Polymer brushes in solvents of variable quality: molecular dynamics simulations using explicit solvent.

The structure and thermodynamic properties of a system of end-grafted flexible polymer chains grafted to a flat substrate and exposed to a solvent of variable quality are studied by molecular dynamics methods. The macromolecules are described by a coarse-grained bead-spring model, and the solvent molecules by pointlike particles, assuming Lennard-Jones-type interactions between pairs of monomers (epsilon(pp)), solvent molecules (epsilon(ss)), and solvent monomer (epsilon(ps)), respectively. Varying the grafting density sigma(g) and some of these energy parameters, we obtain density profiles of solvent particles and monomers, study structural properties of the chain (gyration radius components, bond orientational parameters, etc.), and examine also the profile of the lateral pressure P( parallel)(z), keeping in the simulation the normal pressure P( perpendicular) constant. From these data, the reduction of the surface tension between solvent and wall as a function of the grafting density of the brush has been obtained. Further results include the stretching force on the monomer adjacent to the grafting site and its variation with solvent quality and grafting density, and dynamic characteristics such as mobility profiles and chain relaxation times. Possible phase transitions (vertical phase separation of the solvent versus lateral segregation of the polymers into "clusters," etc.) are discussed, and a comparison to previous work using implicit solvent models is made. The variation of the brush height and the interfacial width of the transition zone between the pure solvent and the brush agrees qualitatively very well with corresponding experiments.