Literature DB >> 16898821

Platinum-catalyzed intramolecular asymmetric hydroarylation of unactivated alkenes with indoles.

Xiaoqing Han1, Ross A Widenhoefer.   

Abstract

[reaction: see text] A 1:1 mixture of the platinum bis(phosphine) complex [(S)-4]PtCl2 [(S)-4 = (S)-3,5-t-Bu-4-MeO-MeOBIPHEP] catalyzes the intramolecular asymmetric hydroarylation of 2-(4-pentenyl)indoles in moderate to good yield with up to 90% ee.

Entities:  

Year:  2006        PMID： 16898821     DOI： 10.1021/ol061441b

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  14 in total

1.  Rhodium catalyzed chelation-assisted C-H bond functionalization reactions.

Authors:  Denise A Colby; Andy S Tsai; Robert G Bergman; Jonathan A Ellman
Journal:  Acc Chem Res       Date:  2011-12-08       Impact factor: 22.384

2.  Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclization.

Authors:  Charles A Mullen; Alison N Campbell; Michel R Gagné
Journal:  Angew Chem Int Ed Engl       Date:  2008       Impact factor: 15.336

3.  Enantioselective Dehydrogenative Heck Arylations of Trisubstituted Alkenes with Indoles to Construct Quaternary Stereocenters.

Authors:  Chun Zhang; Celine B Santiago; Jennifer M Crawford; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2015-12-10       Impact factor: 15.419

4.  Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C-H bond activation.

Authors:  Andy S Tsai; Rebecca M Wilson; Hitoshi Harada; Robert G Bergman; Jonathan A Ellman
Journal:  Chem Commun (Camb)       Date:  2009-06-02       Impact factor: 6.222

5.  Rhodium-Catalyzed Enantioselective Cycloisomerization to Cyclohexenes Bearing Quaternary Carbon Centers.

Authors:  Jung-Woo Park; Zhiwei Chen; Vy M Dong
Journal:  J Am Chem Soc       Date:  2016-03-08       Impact factor: 15.419

6.  One-Pot Catalytic Asymmetric Synthesis of Tetrahydrocarbazoles.

Authors:  Qiong-Jie Liu; Wen-Guang Yan; Lijia Wang; X Peter Zhang; Yong Tang
Journal:  Org Lett       Date:  2015-08-07       Impact factor: 6.005

7.  Enantioselective intramolecular hydroarylation of alkenes via directed C-H bond activation.

Authors:  Hitoshi Harada; Reema K Thalji; Robert G Bergman; Jonathan A Ellman
Journal:  J Org Chem       Date:  2008-08-06       Impact factor: 4.354

Review 8.  Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

Authors:  Denise A Colby; Robert G Bergman; Jonathan A Ellman
Journal:  Chem Rev       Date:  2010-02-10       Impact factor: 60.622

9.  A new approach to carbon-carbon bond formation: Development of aerobic Pd-catalyzed reductive coupling reactions of organometallic reagents and styrenes.

Authors:  Keith M Gligorich; Yasumasa Iwai; Sarah A Cummings; Matthew S Sigman
Journal:  Tetrahedron       Date:  2009-06-27       Impact factor: 2.457

10.  Fe(OTf)3-catalysed Friedel-Crafts reaction of benzenoid arenes with α,β-unsaturated carbonyl compounds: easy access to 1,1-diarylalkanes.

Authors:  Aditya Bhattacharya; Pushpendra Mani Shukla; Biswajit Maji
Journal:  R Soc Open Sci       Date:  2017-10-25       Impact factor: 2.963
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.