal: J Am Chem Soc Date: 2017-09-05 Impact factor: 15.419

6. Influence of catalyst structure and reaction conditions on anti- versus syn-aminopalladation pathways in Pd-catalyzed alkene carboamination reactions of N-allylsulfamides.

Authors: Ryan M Fornwald; Jonathan A Fritz; John P Wolfe
Journal: Chemistry Date: 2014-06-17 Impact factor: 5.236

Cu(I)-catalyzed intermolecular diamination of activated terminal olefins.

1. Complementary regioselectivity in the Cu(I)-catalyzed diamination of conjugated dienes to form cyclic sulfamides.

2. A palladium-catalyzed dehydrogenative diamination of terminal olefins.

3. An effective C-C double bond formation via Cu(I)-catalyzed dehydrogenation.

Review 4. Cross-Coupling of Heteroatomic Electrophiles.

5. Copper-Catalyzed Alkene Aminoazidation as a Rapid Entry to 1,2-Diamines and Installation of an Azide Reporter onto Azahetereocycles.

6. Influence of catalyst structure and reaction conditions on anti- versus syn-aminopalladation pathways in Pd-catalyzed alkene carboamination reactions of N-allylsulfamides.

7. Methods for direct alkene diamination, new & old.

8. Cu(I)-catalyzed asymmetric diamination of conjugated dienes.

9. Cu(I)-catalyzed diamination of disubstituted terminal olefins: an approach to potent NK1 antagonist.

10. Catalytic C-H amination for the preparation of substituted 1,2-diamines.