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Literature DB >> 18698661

Efficient iridium-catalyzed C-H functionalization/silylation of heteroarenes.

Biao Lu¹, John R Falck.

Abstract

Entities: Chemical

Mesh：

Substances：

Year: 2008 PMID： 18698661 PMCID： PMC3768254 DOI： 10.1002/anie.200802456

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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22 in total

1. Palladium-catalyzed intermolecular alkenylation of indoles by solvent-controlled regioselective C-H functionalization.

Authors: Neil P Grimster; Carolyn Gauntlett; Christopher R A Godfrey; Matthew J Gaunt
Journal: Angew Chem Int Ed Engl Date: 2005-05-13 Impact factor: 15.336

Review 2. The synthesis of biologically active organosilicon small molecules.

Authors: Annaliese K Franz
Journal: Curr Opin Drug Discov Devel Date: 2007-11

3. Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds.

Authors: Naofumi Tsukada; John F Hartwig
Journal: J Am Chem Soc Date: 2005-04-13 Impact factor: 15.419

4. C-H bond functionalization in complex organic synthesis.

Authors: Kamil Godula; Dalibor Sames
Journal: Science Date: 2006-04-07 Impact factor: 47.728

5. Hiyama cross-coupling of chloro-, fluoro-, and methoxypyridyltrimethylsilanes: room-temperature novel access to functional bi(het)aryl.

Authors: Philippe Pierrat; Philippe Gros; Yves Fort
Journal: Org Lett Date: 2005-02-17 Impact factor: 6.005

6. Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent.

Authors: Tatsuo Ishiyama; Yusuke Nobuta; John F Hartwig; Norio Miyaura
Journal: Chem Commun (Camb) Date: 2003-12-07 Impact factor: 6.222

7. Directed ortho metalation approach to C-7-substituted indoles. Suzuki-Miyaura cross coupling and the synthesis of pyrrolophenanthridone alkaloids.

Authors: Christian G Hartung; Anja Fecher; Brian Chapell; Victor Snieckus
Journal: Org Lett Date: 2003-05-29 Impact factor: 6.005

8. Directed ortho-metalation of unprotected benzoic acids. Methodology and regioselective synthesis of useful contiguously 3- and 6-substituted 2-methoxybenzoic acid building blocks.

Authors: Thi-Huu Nguyen; Anne-Sophie Castanet; Jacques Mortier
Journal: Org Lett Date: 2006-02-16 Impact factor: 6.005

Efficient iridium-catalyzed C-H functionalization/silylation of heteroarenes.

1. Palladium-catalyzed intermolecular alkenylation of indoles by solvent-controlled regioselective C-H functionalization.

Review 2. The synthesis of biologically active organosilicon small molecules.

3. Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds.

4. C-H bond functionalization in complex organic synthesis.

5. Hiyama cross-coupling of chloro-, fluoro-, and methoxypyridyltrimethylsilanes: room-temperature novel access to functional bi(het)aryl.

6. Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent.

7. Directed ortho metalation approach to C-7-substituted indoles. Suzuki-Miyaura cross coupling and the synthesis of pyrrolophenanthridone alkaloids.

8. Directed ortho-metalation of unprotected benzoic acids. Methodology and regioselective synthesis of useful contiguously 3- and 6-substituted 2-methoxybenzoic acid building blocks.

9. The catalytic cross-coupling of unactivated arenes.

10. Phosphazene base-promoted functionalization of aryltrimethylsilanes.

1. Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation.

2. General and practical one-pot synthesis of dihydrobenzosiloles from styrenes.

3. Catalytic C-H bond silylation of aromatic heterocycles.

4. A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds.

5. Rhodium-Catalyzed Regioselective Silylation of Alkyl C-H Bonds for the Synthesis of 1,4-Diols.

6. Fused heteroaromatic dihydrosiloles: synthesis and double-fold modification.

7. Silylation of C-H bonds in aromatic heterocycles by an Earth-abundant metal catalyst.

8. Iridium-catalyzed (Z)-trialkylsilylation of terminal olefins.

9. Intramolecular Ir(I)-catalyzed benzylic C-H bond amination of ortho-substituted aryl azides.

10. Direct alkenylation of indolin-2-ones by 6-aryl-4-methylthio-2H-pyran-2-one-3-carbonitriles: a novel approach.