Literature DB >> 16901164

ZnO as a new catalyst for N-formylation of amines under solvent-free conditions.

Mona Hosseini-Sarvari1, Hashem Sharghi.   

Abstract

The treatment of amines with formic acid in the presence of ZnO under solvent-free conditions brings about highly and efficient N-formylation to give the corresponding formamides in excellent yields. The N-formylation reaction not only involves mild conditions, simple operation, and high yields but also high chemoselectivity.

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Year:  2006        PMID： 16901164     DOI： 10.1021/jo060847z

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  12 in total

1.  Concise Total Synthesis of (-)-Affinisine Oxindole, (+)-Isoalstonisine, (+)-Alstofoline, (-)-Macrogentine, (+)-Na -Demethylalstonisine, (-)-Alstonoxine A, and (+)-Alstonisine.

Authors:  Michael Rajesh Stephen; M Toufiqur Rahman; V V N Phani Babu Tiruveedhula; German O Fonseca; Jeffrey R Deschamps; James M Cook
Journal:  Chemistry       Date:  2017-10-18       Impact factor: 5.236

2.  Mild and convenient N-formylation protocol in water-containing solvents.

Authors:  Bilal A Aleiwi; Katsuhiko Mitachi; Michio Kurosu
Journal:  Tetrahedron Lett       Date:  2013-04-17       Impact factor: 2.415

3.  N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)formamide.

Authors:  Hao-Wei Wang; Ming-Ming Yang; Qi-Sheng Lu; Fang-Shi Li
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-05-07

4.  Catalyst free N-formylation of aromatic and aliphatic amines exploiting reductive formylation of CO2 using NaBH4.

Authors:  Arun Kumar; Pankaj Sharma; Nidhi Sharma; Yashwant Kumar; Dinesh Mahajan
Journal:  RSC Adv       Date:  2021-07-27       Impact factor: 4.036

5.  MoS2-Catalyzed transamidation reaction.

Authors:  Feng Zhang; Lesong Li; Juan Ma; Hang Gong
Journal:  Sci Rep       Date:  2019-02-22       Impact factor: 4.379

6.  N-formyl-stabilizing quasi-catalytic species afford rapid and selective solvent-free amination of biomass-derived feedstocks.

Authors:  Hu Li; Haixin Guo; Yaqiong Su; Yuya Hiraga; Zhen Fang; Emiel J M Hensen; Masaru Watanabe; Richard Lee Smith
Journal:  Nat Commun       Date:  2019-02-11       Impact factor: 14.919

7.  Efficient N-formylation of primary aromatic amines using novel solid acid magnetic nanocatalyst.

Authors:  Jitendra Kumar Yadav; Priyanka Yadav; Satish K Awasthi; Alka Agarwal
Journal:  RSC Adv       Date:  2020-11-12       Impact factor: 3.361

8.  The synthesis and characterization of Fe2O3@SiO2-SO3H nanofibers as a novel magnetic core-shell catalyst for formamidine and formamide synthesis.

Authors:  Hakimeh Ziyadi; Mitra Baghali; Akbar Heydari
Journal:  Heliyon       Date:  2021-05-29

9.  Molecular-oxygen-promoted Cu-catalyzed oxidative direct amidation of nonactivated carboxylic acids with azoles.

Authors:  Wen Ding; Shaoyu Mai; Qiuling Song
Journal:  Beilstein J Org Chem       Date:  2015-11-11       Impact factor: 2.883

10.  Imidazolium Chloride: An Efficient Catalyst for Transamidation of Primary Amines.

Authors:  Qingqiang Tian; Zongjie Gan; Xuetong Wang; Dan Li; Wen Luo; Huajun Wang; Zeshu Dai; Jianyong Yuan
Journal:  Molecules       Date:  2018-09-02       Impact factor: 4.411
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