Literature DB >> 17705501

Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane.

Eric McNeill1, Timothy E Barder, Stephen L Buchwald.   

Abstract

A method for the palladium-catalyzed silylation of aryl chlorides has been developed. The method affords desired product in good yield, is tolerant of a variety of functional groups, and provides access to a wide variety of aryltrimethylsilanes from commercially available aryl chlorides. Additionally, a one-pot procedure that converts aryl chlorides into aryl iodides has been developed.

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Year:  2007        PMID： 17705501     DOI： 10.1021/ol701518f

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  7 in total

1.  Efficient iridium-catalyzed C-H functionalization/silylation of heteroarenes.

Authors:  Biao Lu; John R Falck
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

2.  Synthesis of an electron-rich KITPHOS monophosphine, preparation of derived metal complexes and applications in catalysis.

Authors:  Simon Doherty; Catherine H Smyth; Julian G Knight; Stephen A K Hashmi
Journal:  Nat Protoc       Date:  2012-09-20       Impact factor: 13.491

Review 3.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

Review 4.  Biaryl phosphane ligands in palladium-catalyzed amination.

Authors:  David S Surry; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

5.  Synthesis of an [(NHC)2 Pd(SiMe3 )2 ] Complex and Catalytic cis-Bis(silyl)ations of Alkynes with Unactivated Disilanes.

Authors:  Melvyn B Ansell; Debbie E Roberts; F Geoffrey N Cloke; Oscar Navarro; John Spencer
Journal:  Angew Chem Int Ed Engl       Date:  2015-04-09       Impact factor: 15.336

6.  Synthesis, Structure, Thermal Behavior and cis/trans Isomerization of 2,2'-(EMe₃)₂ (E = C, Si, Ge, Sn) Substituted Azobenzenes.

Authors:  Jonas Hoffmann; Thomas Josef Kuczmera; Enno Lork; Anne Staubitz
Journal:  Molecules       Date:  2019-01-15       Impact factor: 4.411

7.  Dimethylformamide-stabilised palladium nanoclusters catalysed coupling reactions of aryl halides with hydrosilanes/disilanes.

Authors:  Tatsuki Nagata; Takeru Inoue; Xianjin Lin; Shinya Ishimoto; Seiya Nakamichi; Hideo Oka; Ryota Kondo; Takeyuki Suzuki; Yasushi Obora
Journal:  RSC Adv       Date:  2019-06-03       Impact factor: 4.036
  7 in total

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