Literature DB >> 17463285

A dinuclear Ni(mu-H)Ru complex derived from H2.

Seiji Ogo1, Ryota Kabe, Keiji Uehara, Bunsho Kure, Takashi Nishimura, Saija C Menon, Ryosuke Harada, Shunichi Fukuzumi, Yoshiki Higuchi, Takashi Ohhara, Taro Tamada, Ryota Kuroki.   

Abstract

Models of the active site in [NiFe]hydrogenase enzymes have proven challenging to prepare. We isolated a paramagnetic dinuclear nickel-ruthenium complex with a bridging hydrido ligand from the heterolytic cleavage of H2 by a dinuclear NiRu aqua complex in water under ambient conditions (20 degrees C and 1 atmosphere pressure). The structure of the hexacoordinate Ni(mu-H)Ru complex was unequivocally determined by neutron diffraction analysis, and it comes closest to an effective analog for the core structure of the proposed active form of the enzyme.

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Year:  2007        PMID： 17463285     DOI： 10.1126/science.1138751

Source DB:  PubMed          Journal:  Science        ISSN： 0036-8075            Impact factor:   47.728


  19 in total

1.  Models for the hydrogenases put the focus where it should be--hydrogen.

Authors:  Carlo Mealli; Thomas B Rauchfuss
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

2.  Interplay of hemilability and redox activity in models of hydrogenase active sites.

Authors:  Shengda Ding; Pokhraj Ghosh; Marcetta Y Darensbourg; Michael B Hall
Journal:  Proc Natl Acad Sci U S A       Date:  2017-10-30       Impact factor: 11.205

Review 3.  Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.

Authors:  David Schilter; James M Camara; Mioy T Huynh; Sharon Hammes-Schiffer; Thomas B Rauchfuss
Journal:  Chem Rev       Date:  2016-06-29       Impact factor: 60.622

Review 4.  Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes.

Authors:  R Morris Bullock; Geoffrey M Chambers
Journal:  Philos Trans A Math Phys Eng Sci       Date:  2017-08-28       Impact factor: 4.226

5.  From natural to artificial photosynthesis.

Authors:  James Barber; Phong D Tran
Journal:  J R Soc Interface       Date:  2013-01-30       Impact factor: 4.118

6.  A model for the CO-inhibited form of [NiFe] hydrogenase: synthesis of CO3Fe(micro-StBu)3Ni{SC6H3-2,6-(mesityl)2} and reversible CO addition at the Ni site.

Authors:  Yasuhiro Ohki; Kazunari Yasumura; Masaru Ando; Satoko Shimokata; Kazuyuki Tatsumi
Journal:  Proc Natl Acad Sci U S A       Date:  2010-02-10       Impact factor: 11.205

Review 7.  Small molecule mimics of hydrogenases: hydrides and redox.

Authors:  Frédéric Gloaguen; Thomas B Rauchfuss
Journal:  Chem Soc Rev       Date:  2008-10-31       Impact factor: 54.564

8.  Coordination chemistry of [HFe(CN)(2)(CO)(3)](-) and its derivatives: toward a model for the iron subsite of the [NiFe]-hydrogenases.

Authors:  C Matthew Whaley; Thomas B Rauchfuss; Scott R Wilson
Journal:  Inorg Chem       Date:  2009-05-18       Impact factor: 5.165

9.  Biomimetic chemistry of iron, nickel, molybdenum, and tungsten in sulfur-ligated protein sites.

Authors:  Stanislav Groysman; R H Holm
Journal:  Biochemistry       Date:  2009-03-24       Impact factor: 3.162

10.  Thiolate-bridged dinuclear iron(tris-carbonyl)-nickel complexes relevant to the active site of [NiFe] hydrogenase.

Authors:  Yasuhiro Ohki; Kazunari Yasumura; Katsuaki Kuge; Soichiro Tanino; Masaru Ando; Zilong Li; Kazuyuki Tatsumi
Journal:  Proc Natl Acad Sci U S A       Date:  2008-05-29       Impact factor: 11.205
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