Literature DB >> 17551648

Hydroaminations of unactivated alkenes with basic alkylamines: group 4 metal halide catalysts and Brønsted-acid organocatalysts.

Lutz Ackermann1, Ludwig T Kaspar, Andreas Althammer.   

Abstract

Two distinct economical catalysts for intramolecular hydroaminations of electronically unactivated alkenes with basic amines are described, which are based on (a) group 4 metal halides under basic reaction conditions or (b) Brønsted-acid organocatalysts.

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Year:  2007        PMID： 17551648     DOI： 10.1039/b706301f

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  5 in total

1.  Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines.

Authors:  Zhijian Liu; John F Hartwig
Journal:  J Am Chem Soc       Date:  2008-01-10       Impact factor: 15.419

2.  Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex.

Authors:  Lisa D Julian; John F Hartwig
Journal:  J Am Chem Soc       Date:  2010-10-06       Impact factor: 15.419

3.  Hydroamination versus Allylic Amination in Iridium-Catalyzed Reactions of Allylic Acetates with Amines: 1,3-Aminoalcohols via Ester-Directed Regioselectivity.

Authors:  Seung Wook Kim; Thomas Wurm; Gilmar A Brito; Woo-Ok Jung; Jason R Zbieg; Craig E Stivala; Michael J Krische
Journal:  J Am Chem Soc       Date:  2018-07-10       Impact factor: 15.419

4.  Ruthenium-Catalyzed Amination of Secondary Alcohols using Borrowing Hydrogen Methodology.

Authors:  Kostiantyn O Marichev; James M Takacs
Journal:  ACS Catal       Date:  2016-02-23       Impact factor: 13.084

5.  Stereochemistry and mechanism of the Brønsted acid catalyzed intramolecular hydrofunctionalization of an unactivated cyclic alkene.

Authors:  Rachel E McKinney Brooner; Ross A Widenhoefer
Journal:  Chemistry       Date:  2011-04-19       Impact factor: 5.236
  5 in total

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