Literature DB >> 19088969

Small molecule mimics of hydrogenases: hydrides and redox.

Frédéric Gloaguen1, Thomas B Rauchfuss.   

Abstract

This tutorial review is aimed at chemical scientists interested in understanding and exploiting the remarkable catalytic behavior of the hydrogenases. The key structural features are analyzed for the active sites of the two most important hydrogenases. Reactivity is emphasized, focusing on mechanism and catalysis. Through this analysis, gaps are identified in the synthesis of functional replicas of these fascinating and potentially useful enzymes.

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Year:  2008        PMID： 19088969      PMCID： PMC3462221          DOI： 10.1039/b801796b

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN： 0306-0012            Impact factor:   54.564


  46 in total

1.  Unsaturated, mixed-valence diiron dithiolate model for the H(ox) state of the [FeFe] hydrogenase.

Authors:  Aaron K Justice; Thomas B Rauchfuss; Scott R Wilson
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

2.  Pendant bases as proton relays in iron hydride and dihydrogen complexes.

Authors:  Renee M Henry; Richard K Shoemaker; Daniel L DuBois; M Rakowski DuBois
Journal:  J Am Chem Soc       Date:  2006-03-08       Impact factor: 15.419

3.  Preparative and structural studies on the carbonyl cyanides of iron, manganese, and ruthenium: fundamentals relevant to the hydrogenases.

Authors:  Stephen M Contakes; Sodio C N Hsu; Thomas B Rauchfuss; Scott R Wilson
Journal:  Inorg Chem       Date:  2002-03-25       Impact factor: 5.165

4.  Electrocatalytic proton reduction by phosphido-bridged diiron carbonyl compounds: distant relations to the H-cluster?

Authors:  Mun Hon Cheah; Stacey J Borg; Mark I Bondin; Stephen P Best
Journal:  Inorg Chem       Date:  2004-09-06       Impact factor: 5.165

5.  Diiron dithiolato carbonyls related to the H(ox)CO state of [FeFe]-hydrogenase.

Authors:  Aaron K Justice; Mark J Nilges; Thomas B Rauchfuss; Scott R Wilson; Luca De Gioia; Giuseppe Zampella
Journal:  J Am Chem Soc       Date:  2008-03-15       Impact factor: 15.419

6.  Nitrosyl derivatives of diiron(I) dithiolates mimic the structure and Lewis acidity of the [FeFe]-hydrogenase active site.

Authors:  Matthew T Olsen; Maurizio Bruschi; Luca De Gioia; Thomas B Rauchfuss; Scott R Wilson
Journal:  J Am Chem Soc       Date:  2008-08-14       Impact factor: 15.419

7.  Terminal hydride in [FeFe]-hydrogenase model has lower potential for H2 production than the isomeric bridging hydride.

Authors:  Bryan E Barton; Thomas B Rauchfuss
Journal:  Inorg Chem       Date:  2008-03-12       Impact factor: 5.165

8.  Visible light-driven electron transfer and hydrogen generation catalyzed by bioinspired [2Fe2S] complexes.

Authors:  Yong Na; Mei Wang; Jingxi Pan; Pan Zhang; Björn Akermark; Licheng Sun
Journal:  Inorg Chem       Date:  2008-03-12       Impact factor: 5.165

9.  Ligand versus metal protonation of an iron hydrogenase active site mimic.

Authors:  Gerriet Eilers; Lennart Schwartz; Matthias Stein; Giuseppe Zampella; Luca de Gioia; Sascha Ott; Reiner Lomoth
Journal:  Chemistry       Date:  2007       Impact factor: 5.236

10.  Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases.

Authors:  Jane L Stanley; Zachariah M Heiden; Thomas B Rauchfuss; Scott R Wilson; Luca De Gioia; Guiseppe Zampella
Journal:  Organometallics       Date:  2008-01       Impact factor: 3.876
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  55 in total

1.  Hydride-containing models for the active site of the nickel-iron hydrogenases.

Authors:  Bryan E Barton; Thomas B Rauchfuss
Journal:  J Am Chem Soc       Date:  2010-10-27       Impact factor: 15.419

2.  Combining acid-base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase.

Authors:  James M Camara; Thomas B Rauchfuss
Journal:  Nat Chem       Date:  2011-10-30       Impact factor: 24.427

3.  A molecular molybdenum-oxo catalyst for generating hydrogen from water.

Authors:  Hemamala I Karunadasa; Christopher J Chang; Jeffrey R Long
Journal:  Nature       Date:  2010-04-29       Impact factor: 49.962

4.  A nonclassical dihydrogen adduct of S = ½ Fe(I).

Authors:  Yunho Lee; R Adam Kinney; Brian M Hoffman; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2011-09-28       Impact factor: 15.419

5.  Catalytic reduction of N2 to NH3 by an Fe-N2 complex featuring a C-atom anchor.

Authors:  Sidney E Creutz; Jonas C Peters
Journal:  J Am Chem Soc       Date:  2014-01-09       Impact factor: 15.419

Review 6.  Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.

Authors:  Aaron M Appel; John E Bercaw; Andrew B Bocarsly; Holger Dobbek; Daniel L DuBois; Michel Dupuis; James G Ferry; Etsuko Fujita; Russ Hille; Paul J A Kenis; Cheryl A Kerfeld; Robert H Morris; Charles H F Peden; Archie R Portis; Stephen W Ragsdale; Thomas B Rauchfuss; Joost N H Reek; Lance C Seefeldt; Rudolf K Thauer; Grover L Waldrop
Journal:  Chem Rev       Date:  2013-06-14       Impact factor: 60.622

Review 7.  Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides.

Authors:  David Schilter; James M Camara; Mioy T Huynh; Sharon Hammes-Schiffer; Thomas B Rauchfuss
Journal:  Chem Rev       Date:  2016-06-29       Impact factor: 60.622

8.  Terminal vs bridging hydrides of diiron dithiolates: protonation of Fe2(dithiolate)(CO)2(PMe3)4.

Authors:  Riccardo Zaffaroni; Thomas B Rauchfuss; Danielle L Gray; Luca De Gioia; Giuseppe Zampella
Journal:  J Am Chem Soc       Date:  2012-11-13       Impact factor: 15.419

9.  An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen.

Authors:  Tianbiao Liu; Daniel L Dubois; R Morris Bullock
Journal:  Nat Chem       Date:  2013-02-17       Impact factor: 24.427

10.  Hydrogen activation by biomimetic diiron dithiolates.

Authors:  Matthew T Olsen; Bryan E Barton; Thomas B Rauchfuss
Journal:  Inorg Chem       Date:  2009-08-17       Impact factor: 5.165
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