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Literature DB >> 20368750

An effective C-C double bond formation via Cu(I)-catalyzed dehydrogenation.

Thomas A Ramirez¹, Baoguo Zhao, Yian Shi.

Abstract

A dehydrogenation method using Cu(I) and either N,N-di-tert-butylthiadiaziridine 1,1-dioxide or N,N-di-tert-butyldiaziridinone is reported. The dehydrogenation allows a facile introduction of C-C double bond(s) into various carbo- and heterocycles such as oxazolines and thiazolines.

Entities: Chemical Disease Gene

Year: 2010 PMID： 20368750 PMCID： PMC2847290 DOI： 10.1016/j.tetlet.2010.01.114

Source DB: PubMed Journal: Tetrahedron Lett ISSN： 0040-4039 Impact factor: 2.415

28 in total

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Journal: Angew Chem Int Ed Engl Date: 2008 Impact factor: 15.336

2. Copper(II) acetate promoted intramolecular diamination of unactivated olefins.

Authors: Thomas P Zabawa; Dhanalakshmi Kasi; Sherry R Chemler
Journal: J Am Chem Soc Date: 2005-08-17 Impact factor: 15.419

3. Radical transfer hydroamination with aminated cyclohexadienes using polarity reversal catalysis: scope and limitations.

Authors: Joyram Guin; Christian Mück-Lichtenfeld; Stefan Grimme; Armido Studer
Journal: J Am Chem Soc Date: 2007-03-20 Impact factor: 15.419

4. A facile Pd(0)-catalyzed regio- and stereoselective diamination of conjugated dienes and trienes.

Authors: Haifeng Du; Baoguo Zhao; Yian Shi
Journal: J Am Chem Soc Date: 2007-01-31 Impact factor: 15.419

5. Metal-catalysed 1,2-diamination reactions.

Authors: Francesca Cardona; Andrea Goti
Journal: Nat Chem Date: 2009-06-22 Impact factor: 24.427

6. Cu(I)-catalyzed asymmetric diamination of conjugated dienes.

Authors: Haifeng Du; Baoguo Zhao; Weicheng Yuan; Yian Shi
Journal: Org Lett Date: 2008-09-03 Impact factor: 6.005

7. Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene.

Authors: Liang Xu; Yian Shi
Journal: J Org Chem Date: 2007-12-21 Impact factor: 4.354

Review 8. Vicinal diamino functionalities as privileged structural elements in biologically active compounds and exploitation of their synthetic chemistry.

Authors: S R S Saibabu Kotti; Cody Timmons; Guigen Li
Journal: Chem Biol Drug Des Date: 2006-02 Impact factor: 2.817

9. Catalytic asymmetric allylic and homoallylic diamination of terminal olefins via formal C-H activation.

Authors: Haifeng Du; Baoguo Zhao; Yian Shi
Journal: J Am Chem Soc Date: 2008-06-13 Impact factor: 15.419

10. Cu(I)-catalyzed cycloguanidination of olefins.

Authors: Baoguo Zhao; Haifeng Du; Yian Shi
Journal: Org Lett Date: 2008-02-27 Impact factor: 6.005

6 in total

1. Complementary regioselectivity in the Cu(I)-catalyzed diamination of conjugated dienes to form cyclic sulfamides.

Authors: Richard G Cornwall; Baoguo Zhao; Yian Shi
Journal: Org Lett Date: 2010-12-30 Impact factor: 6.005

2. Cu(I)-catalyzed diamination of conjugated dienes. Complementary regioselectivity from two distinct mechanistic pathways involving Cu(II) and Cu(III) species.

Authors: Baoguo Zhao; Xingao Peng; Yingguang Zhu; Thomas A Ramirez; Richard G Cornwall; Yian Shi
Journal: J Am Chem Soc Date: 2011-12-02 Impact factor: 15.419