Literature DB >> 16448111

Palladium(II)-catalyzed aerobic dialkoxylation of styrenes: a profound influence of an o-phenol.

Mitchell J Schultz1, Matthew S Sigman.   

Abstract

We report a Pd(II)-catalyzed aerobic dialkoxylation of styrene derivatives that requires an o-phenol. Initial scope and preliminary mechanistic studies are presented in which the o-phenol is proposed to facilitate the formation of a quinone methide intermediate.

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Year:  2006        PMID： 16448111     DOI： 10.1021/ja0579053

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  15 in total

1.  Efficient diacetoxylation of alkenes via Pd(II)/Pd(IV) process with peracetic acid and acetic anhydride.

Authors:  Chan Pil Park; Joo Ho Lee; Kyung Soo Yoo; Kyung Woon Jung
Journal:  Org Lett       Date:  2010-06-04       Impact factor: 6.005

2.  N-Nosyl Oxaziridines as Terminal Oxidants in Copper(II)-Catalyzed Olefin Oxyaminations.

Authors:  Sandra M Deporter; Ashley C Jacobsen; Katherine M Partridge; Kevin S Williamson; Tehshik P Yoon
Journal:  Tetrahedron Lett       Date:  2010-10-06       Impact factor: 2.415

3.  Palladium(II)-catalyzed enantio- and diastereoselective synthesis of pyrrolidine derivatives.

Authors:  Ranjan Jana; Tejas P Pathak; Katrina H Jensen; Matthew S Sigman
Journal:  Org Lett       Date:  2012-08-08       Impact factor: 6.005

4.  Pd(II)-catalyzed oxidative 1,1-diarylation of terminal olefins.

Authors:  Erik W Werner; Kaveri B Urkalan; Matthew S Sigman
Journal:  Org Lett       Date:  2010-06-18       Impact factor: 6.005

5.  A palladium-catalyzed three-component cross-coupling of conjugated dienes or terminal alkenes with vinyl triflates and boronic acids.

Authors:  Longyan Liao; Ranjan Jana; Kaveri Balan Urkalan; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2011-03-30       Impact factor: 15.419

6.  Recent advancements and challenges of palladium(II)-catalyzed oxidation reactions with molecular oxygen as the sole oxidant.

Authors:  Keith M Gligorich; Matthew S Sigman
Journal:  Chem Commun (Camb)       Date:  2009-05-14       Impact factor: 6.222

7.  Advancing the mechanistic understanding of an enantioselective palladium-catalyzed alkene difunctionalization reaction.

Authors:  Katrina H Jensen; Jonathan D Webb; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2010-11-17       Impact factor: 15.419

8.  Palladium-catalyzed enantioselective addition of two distinct nucleophiles across alkenes capable of quinone methide formation.

Authors:  Katrina H Jensen; Tejas P Pathak; Yang Zhang; Matthew S Sigman
Journal:  J Am Chem Soc       Date:  2009-12-02       Impact factor: 15.419

9.  Asymmetric cycloadditions of palladium-polarized aza-o-xylylenes.

Authors:  Chao Wang; Jon A Tunge
Journal:  J Am Chem Soc       Date:  2008-06-06       Impact factor: 15.419

10.  Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions.

Authors:  Katrina H Jensen; Matthew S Sigman
Journal:  Org Biomol Chem       Date:  2008-10-09       Impact factor: 3.876
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