David E Olson1, J Du Bois. 1. Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA.
Abstract
Rhodium-catalyzed C-H insertion of hydroxylamine-derived sulfamate esters makes possible the synthesis of unique oxathiadiazinane heterocycles, which upon mild reduction furnish differentially substituted 1,2-diamine products. This highly chemo- and diastereoselective transformation underscores the power of catalytic C-H functionalization as a general approach to C-N bond construction.
Rhodium-catalyzed C-H insertion of n class="Chemical">hydroxylamine-derived sulfamate esters makes possible the synthesis of unique oxathiadiazinane heterocycles, which upon mild reduction furnish differentially substituted 1,2-diamine products. This highly chemo- and diastereoselective transformation underscores the power of catalytic C-H functionalization as a general approach to C-N bond construction.
Authors: Jennifer M Schomaker; W Christopher Boyd; Ian C Stewart; F Dean Toste; Robert G Bergman Journal: J Am Chem Soc Date: 2008-03-05 Impact factor: 15.419
Authors: Gary A Cutting; Nikki E Stainforth; Matthew P John; Gabriele Kociok-Köhn; Michael C Willis Journal: J Am Chem Soc Date: 2007-08-11 Impact factor: 15.419
Authors: Jared W Rigoli; Luke A Boralsky; John C Hershberger; Dagmara Marston; Alan R Meis; Ilia A Guzei; Jennifer M Schomaker Journal: J Org Chem Date: 2012-02-14 Impact factor: 4.354