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Literature DB >> 17892296

Regiodivergent metal-catalyzed rearrangement of 3-iminocyclopropenes into N-fused heterocycles.

Abstract

A highly efficient regiodivergent method for the synthesis of N-fused heterocycles via transition-metal-catalyzed rearrangement of 3-iminocyclopropenes has been developed.

Entities: Chemical

Mesh：

Substances：

Year: 2007 PMID： 17892296 PMCID： PMC3684432 DOI： 10.1021/ol702084f

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

21 in total

1. Catalytic enantioselective hydrostannation of cyclopropenes.

Authors: Marina Rubina; Michael Rubin; Vladimir Gevorgyan
Journal: J Am Chem Soc Date: 2004-03-31 Impact factor: 15.419

2. Gold-catalyzed 1,2-migration of silicon, tin, and germanium en route to C-2 substituted fused pyrrole-containing heterocycles.

Authors: Ilya V Seregin; Vladimir Gevorgyan
Journal: J Am Chem Soc Date: 2006-09-20 Impact factor: 15.419

3. Gold-catalyzed organic reactions.

Authors: A Stephen K Hashmi
Journal: Chem Rev Date: 2007-06-20 Impact factor: 60.622

4. Transition metal chemistry of cyclopropenes and cyclopropanes.

Authors: Michael Rubin; Marina Rubina; Vladimir Gevorgyan
Journal: Chem Rev Date: 2007-07 Impact factor: 60.622

5. Rh-catalyzed transannulation of pyridotriazoles with alkynes and nitriles.

Authors: Stepan Chuprakov; Frank W Hwang; Vladimir Gevorgyan
Journal: Angew Chem Int Ed Engl Date: 2007 Impact factor: 15.336

6. Transition metal-catalyzed hydro-, sila-, and stannastannation of cyclopropenes: stereo- and regioselective approach toward multisubstituted cyclopropyl synthons.

Authors: Marina Rubina; Michael Rubin; Vladimir Gevorgyan
Journal: J Am Chem Soc Date: 2002-10-02 Impact factor: 15.419

7. A copper-catalyzed method for the facially selective addition of grignard reagents to cyclopropenes.

Authors: Lian-An Liao; Joseph M Fox
Journal: J Am Chem Soc Date: 2002-12-04 Impact factor: 15.419

8. Theory-guided discovery of unique chemical transformations of cyclopropenes.

Authors: Robin A Weatherhead-Kloster; E J Corey
Journal: Org Lett Date: 2006-01-05 Impact factor: 6.005

9. Catalytic enantioselective hydroboration of cyclopropenes.

Authors: Marina Rubina; Michael Rubin; Vladimir Gevorgyan
Journal: J Am Chem Soc Date: 2003-06-18 Impact factor: 15.419

10. Dirhodium(II) tetra(N-(dodecylbenzenesulfonyl)prolinate) catalyzed enantioselective cyclopropenation of alkynes.

Authors: Huw M L Davies; Gene H Lee
Journal: Org Lett Date: 2004-04-15 Impact factor: 6.005

17 in total

1. Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.

Authors: Stepan Chuprakov; Jamal A Malik; Mikhail Zibinsky; Valery V Fokin
Journal: J Am Chem Soc Date: 2011-06-20 Impact factor: 15.419

2. Rhodium-catalyzed NH insertion of pyridyl carbenes derived from pyridotriazoles: a general and efficient approach to 2-picolylamines and imidazo[1,5-a]pyridines.

Authors: Yi Shi; Anton V Gulevich; Vladimir Gevorgyan
Journal: Angew Chem Int Ed Engl Date: 2014-10-21 Impact factor: 15.336

Regiodivergent metal-catalyzed rearrangement of 3-iminocyclopropenes into N-fused heterocycles.

1. Catalytic enantioselective hydrostannation of cyclopropenes.

2. Gold-catalyzed 1,2-migration of silicon, tin, and germanium en route to C-2 substituted fused pyrrole-containing heterocycles.

3. Gold-catalyzed organic reactions.

4. Transition metal chemistry of cyclopropenes and cyclopropanes.

5. Rh-catalyzed transannulation of pyridotriazoles with alkynes and nitriles.

6. Transition metal-catalyzed hydro-, sila-, and stannastannation of cyclopropenes: stereo- and regioselective approach toward multisubstituted cyclopropyl synthons.

7. A copper-catalyzed method for the facially selective addition of grignard reagents to cyclopropenes.

8. Theory-guided discovery of unique chemical transformations of cyclopropenes.

9. Catalytic enantioselective hydroboration of cyclopropenes.

10. Dirhodium(II) tetra(N-(dodecylbenzenesulfonyl)prolinate) catalyzed enantioselective cyclopropenation of alkynes.

1. Catalytic asymmetric C-H insertions of rhodium(II) azavinyl carbenes.

2. Rhodium-catalyzed NH insertion of pyridyl carbenes derived from pyridotriazoles: a general and efficient approach to 2-picolylamines and imidazo[1,5-a]pyridines.

3. Aziridinium Ylides: Underutilized Intermediates for Complex Amine Synthesis.

4. Intramolecular transannulation of alkynyl triazoles via alkyne-carbene metathesis step: access to fused pyrroles.

5. Rhodium-catalyzed transannulation of 1,2,3-triazoles with nitriles.

6. (7R,8S,8aS)-8-Hydr-oxy-7-phenyl-perhydro-indolizin-3-one.

7. Transannulation of 1-sulfonyl-1,2,3-triazoles with heterocumulenes.

8. Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles.

9. Arylation of rhodium(II) azavinyl carbenes with boronic acids.

10. Highly substituted 2-amido-furans from Rh(II)-catalyzed cyclopropenations of ynamides.