Literature DB >> 28936364

Ruthenium-Catalyzed Amination of Secondary Alcohols using Borrowing Hydrogen Methodology.

Kostiantyn O Marichev1, James M Takacs1.   

Abstract

A new ruthenium complex catalyzes the amination of primary and secondary alcohols and the regioselective mono- and sequential diamination of diols via the borrowing hydrogen pathway. Several variations on new intra- and intermolecular cyclizations of aminoalcohols, diols and diamines lead to heterocyclic ring systems.

Entities:  

Keywords:  aminations; borrowing hydrogen; heterocycle synthesis; hydrogen autotransfer; ruthenium(II) complex

Year:  2016        PMID： 28936364      PMCID： PMC5604847          DOI： 10.1021/acscatal.6b00175

Source DB:  PubMed          Journal:  ACS Catal            Impact factor:   13.084


  45 in total

1.  Hydrogen autotransfer in the N-alkylation of amines and related compounds using alcohols and amines as electrophiles.

Authors:  Gabriela Guillena; Diego J Ramón; Miguel Yus
Journal:  Chem Rev       Date:  2010-03-10       Impact factor: 60.622

2.  Catalytic enantioselective amination of alcohols by the use of borrowing hydrogen methodology: cooperative catalysis by iridium and a chiral phosphoric acid.

Authors:  Yao Zhang; Ching-Si Lim; Derek Sui Boon Sim; Hui-Jie Pan; Yu Zhao
Journal:  Angew Chem Int Ed Engl       Date:  2013-12-20       Impact factor: 15.336

3.  Selective alkylation of (hetero)aromatic amines with alcohols catalyzed by a ruthenium pincer complex.

Authors:  Santosh Agrawal; Maud Lenormand; Belén Martín-Matute
Journal:  Org Lett       Date:  2012-02-27       Impact factor: 6.005

4.  A sustainable catalytic pyrrole synthesis.

Authors:  Stefan Michlik; Rhett Kempe
Journal:  Nat Chem       Date:  2013-01-20       Impact factor: 24.427

5.  Cobalt-Catalyzed Alkylation of Aromatic Amines by Alcohols.

Authors:  Sina Rösler; Michael Ertl; Torsten Irrgang; Rhett Kempe
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-16       Impact factor: 15.336

6.  Borrowing hydrogen methodology for amine synthesis under solvent-free microwave conditions.

Authors:  Andrew J A Watson; Aoife C Maxwell; Jonathan M J Williams
Journal:  J Org Chem       Date:  2011-02-23       Impact factor: 4.354

7.  Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex.

Authors:  Lisa D Julian; John F Hartwig
Journal:  J Am Chem Soc       Date:  2010-10-06       Impact factor: 15.419

8.  A Sustainable Multicomponent Pyrimidine Synthesis.

Authors:  Nicklas Deibl; Kevin Ament; Rhett Kempe
Journal:  J Am Chem Soc       Date:  2015-10-01       Impact factor: 15.419

9.  Oxidative cyclization of amino alcohols catalyzed by a CpIr complex. Synthesis of indoles, 1,2,3,4-tetrahydroquinolines, and 2,3,4,5-tetrahydro-1-benzazepine.

Authors:  Ken-Ichi Fujita; Kazunari Yamamoto; Ryohei Yamaguchi
Journal:  Org Lett       Date:  2002-08-08       Impact factor: 6.005

10.  Ruthenium-catalyzed N-alkylation of amines and sulfonamides using borrowing hydrogen methodology.

Authors:  M Haniti S A Hamid; C Liana Allen; Gareth W Lamb; Aoife C Maxwell; Hannah C Maytum; Andrew J A Watson; Jonathan M J Williams
Journal:  J Am Chem Soc       Date:  2009-02-11       Impact factor: 15.419
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  2 in total

1.  Effect of Re promoter on the structure and catalytic performance of Ni-Re/Al2O3 catalysts for the reductive amination of monoethanolamine.

Authors:  Lei Ma; Li Yan; An-Hui Lu; Yunjie Ding
Journal:  RSC Adv       Date:  2018-02-20       Impact factor: 4.036

2.  Efficient and selective N-alkylation of amines with alcohols catalysed by manganese pincer complexes.

Authors:  Saravanakumar Elangovan; Jacob Neumann; Jean-Baptiste Sortais; Kathrin Junge; Christophe Darcel; Matthias Beller
Journal:  Nat Commun       Date:  2016-10-06       Impact factor: 14.919
  2 in total

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