| Literature DB >> 20481606 |
Erik W Werner1, Kaveri B Urkalan, Matthew S Sigman.
Abstract
Evaluation of the scope of a Pd(II)-catalyzed oxidative 1,1-diarylation reaction of terminal olefins using aryl stannanes is reported. The reaction is shown to be tolerant of functionality commonly encountered in organic synthesis; however, the reaction outcome was found to be dependent on the nature of the aryl stannane used. A mechanistic rationale for the observation of this influence is provided.Entities:
Mesh:
Substances:
Year: 2010 PMID: 20481606 PMCID: PMC2908953 DOI: 10.1021/ol1009575
Source DB: PubMed Journal: Org Lett ISSN: 1523-7052 Impact factor: 6.005