Literature DB >> 16529452

Synthesis of cationic oxorhenium salen complexes via mu-oxo abstraction and their activity in catalytic reductions.

Elon A Ison1, Jeanette E Cessarich, Guodong Du, Phillip E Fanwick, Mahdi M Abu-Omar.   

Abstract

Cationic oxorhenium salen complexes are prepared by the abstraction of bridging oxo ligands with [Et3Si][B(C6F5)4] and [Ph3C][B(C6F5)4]. These complexes catalyze the reduction of 2-butanone with Et3SiH under ambient conditions.

Entities:  

Year:  2006        PMID： 16529452     DOI： 10.1021/ic0520768

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  6 in total

1.  Re(V) and Re(III) complexes with sal2phen and triphenylphosphine: rearrangement, oxidation and reduction.

Authors:  Stephanie Renee Lane; Nebiat Sisay; Brett Carney; Shorouk Dannoon; Stephen Williams; Hendrik Petrus Engelbrecht; Charles Leslie Barnes; Silvia Sabine Jurisson
Journal:  Dalton Trans       Date:  2010-11-15       Impact factor: 4.390

2.  Enantioselective reduction of ketones and imines catalyzed by (CN-box)Re(V)-oxo complexes.

Authors:  Kristine A Nolin; Richard W Ahn; Yusuke Kobayashi; Joshua J Kennedy-Smith; F Dean Toste
Journal:  Chemistry       Date:  2010-08-16       Impact factor: 5.236

3.  Hydrosilation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η-Silane Iridium(III) Complex.

Authors:  Sehoon Park; Maurice Brookhart
Journal:  Organometallics       Date:  2010-10       Impact factor: 3.876

4.  Novel rhenium(III, IV, and V) tetradentate N2O2 Schiff base mononuclear and dinuclear complexes.

Authors:  David A Rotsch; Kimberly M Reinig; Eric M Weis; Anna B Taylor; Charles L Barnes; Silvia S Jurisson
Journal:  Dalton Trans       Date:  2013-07-04       Impact factor: 4.390

Review 5.  Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different.

Authors:  Pablo Ríos; Amor Rodríguez; Salvador Conejero
Journal:  Chem Sci       Date:  2022-06-06       Impact factor: 9.969

Review 6.  Hydrosilylation Reactions Catalyzed by Rhenium.

Authors:  Duo Wei; Ruqaya Buhaibeh; Yves Canac; Jean-Baptiste Sortais
Journal:  Molecules       Date:  2021-04-29       Impact factor: 4.411
  6 in total

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